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Abstract: Analysis of a fuel processor based on methanol steam reforming has been carried out to produce fuel cell grade H2. Six reactor configurations namely FBR1 (fixed bed reactor), MR1 (H2 selective membrane reactor with one reaction tube), MR2 (H2 selective membrane reactor with two reaction tubes), FBR2 (FBR1+preferential CO oxidation (PROX) reactor), MR3 (MR1+PROX), and MR4 (MR2+PROX) are evaluated by simulation to identify the suitable processing scheme. The yield of H2 is significantly affected by H2 selective membrane, residence time, temperature, and pressure conditions at complete methanol conversion. The enhancement in residence time in MR2 by using two identical reaction tubes provides H2 yield of 2.96 with 91.25mol% recovery at steam/methanol ratio of 1.5, pressure of 2bar and 560K temperature. The exit retentate gases from MR2 are further treated in PROX reactor of MR4 to reduce CO concentration to 4.1ppm to ensure the safe discharge to the environment. The risk of carbon deposition on reforming catalyst is highly reduced in MR4, and MR4 reactor configuration generates 7.4NLmin−1 of CO free H2 from 0.12molmin−1 of methanol which can provide 470W PEMFC feedstock requirement. Hence, process scheme in MR4 provides a compact and innovative fuel cell grade H2 generating unit. [Copyright &y& Elsevier]

Abstract: A one-dimensional non-isothermal model for oxygen permeable membrane reactor has been developed to simulate the partial oxidation of methane to produce hydrogen. The performance of two fixed bed reactors (FBRs) viz. one with pure O2 in feed (FBR1), other with air in feed (FBR2), and a membrane reactor (MR) having air in non-reaction side have been studied at various feed conditions and inlet temperatures in order to investigate the effect of these parameters on conversion of methane and yield of hydrogen. The fixed bed reactor with pure O2 in feed has been found to provide better performance as compared to fixed bed reactor with air and membrane reactor. [Copyright &y& Elsevier]