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Metal hydride (MH) suffers from strong thermal effects during hydrogen absorption. To fully utilize the reaction heat during hydrogen absorption, phase change material (PCM) can be used to achieve efficient thermal management in the reactor. A novel MH-PCM reactor with the partition arrangement of MH and PCM was proposed in this paper. Then, the two-dimensional multiphysics coupled model of the reactor was developed, and the effects of the number of partitions n , the mass of PCM and the hydrogen absorption pressure P a on the hydrogen absorption performance were discussed detailedly. The results indicated that the novel MH-PCM reactor not only increases the heat transfer area and boots the hydrogen absorption rate, but also improves the uniformity of temperature distribution. As the n increases from 2 to 5, the hydrogen absorption time gradually shortens. Compared to the conventional MH-PCM reactor, the time for 90% hydrogen absorption shortens by 67.13%. Furthermore, the hydrogen absorption rate can be enhanced with the increasing mass of PCM and P a. However, the larger these values are, the weaker the enhancement effect becomes. The results of this paper may provide a new direction for the optimized design and engineering application of MH-PCM reactors. • A novel reactor with the partition arrangement of MH and PCM is proposed. • Effects of partition number, hydrogen storage pressure and PCM mass are examined. • Novel reactor boosts hydrogen absorption rate and improves temperature uniformity. • The hydrogen absorption time is shortened by 67.13% via a partition number of 5. • Absorption enhancement ratio reduces as hydrogen pressure and PCM mass increase. [ABSTRACT FROM AUTHOR]

With the wide application of hydrogen, the research related to 70 MPa pressure level hydrogen storage tank is very important. This paper takes the 70 MPa hydrogen storage tank in the hydrogen refueling station as the research object, and analyses the diffusion characteristics of hydrogen after leakage from the tank under different wind conditions by FLUENT. Studies find that after hydrogen ejects to the obstacle by the effect of high-pressure, it transforms to be dominated by the simple diffusion and the wind condition. The ambient wind helps to reduce the volume fraction of hydrogen. This paper proposes risk mitigation measures based on the distribution of the flammable clouds — installing nitrogen outlets and reducing the height of the enclosure. The volume of flammable clouds is reduced from about 2.72 m3 to less than 0.045 m3 after adding measures, which proves the feasibility of the measures. • A hydrogenation station model is established to simulate the leakage of a 70 MPa hydrogen storage tank. • The diffusion of hydrogen under different wind conditions is compared. • Risk mitigation measures based on the distribution of flammable clouds are proposed and validated. [ABSTRACT FROM AUTHOR]

The application of hydrogen energy is affected by the safety of hydrogen storage system. To grasp the current status of research and application in the research field of hydrogen storage safety and explore its research development trend, data analysis techniques, such as co-occurrence, co-citation, and burst detection, were adopted to conduct bibliometric analysis of the relevant literature. The study results show that the research hotspots of hydrogen storage safety mainly concentrate on six aspects: the stability of metal hydride hydrogen storage materials, the study of thermal management and stress relief in metal hydride reactors, the safety analysis of hydrogen fuel cells and hydrogen leakage monitoring, the analysis of leakage and explosion risks in hydrogen refueling stations, the study of filling pressure and temperature distribution in hydrogen storage tanks, and the study of safety issues in underground hydrogen storage. Mg-based hydride stability and underground hydrogen storage risk analyses are current research frontiers in hydrogen storage safety. • This paper presents the development of hydrogen storage in safety research. • 1552 papers are visualized and analyzed using bibliometrics. • Identifying research frontiers by combining timeline view with burst detection. • Knowledge bases, research hotspots, and frontiers are discussed. • The current challenges and perspectives for the future are proposed. [ABSTRACT FROM AUTHOR]

Underground hydrogen storage (UHS) is considered to solve the intermittency problem of renewable energy. A geological assessment indicated that the B unit of the Salina Group in Southern Ontario, Canada, is the most promising for UHS because it is the thickest and most regionally extensive salt rock deposit. However, the comprehensive geological knowledge of potential sites and overall salt volume for UHS remains undiscovered. This paper collected 1112 wells' logging data to assess the geologic potential for UHS in Lambton County. The geological characteristic analysis of the B unit was conducted using high-frequency stratigraphic sequences and logging interpretation. The internal lithologies and thicknesses of the B unit were interpreted from 426 available wells. The storage capacity of the salt caverns was calculated from simplified cylinder models. The results indicate that the B unit can be subdivided into three high-frequency sequences, denoted as the SQ1, SQ2, and SQ3 subunits. SQ1 corresponds to salt–limestone, SQ2 corresponds to bedded salt rocks, and SQ3 corresponds to massive salt rocks. Well sections and thickness maps indicate that the study area can be divided into two sub-areas along the Wilikesport, Oil Spring, and Watford line. To the northwest, unit B was thicker and deeper in terms of paleo-water depth, and to the southeast, less of the B unit was deposited on the paleo-highs. The main thicknesses in SQ1, SQ2, and SQ3 range from 20 to 30 m, 25 to 35 m, and 30 to 40 m, respectively. In conclusion, the best subunit for UHS is SQ3, with a secondary target being SQ2. The main factor impacting cavern storage capacity for the SQ2 subunit is high mud content, while for SQ3, it is the meters-thick anhydrite developed towards the base of the unit. The available underground storage volume of the salt caverns in the B unit is 9.10 × 106 m3. At the standard state, the working gas volume is 557.80 × 106 m3. The favorable area for UHS is the western part surrounded by Wallaceburg, Oil Spring, and Watford. The thickness distribution of the B unit is the combined result of paleo-topography, sea-level changes, and tectonic movement in Lambton. The geological storage capacity of the salt caverns exhibits significant potential. [ABSTRACT FROM AUTHOR]

