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Start Over Author "Xie, Xianna" Topic hydrogen spillover
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1. Selective conversion of microcrystalline cellulose into hexitols over a Ru/[Bmim]3PW12O40 catalyst under mild conditions.

Author

Xie, Xianna, Han, Jinyu, Wang, Hua, Zhu, Xinli, Liu, Xiao, Niu, Yufei, Song, Zhiqiang, and Ge, Qingfeng

Subjects
*MICROCRYSTALLINE polymers, *CELLULOSE, *RUTHENIUM catalysts, *BIFUNCTIONAL catalysis, *HYDROGENOLYSIS
Abstract

Highlights: [•] The bifunctional Ru/[Bmim]3PW12O40 catalyst has a high hexitol selectivity in cellulose conversion. [•] Brønsted acid sites were generated in situ via hydrogen spillover from Ru to the support. [•] The Brønsted acids work synergistically with Ru to catalyze the hydrogenolysis of cellulose. [ABSTRACT FROM AUTHOR]

Published
2014
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