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A thermodynamic equilibrium analysis on steam reforming process to utilize acetone-butanol-ethanol-water mixture obtained from biomass fermentation as biorenewable fuel has been performed to produce clean energy carrier H 2 via non-stoichiometric approach namely Gibbs free energy minimization method. The effect of process variables such as temperature (573–1473 K), pressure (1–10 atm), and steam/fuel molar feed ratio ( F ABE  = 5.5–12) have been investigated on equilibrium compositions of products, H 2 , CO, CO 2 , CH 4 and solid carbon. The best suitable conditions for maximization of desired product H 2 , suppression of CH 4 , and inhibition of solid carbon are 973 K, 1 atm, steam/fuel molar feed ratio = 12. Under these conditions, the maximum molar production of hydrogen is 8.35 with negligible formation of carbon and methane. Furthermore, the energy requirement per mol of H 2 (48.96 kJ), thermal efficiency (69.13%), exergy efficiency (55.09%), exergy destruction (85.36 kJ/mol), and generated entropy (0.29 kJ/mol.K) have been achieved at same operating conditions. [ABSTRACT FROM AUTHOR]

Recently, hydrogen is utilized by numerous chemical industries as an alternate over non-renewable fuels, and surely it will be considered as an important fuel in the near future. This paper reports a review of various reforming technologies for hydrogen production from butanol produced by fermentation of feedstocks like wheat, sugar beets, sugar cane, etc. with a number of aspects involving selection of an appropriate catalyst to suppress undesirable products as many reforming reactions are dependent on the catalyst properties to enhance the formation of significant fuels which may fulfill the future energy needs. An overview of butanol reforming processes with experimental and theoretical studies in order to grasp possibilities and restrictions of these processes is not comprehensively presented yet. In this paper, an assessment of published articles in brief related to essential parameters to carry out a pertinent research in the future is presented for the advancement of fuel processing technologies. [ABSTRACT FROM AUTHOR]