Aviation is a contributor to global warming. Hydrogen-powered aircraft are seen as an important option to decarbonise parts of commercial aviation. Airports have a pivotal role in facilitating the development of ground infrastructure. This paper provides a broader perspective on the supply and handling of liquid hydrogen, and necessary airport developments, to enable hydrogen-powered aviation. Hydrogen-related airport development projects at Rotterdam The Hague Airport (RTHA) are presented and discussed, and a detailed overview of the airport's liquid hydrogen (LH2) storage facility is given. To link the ongoing developments to future needs, a LH2 demand scenario for RTHA is determined for the years 2040 and 2050. Based on this demand, analysis of levelised cost of hydrogen for relevant value chains were conducted. This study exemplifies that the LH2 value chain for an airport depends on individual characteristics of the airport and its surroundings. The hydrogen demand, the airport's proximity to larger hydrogen hubs (import and/or production hubs) and the availability of local renewable resources, which influence electricity price and hydrogen production and liquefaction costs, are key parameters and heavily influence the airport LH2 value chain. Conceptualisation and future development of hydrogen infrastructure for airport supply should take into account the above factors. LH2 demand at RTHA in the year 2050 is predicted to range between 8–14kt. Under the given electricity price assumptions, local production and liquefaction of hydrogen at the airport is not seen as a viable option, as cost savings can be achieved by making use of the Port of Rotterdam's large hydrogen production and import cluster nearby. The work shows that trailer-based logistics for both the delivery of LH2 to the airport and subsequent usage of these trailers in the storage and dispensing process at the airport seems the most viable for RTHA (and airports that show similarities). This further indicates that current small-scale LH2 demonstration at airports provides important lessons for scaling up. [ABSTRACT FROM AUTHOR]

Liquid hydrogen is a promising energy carrier in the global hydrogen value chain with the advantages of high volumetric energy density/purity, low operating pressure, and high flexibility in delivery. Safe and high-efficiency storage and transportation are essential in the large-scale utilization of liquid hydrogen. Aiming at the two indicators of the hold time and normal evaporation rate (NER) required in standards, this paper focuses on the thermal behaviors of fluid during the no-vented storage of liquid hydrogen and thermal insulations applied for the liquid hydrogen tanks, respectively. After presenting an overview of experimental/theoretical investigations on thermal behaviors, as well as typical forms/testing methods of performance of thermal insulations for liquid hydrogen tanks, seven perspectives are proposed on the key challenges and recommendations for future work. This work can benefit the design and improvement of high-performance LH2 tanks. [ABSTRACT FROM AUTHOR]

The uncertainty of renewable energy undermines the competitiveness of Renewable Energy Generation Companies (REGC) in market bidding. Hydrogen energy storage, as a novel high-energy-density energy storage technology, is considered an ideal solution to address the uncertainty of renewable energy and provide flexible ramping products (FRP) to the grid. Building upon this, this paper combines hydrogen energy storage and renewable energy to build a hydrogen-wind-photovoltaic (HWP) system, and introduces HWP into the flexible ramping market for the first time, while participating in the energy market. To capture the interactions between HWP and market players with different utility functions, this paper establishes a bi-level bidding strategy model for HWP participation in the integrated energy and flexible ramping markets, It enables HWP to optimize its internal unit output to increase revenue based on current market conditions. In addition to this, the uncertainty of renewable energy output is taken into account in the upper-level model. Finally, the effectiveness of the proposed two-stage stochastic bi-level optimization scheduling model was validated on IEEE 6-bus and 36-bus transmission-constrained networks. Tests demonstrated that the proposed model effectively assists HWP in formulating optimal bidding strategies in the joint market under uncertainty. Compared to solely participating in a single energy market, HWP's simultaneous participation in energy and flexible ramping markets increased total revenue by 12.22%. • Utilizing hydrogen energy storage to provide Flexible Ramping Product (FRP). • Hydrogen-Wind-Photovoltaic (HWP) participates in energy and flexible ramping market. • Establishing a bi-level strategic bidding model for HWP. • Considering the influence of renewable energy uncertainty on bidding strategies. • The introduction of the FRP increased HWP's total revenue by 12.22%. [ABSTRACT FROM AUTHOR]

