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Abstract: In the present work, the effect of the hydrogen and the air temperature values on the temperature distribution in a Planar Solid Oxide Fuel Cell is studied by the aid of a two-dimensional mathematical model. Two different configurations of the Solid Oxide Fuel Cells are examined: i) the Anode Supported Planar Solid Oxide Fuel Cell (ASP_SOFC) and ii) the Electrolyte Supported Planar Solid Oxide Fuel Cell (ESP_SOFC). In order to describe the temperature distribution within the SOFC, the coupling of the mass and energy transport phenomena along with the electrochemistry is required. The studied parameters are: a) the hydrogen and the air temperature values and b) the geometry configurations. The complex system of the governing equations is numerically solved with the finite differences method and the calculation of the temperature distribution within each domain of the SOFCs is calculated via the 2-D mathematical model processed by FORTRAN language. Finally, the mathematical model predictions for the temperature distribution under the influence of the studied parameters are thoroughly discussed. [Copyright &y& Elsevier]

Energy and exergy assessments are reported of integrated power generation using solid oxide fuel cells (SOFCs) with internal reforming and a gas turbine cycle. The gas turbine inlet temperature is fixed at 1573 K and the high-temperature turbine exhaust heats the natural gas and air inputs, and generates pressurized steam. The steam mixes at the SOFC stack inlet with natural gas to facilitate the reformation process. The integration of solid oxide fuel cells with gas turbines increases significantly the power generation efficiency relative to separate processes and reduces greatly the exergy loss due to combustion, which is the most irreversible process in the system. The other main exergy destruction is attributable to electrochemical fuel oxidation in the SOFC. The energy and exergy efficiencies of the integrated system reach 70-80%, which compares well to the efficiencies of approximately 55% typical of conventional combined-cycle power generation systems. Variations in the energy and exergy efficiencies of the integrated system with operating conditions are provided, showing, for example, that SOFC efficiency is enhanced if the fuel cell active area is augmented. The SOFC stack efficiency can be maximized by reducing the steam generation while increasing the stack size, although such measures imply a significant and nonproportional cost rise. Such measures must be implemented cautiously, as a reduction in steam generation decreases the steam/methane ratio at the anode inlet, which may increase the risk of catalyst coking. A detailed assessment of an illustrative example highlights the main results. [ABSTRACT FROM AUTHOR]

We investigate the effects of Pauli blocking on the properties of hydrogen at high pressures, where recent experiments have shown a transition from insulating behavior to metal-like conductivity. Since the Pauli principle prevents multiple occupation of electron states (Pauli blocking), atomic states disintegrate subsequently at high densities (Mott effect). We calculate the energy shifts due to Pauli blocking and discuss the Mott effect solving an effective Schrodinger equation for strongly correlated systems. The ionization equilibrium is treated on the basis of a chemical approach. Results for the ionization equilibrium and the pressure in the region 4000 K