Efficient hydrogen storage and transportation are crucial for the sustainable development of human society. Ammonia, with a hydrogen storage density of up to 17.6 wt%, is considered an ideal energy carrier for large-scale hydrogen storage and has great potential for development and application in the "hydrogen economy". However, achieving ammonia decomposition to hydrogen under mild conditions is challenging, and therefore, the development of suitable catalysts is essential. Metal oxide-based catalysts are commonly used in the industry. This paper presents a comprehensive review of single and composite metal oxide catalysts for ammonia decomposition catalysis. The focus is on analyzing the conformational relationships and interactions between metal oxide carriers and active metal sites. The aim is to develop new and efficient metal oxide-based catalysts for large-scale green ammonia decomposition. [ABSTRACT FROM AUTHOR]

Heat transfer analysis for the compression hydrogen storage tank (CHST) during the charge–discharge cycle is necessary to ensure quick and safe refueling for fuel cell vehicles. In this paper, a dual‐zone dual‐temperature (DZDT) model for a CHST during the charge–discharge cycle process is established. The constant/variable mass flow rates and heat transfer coefficients (HTCs) are combined to form three methods. Method 1 uses constant mass flow rate and constant HTC. Method 2 uses variable mass flow rate and variable HTC calculated through the energy conservation equation. Method 3 uses variable mass flow rate and variable HTC calculated through the empirical equation. Then, these methods are applied to the DZDT model for heat transfer analysis in three cases. Research shows that for the charging process, the simulated hydrogen temperatures by Method 2 agree well with experiment data for three CHSTs. Method 1 has a maximum error of about 20°C for 19 L CHST, 15°C for 29 L CHST, and 25°C for 40 L CHST. The error of Method 3 is between Methods 1 and 2. The simulated hydrogen pressures by Methods 2 and 3 agree well with the experimental data, while Method 1 has a maximum error of about 5 MPa for 19 L CHST, 10 MPa for 29 L CHST, and 3 MPa for 40 L CHST. For the discharge process, the simulated hydrogen temperatures by Methods 2 and 3 have a relatively slight difference with the experimental data, while Method 1 has relatively significant differences for three CHSTs. Only slight differences exist between the simulated hydrogen pressures by Methods 1, 2, and 3 with the experimental data for three CHSTs. In short, Method 2 can simulate the hydrogen temperature and pressure well during the charge–discharge process. Method 3 can simulate the approximate hydrogen temperature and precise hydrogen pressure during the charge–discharge process. Method 1 can only simulate the hydrogen pressure during the discharging process. The conclusions of this article can inform researchers which analysis methods are more reasonable to choose in future hydrogen‐filling studies. [ABSTRACT FROM AUTHOR]

Multi-rotor drones, a kind of unmanned equipment which is widely used in the military, commercial consumption and other fields, have been developed very rapidly in recent years. However, their short flight time has hindered the expansion of their application range. This can be addressed by utilizing hydrogen fuel cells, which exhibit high energy density, strong adaptability to ambient temperature, and no pollution emissions, as the power source. Accordingly, the application of hydrogen fuel cells as the power source in multi-rotor drones is a promising technology that has attracted significant research attention. This paper summarizes the development process of hydrogen fuel cell multi-rotor drones and analyzes the key obstacles that need to be addressed for the further development of hydrogen fuel cell multi-rotor drones, including structural light weight, hydrogen storage methods, energy management strategies, thermal management, etc. Additionally, prospects for the future development of hydrogen fuel cell multi-rotor drones are presented. [ABSTRACT FROM AUTHOR]

In the current literature, there exists a lack of analysis regarding the coordination of the spinning reserve and time-shift characteristics of hydrogen storage systems (HSS) and flexible carbon capture systems (FCCS) in terms of low-carbon economic operation. They are presently used solely as a tool to capture carbon dioxide, without fully utilizing the advantages of their flexible operation. The coordination and complementarity of the FCCS and HSS can ensure stable power supply and improve renewable energy (RE) consumption. Combined with demand side response (DSR), these factors can maximize the RE consumption capacity, reduce carbon emissions, and improve revenue. In this paper, a source-storage-load flexible scheduling strategy is proposed by considering the complementary nature of FCCS and HSS in terms of rotating standby and time-shift characteristics. First, the operational mechanisms of FCCS, HSS, and demand side response (DSR) are analyzed, and their mathematical models are constructed to improve flexibility in grid operation and regulation. Next, deficiencies in FCCS and HSS operation under rotating reserve requirements are analyzed to design a coordinated operation framework for the FCCS and HSS. This operational framework aims to enable the complementarity of the rotating reserve and time-shift characteristics of FCCS and HSS. Finally, based on the carbon emission trading mechanism, a three-stage ladder carbon emission trading cost model is constructed, and a source-storage-load flexible scheduling strategy is established to achieve an effective balance between low carbon emissions and economic performance. The simulation results demonstrate that the strategy reduces the overall cost by 8.57%, reduces the carbon emissions by 35.33%, and improves the renewable energy consumption by 3.5% compared with the unoptimized scheme. [ABSTRACT FROM AUTHOR]

In this paper, compositions within the TiZrAlCrMn, TiZrAlCrFe, and TiZrAlMnFe alloy systems that form the C14 Laves phase are investigated. The design, synthesis, structural, and hydrogen storage characterizations for an equiatomic and a non‐equiatomic composition for each alloy system are presented. Additionally, the further development of a thermodynamic method for the calculation of pressure‐composition‐isotherms (PCIs) is presented of C14 Laves phase alloys that absorb hydrogen by solid solution. Overall, the results shown in this paper indicate that Al‐containing multicomponent alloys can present promising hydrogen storage performance under high pressures. Nonetheless, high concentrations of aluminum in highly concentrated (equiatomic) alloys can have a negative impact on the hydrogenation properties. The Ti0.29Zr0.05Al0.05Cr0.26Mn0.35 composition showed promising hydrogenation/dehydrogenation properties. The gravimetric capacity of this alloy is ≈1.76 wt.% H2 and the PCIs measured indicate that this material has potential for high‐pressure hydrogen storage and compression applications. The use of the presented thermodynamic model for the design of multicomponent alloys is suggested. [ABSTRACT FROM AUTHOR]

Fuel cell vehicles are considered as the direct alternative to fuel vehicles due to their similar driving range and refueling time. The United Nations World Forum for Harmonization of Vehicle Regulations (UN/WP29) released the Global Technical Regulation on Hydrogen and Fuel Cell Vehicles (GTR13) in July 2013, which was the first international regulation in the field of fuel cell vehicles. There exist some differences between GTR13 and the existing safety technical specifications and standards in China. This paper studied the safety requirements of the GTR13 compressed hydrogen storage system, analyzed the current hydrogen storage safety standards for fuel cell vehicles in China, and integrated the advantages of GTR13 to propose relevant suggestions for future revision of hydrogen storage standards for fuel cell vehicle in China. [ABSTRACT FROM AUTHOR]

Combining electrolytic hydrogen production with wind–photovoltaic power can effectively smooth the fluctuation of power and enhance the schedulable wind–photovoltaic power, which provides an effective solution to solve the problem of wind–photovoltaic power accommodation. In this paper, the optimization operation strategy is studied for the wind–photovoltaic power-based hydrogen production system. Firstly, to make up for the deficiency of the existing research on the multi-state and nonlinear characteristics of electrolyzers, the three-state and power-current nonlinear characteristics of the electrolyzer cell are modeled. The model reflects the difference between the cold and hot starting time of the electrolyzer, and the linear decoupling model is easy to apply in the optimization model. On this basis, considering the operation constraints of the electrolyzer, hydrogen storage tank, battery, and other equipment, the optimization operation model of the wind–photovoltaic power-based hydrogen production system is developed based on the typical scenario approach. It also considers the cold and hot starting time of the electrolyzer with the daily operation cost as the goal. The results show that the operational benefits of the system can be improved through the proposed strategy. The hydrogen storage tank capacity will have an impact on the operation income of the wind–solar hydrogen coupling system, and the daily operation income will increase by 0.32% for every 10% (300 kg) increase in the hydrogen storage tank capacity. [ABSTRACT FROM AUTHOR]

Developing advanced hydrogen storage materials with high capacity and efficient reversibility is a crucial aspect for utilizing hydrogen source as a promising alternate to fossil fuels. In this paper, we have systematically investigated the hydrogen storage properties of neutral and negatively charged C9N4 monolayer based on density functional theory (DFT). Our foundings indicate that injecting additional electrons into the adsorbent significantly boosts the adsorption capacity of C9N4 monolayer to H2 molecules. The gravimetric density of negatively charged C9N4 monolayer can reach up to 10.80 wt% when fully covered with hydrogen. Unlike other hydrogen storage methods, the storage and release processes happen automatically upon introducing or removing extra electrons. Moreover, these operations can be easily adjusted through activating or deactivating the charging voltage. As a result, the method is easily reversible and has tunable kinetics without requiring particular activators. Significantly, C9N4 is proved to be a suitable candidate for efficient electron injection/release due to its well electrical conductivity. Our work can serve as a valuable guide in the quest for a novel category of materials for hydrogen storage with high capacity. [ABSTRACT FROM AUTHOR]

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To achieve a more ecologically friendly energy transition by the year 2050 under the European "green" accord, hydrogen has recently gained significant scientific interest due to its efficiency as an energy carrier. This paper focuses on large-scale hydrogen production systems based on marine renewable-energy-based wind turbines and tidal turbines. The paper reviews the different technologies of hydrogen production using water electrolyzers, energy storage unit base hydrogen vectors, and fuel cells (FC). The focus is on large-scale hydrogen production systems using marine renewable energies. This study compares electrolyzers, energy storage units, and FC technologies, with the main factors considered being cost, sustainability, and efficiency. Furthermore, a review of aging models of electrolyzers and FCs based on electrical circuit models is drawn from the literature and presented, including characterization methods of the model components and the parameters extraction methods, using a dynamic current profile. In addition, industrial projects for producing hydrogen from renewable energies that have already been completed or are now in progress are examined. The paper is concluded through a summary of recent hydrogen production and energy storage advances, as well as some applications. Perspectives on enhancing the sustainability and efficiency of hydrogen production systems are also proposed and discussed. This paper provides a review of behavioral aging models of electrolyzers and FCs when integrated into hydrogen production systems, as this is crucial for their successful deployment in an ever-changing energy context. We also review the EU's potential for renewable energy analysis. In summary, this study provides valuable information for research and industry stakeholders aiming to promote a sustainable and environmentally friendly energy transition. [ABSTRACT FROM AUTHOR]

The escalating demand for renewable energy solutions and the imperative for efficient energy storage mechanisms have catalyzed the evolution of Power-to-X (PtX) technologies. Germany has the most PtX projects, accounting for 44% of all projects that have been reported. PtX encompasses a spectrum of processes engineered to convert surplus renewable energy into versatile energy carriers or chemical commodities, such as hydrogen, methane, or synthetic fuels. The Paramount to this domain is to synergistically harness renewable energy sources and hydrogen carriers to curtail waste and bolster sustainability. Central to achieving this synergy is the effective control of PtX processes, ensuring optimal performance, cost efficiency, and seamless integration within existing energy frameworks. This paper delves into the control processes and environmental prerequisites within the PtX landscape, elucidating key challenges, and strategies within this dynamic realm. While providing an initial overview of fundamental PtX process chains, this paper accentuates the critical role of geographical considerations. Subsequently, it conducts a thorough analysis of equipment modeling challenges, addressing performance metrics, operational requisites, and capital investments, particularly focusing on methanol and hydrogen production and storage. Through holistic examination, this paper endeavors to delineate the evolving landscape of PtX control processes and conditions, advancing our understanding of this expanding field. [Display omitted] • Comprehensive overview of PtX control process, challenges, strategies, and advancements. • Overview of PtX process chains and geographical conditions. • Analysis of equipment modeling challenges for methanol and hydrogen. • Addressing crucial storage challenges in PtX system. • Exploration of diverse influences on PtX control processes. [ABSTRACT FROM AUTHOR]

Owing to the massive expansion and intermittent nature of renewable power, green hydrogen production, storage, and transportation technologies with improved economic returns need to be developed. Moreover, the slowness of the dehydrogenation reaction is a primary barrier to the commercialization of liquid organic hydrogen carrier (LOHC) technology. The present study focused on increasing the speed of dehydrogenation, resulting in the proposal of a triple-loop dehydrogenation system comprising reaction, heating, and chilling loops. The reactor has a rotating cage containing a packed bed of catalyst pellets, which is designed to enhance both heat and mass transfer by helping to detach precipitated hydrogen bubbles from the catalyst surface. In addition, the centrifugal force aids in isolating the gas phase from the LOHC liquid. A dehydrogenation experiment was conducted using the reaction and chilling loops, which revealed that the average hydrogen production rate during the first hour was 52.6 LPM (liter per minute) from 26.3 L of perhydro-dibenzyl-toluene with 1.5 kg of 0.5 wt% Pt/Al2O3 catalyst. This was approximately 48% more than the value predicted with the reaction kinetics measured with a small-scale plug flow dehydrogenation reactor with less than 1.0 g of 5.0 wt% Pt/Al2O3 catalyst. The concept, construction methods, and results of the preliminary gas infiltration, flow visualization, and reactor pumping experiments are also described in this paper. [ABSTRACT FROM AUTHOR]

In the past, hydrogen was mostly produced from fossil fuels, causing a certain degree of energy and environmental problems. With the development of low-carbon energy systems, renewable energy hydrogen production technology has developed rapidly and become one of the focuses of research in recent years. However, the existing work is still limited by small-scale hydrogen production systems, and there is a lack of comprehensive research on the whole production-storage-transportation-utilization hydrogen system (PSTUH2S), especially on the modeling of different hydrogen transportation modes and various hydrogen loads in different fields. To make up for these deficiencies, the specific physical and mathematical models of the PSTUH2S are firstly described in this paper, with a full account of large-scale water-electrolytic hydrogen production from renewable power curtailment and grid power, various hydrogen storage and transportation modes, and multi-field hydrogen consumption paths. Furthermore, to achieve the maximum economic, energy, and environmental benefits from the PSTUH2S, a multi-objective nonlinear optimization model is also presented herein and then solved by the hybrid method combining the nonlinear processing method, the CPLEX solver and the piecewise time series production simulation method. Lastly, case studies are conducted against the background of a region in northwest China, where hydrogen consumption capacity in various years is accurately assessed and the potential advantages of the PSTUH2S are demonstrated. As the simulation results show, the power curtailment of renewable energy generation can be reduced by 3.61/11.87/14.72 billion kW·h in 2025/2030/2035, respectively, thus contributing to a 4.98%~10.09% increase in the renewable energy consumption rate and millions of tons of carbon emission reduction in these years. In terms of the total equivalent economic benefits, the proposed method is able to bring about a cost saving of USD 190.44 million, USD 634.66 million, and USD 865.87 million for 2025, 2030, and 2035, respectively. [ABSTRACT FROM AUTHOR]

Transitioning to a sustainable energy future necessitates innovative storage solutions for renewable energies, where hydrogen (H₂) emerges as a pivotal energy carrier for its low emission potential. This paper explores unlined rock caverns (URCs) as a promising alternative for underground hydrogen storage (UHS), overcoming the geographical and technical limitations of UHS methods like salt rock caverns and porous media. Drawing from the experiences of natural gas (NG) and compressed air energy storage (CAES) in URCs, we explore the viability of URCs for storing hydrogen at gigawatt-hour scales (>100 GWh). Despite challenges such as potential uplift failures (at a depth of approximately less than 1000 m) and hydrogen reactivity with storage materials at typical conditions (below temperatures of 100°C and pressures of 15 MPa), URCs present a flexible, scalable option closely allied with green hydrogen production from renewable sources. Our comprehensive review identifies critical design considerations, including hydraulic containment and the integrity of fracture sealing materials under UHS conditions. Addressing identified knowledge gaps, particularly around the design of hydraulic containment systems and the interaction of hydrogen with cavern materials, will be crucial for advancing URC technology. The paper underscores the need for further experimental and numerical studies to refine URC suitability for hydrogen storage, highlighting the role of URCs in enhancing the compatibility of renewable energy sources with the grid. • Detailed exploration of unlined rock cavern (URC) technology. • Analysis of URCs' potential for large-scale hydrogen storage. • Insights from historical use of URCs in compressed gas storage. • Examination of the opportunities and challenges in using URCs for hydrogen storage. [ABSTRACT FROM AUTHOR]

This paper addresses the micro wind-hydrogen coupled system, aiming to improve the power tracking capability of micro wind farms, the regulation capability of hydrogen storage systems, and to mitigate the volatility of wind power generation. A predictive control strategy for the micro wind-hydrogen coupled system is proposed based on the ultra-short-term wind power prediction, the hydrogen storage state division interval, and the daily scheduled output of wind power generation. The control strategy maximizes the power tracking capability, the regulation capability of the hydrogen storage system, and the fluctuation of the joint output of the wind-hydrogen coupled system as the objective functions, and adaptively optimizes the control coefficients of the hydrogen storage interval and the output parameters of the system by the combined sigmoid function and particle swarm algorithm (sigmoid-PSO). Compared with the real-time control strategy, the proposed predictive control strategy can significantly improve the output tracking capability of the wind-hydrogen coupling system, minimize the gap between the actual output and the predicted output, significantly enhance the regulation capability of the hydrogen storage system, and mitigate the power output fluctuation of the wind-hydrogen integrated system, which has a broad practical application prospect. [ABSTRACT FROM AUTHOR]

Due to the increasing energy consumption and the promoting of the carbon neutral target, the exploitation of shale oil and gas, as well as carbon dioxide sequestration and hydrogen storage using shale as caprock, has received enormous attention. As a foundation for these hotspots, the characterization of pore structure in shale reservoirs has been widely studied. In this paper, the application of fluid intrusion and radiation methods in the characterization of pore structure in shale reservoirs was systematically reviewed, and the merits and limitations of both methods were highlighted. Taking the Fengcheng shale as an example, a detailed investigation of the fluid occurrence state was conducted, indicating that the fluid occurrence state significantly impacts the exploitation of hydrocarbon from shale reservoirs. Furthermore, there needs to be a systematic of investigation of how the pore structure characteristics and inorganic components of shale reservoirs control the integrity and safety of CO2 and H2 storage. Moreover, confinement effect of nanopores in shale should be paid attention to in future research on carbon and hydrogen storage. [ABSTRACT FROM AUTHOR]

Although several studies have been performed on energy systems, there is a gap in examining the impact of energy storage systems (ESSs) technologies on the technoeconomic design of optimal multicarrier microgrids (MCMGs), considering environmental concerns. This paper aims to address this research gap by developing an optimal technoeconomic reliability‐oriented design of MCMGs, specifically focusing on battery storage systems (BSSs) and hydrogen storage systems (HSSs). The study was applied to MCMG at an actual MCMG, using HOMER Pro software. Additionally, a reliability‐oriented sensitivity analysis is conducted to understand the effects of reliability constraints, such as desired maximum capacity shortage, on the performance of various ESS technologies. One of the main contributions is analyzing the HSS and BSS from different viewpoints, such as cost, emission, and other technical–economic features for MCMGs. The comparative test results show that if a highly reliable MCMG is desired, the BSS‐based MCMG is the more practical option in terms of technoeconomic indices. However, regardless of reliability constraints, the HSS‐based MCMGs offer better environmental conditions. The total net present cost of the HSS‐based MCMG is 1.68% higher than the BSS‐based one, while it has 17.99% less CO2 emissions, while the HSS one has 17.99% less CO2 emissions. [ABSTRACT FROM AUTHOR]

The storage and transportation of gas hydrogen in a large scale is the bottleneck of hydrogen economy at present, and using liquid organic hydrogen carrier (LOHC) may be a hopefully competitive technique for hydrogen storage. This paper aims at a deep understanding of the hydrogenation kinetics of dibenzyltoluene (DBT) as the LOHC using Ru/Al2O3 as the hydrogenation catalyst. The original data for establishing the kinetic model of the hydrogenation of DBT was collected by analyzing the effects of reaction temperature, pressure, catalyst dosage and process parameters on the mass transfer reaction process. The results show that the initial apparent reaction kinetics was a first-order reaction. The main reaction resistance was the internal diffusion process and reaction resistance on the surface of catalyst solid particles, and could be mainly contributed by the internal diffusion in the catalyst pores. This has important guiding significance for reaction optimization and catalyst design in industrial production. [ABSTRACT FROM AUTHOR]

Despite hydrogen being an attractive energy source, there are two challenges to overcome in its use: hydrogen storage and the use of catalysts to optimize its conversion into energy. N-doped carbons are considered promising candidates for hydrogen storage and catalysis. This paper reports a fast and controllable strategy for obtaining porous N-doped carbons with a monolith-type morphology, high surface area, and hierarchical porosity. The presence of nitrogen increases the electron donor and wettability of carbons, making them favorable for use in hydrogen adsorption and electrodes. The method is based on using aniline as a carbon source and polymerizing it in a Pluronic F127 micellar system before carbonization. It is shown that the pore size and pore volume of porous carbon can be effectively tuned by using tetraethyl orthosilicate (TEOS). The relationship between aniline polymerization conditions, surface chemistry, and porous carbon properties has been investigated. Polyaniline permitted a high conversion to carbon (43.5–98.1%) and a nitrogen content of 5% wt in the N-doped carbon. In addition to the well-developed porosity and interesting monolithic morphology, electrochemical characterization showed that increasing the temperature of carbon synthesis improved the electroactive performance due to higher graphitization. In our previous study on hydrogen diffusion, we observed higher rates in our material compared to other carbon materials. This enhanced performance can be attributed to the effective combination of doping and hierarchical porosity, facilitating improved charge transfer and establishing favorable diffusion pathways. Thus, we demonstrate that pore size and surface area impact the electrochemical properties and hydrogen diffusion in this type of carbon. [ABSTRACT FROM AUTHOR]

Copyright of Przegląd Elektrotechniczny is the property of Przeglad Elektrotechniczny and its content may not be copied or emailed to multiple sites or posted to a listserv without the copyright holder's express written permission. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)

Hydrogen emerges as a promising alternative energy source, particularly in fuel cell applications, necessitating efficient and safe charging and storage systems. This paper presents the design and development of a specialized regulator tailored for high-pressure hydrogen environments. Focusing on precision control, the regulator ensures optimal performance and safety during charging and storage phases. In order to improve the unstable response characteristics of the existing commercial hydrogen regulator, which has the same differential pressure generation site and pressure control site, a regulator operating at an ultra-high pressure of 105 MPa was designed by separating the differential pressure site and the control site. And structural safety and performance of the regulator were predicted through structural and flow analysis. The results of structural and flow analysis of a 105 MPa high-pressure regulator that can be used for high-pressure hydrogen charging and storage systems were compared with the experimentally measured values. [ABSTRACT FROM AUTHOR]

The paper is devoted to the development of a device for protecting facilities with turn-to-turn insulation, namely transformers and wind generators in order to increase the reliability of operation of electrical power systems, renewable energy installations and energy storage systems. The paper presents the results of experimental studies of the parameters of a prototype frequency-dependent device, as well as an assessment of the effectiveness of suppression of high-frequency surge voltages by the proposed device. The results of four groups of measurements are shown, which were compared with each other and with the results of previously showed computer simulations. The high efficiency of the proposed device when influencing the slope and amplitude of short high-frequency transients is shown. It is indicated that the parameters proposed earlier in the simulation allow the device to be used effectively. A brief analysis of alternative methods and means of protection is provided, and the prospects for using the device as protective equipment for wind power plants are also considered. [ABSTRACT FROM AUTHOR]

Global warming increases the risk of power outages. Mine water pumping stations pump approximately 100 million m3 of water per year (2023). The cessation of mine water pumping would expose neighboring mines and lower lying areas to flooding. The pumping stations have some containment, but a prolonged shutdown could cause environmental problems. Remediation of the resulting damage would be costly and time-consuming. The combination of the problems of dewatering abandoned mines and storing energy in the form of hydrogen to ensure continuity of power supply to pumping stations has not been the subject of extensive scientific research. The purpose of this paper was to develop options for protecting mine water pumping stations against the "blackout" phenomenon and to assess their investment relevance. Six technically feasible options for the modernization of mine water pumping stations were designed and analyzed in the study. All pumping station modernization options include storage of the generated energy in the form of green hydrogen. For Q1 2024 conditions, the option with the partial retail sale of the produced hydrogen and the increased volume of produced water for treatment is recommended for implementation. [ABSTRACT FROM AUTHOR]

Concerning the emerging power-to-gas technologies, which are considered the most promising technology for seasonal renewable energy storage, Underground Hydrogen Storage (UHS) has gained attention in the last few years. For safe and efficient storage, possible hydrogen losses due to dissolution into the aquifer must be estimated accurately. Due to safety concerns, experimental measurements of hydrogen solubility in brine at reservoir conditions are limited. In this study, a PVT cell is used to characterize the solubility of hydrogen and its mixtures with methane in saline water/brine. The experiments were carried out at 45, 50, and 55°C and from 1 bar up to 500 bar, mimicking a significant range of possible reservoir conditions. Two brine samples representative of two different reservoirs were tested. Two mixtures of methane and hydrogen (10 mol% H2 and 50 mol% H2, respectively) were considered, along with pure hydrogen, to account for the presence of methane in the primary phase of hydrogen storage in a depleted gas reservoir. In the current paper, a comparison of the experimental results with literature models is provided. At the experiment conditions, the impact of the differences in the composition of the two analyzed brines as well as the impact of the analyzed range of temperatures was not significant. Conversely, a non-negligible variation in terms of the slope of the solubility curve was observed as a function of the gas mixture composition: the curve increased more steeply as the percentage of hydrogen reduced. [ABSTRACT FROM AUTHOR]

In the paper, the maiden application of Tilted Integral Fractional Derivative with Filter plus Fractional Derivative controller (TIDμ1NDμ2$TI{D^{{\mu _1}}}N{D^{{\mu _2}}}$), called TIFDNFD controller, is proposed to achieve load frequency control (LFC) of two area‐multi source power system. In the study, both areas include thermal power, hydropower, and gas turbine power systems. In this study, generation rate constraint and governor dead‐band are integrated into the power system to evaluate the performance of the controller in a non‐linear environment. The wild horse optimizer (WHO) is used for controller parameter tuning in the LFC problem for the first time. The performance of the proposed controller is demonstrated by comparing it with the recently published studies including different controllers. In this study, to obtain more realistic results, solar photovoltaic (PV) power, wind power, and load demand with stochastic form have been added to the power system. In addition, the dynamic effect of the hydrogen storage system, consisting of an electrolyser and a fuel cell, is considered a grid supporter. The superiority of the WHO algorithm in optimization has been verified by comparing it with three optimization algorithms recently proposed. Finally, the resilience and robustness of the power system are evaluated in perturbed system parameters. [ABSTRACT FROM AUTHOR]

Carbon nanotubes (CNTs) have a wide range of applications in many fields, such as electronic devices, composites, sensors, catalysts, hydrogen storage materials, biomedicine, and energy, due to their unique structure and excellent physicochemical properties. As new composite materials require more and more precise control of carbon nanotube growth, the traditional research on carbon nanotube growth mechanism and growth parameter mechanism is difficult to meet the demand for precise control of carbon nanotube growth under complex conditions such as in-situ growth on the surface of composite materials. Given, Because of, it has become one of the hotspots to explore the growth mechanism of CNTs on the microscopic scale by high-end characterization tests and simulations under complex conditions, and then precisely regulate the growth of CNTs. This paper summarizes the latest research progress on the growth mechanism, preparation, and application of CNTs in recent years, and focuses on the research progress on the latest application of CNTs in different fields of high-end materials, especially in the control of carbon nanotube growth by intelligent algorithms and other aspects of the proposed new understanding. [ABSTRACT FROM AUTHOR]

In this paper, high-temperature storage of hydrogen-treated AlGaN/GaN HEMTs is conducted for the first time to study the effect of high temperature on the electrical characteristics of the devices after hydrogen treatment, and it is found that high-temperature storage can effectively reduce the impact of hydrogen on the devices. After hydrogen treatment, the output current and the maximum transconductance of the device increase, and the threshold voltage drifts negatively. However, after high-temperature treatment at 200 °C for 24 h, the output current, threshold voltage, and the maximum transconductance of the device all approach their initial values before hydrogen treatment. By using low-frequency noise analysis technology, the trap density of the hydrogen-treated AlGaN/GaN HEMT is determined to be 8.9 × 1023 cm−3·eV−1, while it changes to 4.46 × 1022 cm−3·eV−1 after high-temperature storage. We believe that the change in the electrical characteristics of the device in hydrogen is due to the passivation of hydrogen on the inherent trap of the device, and the variation in the electrical properties of the device in the process of high-temperature storage involves the influence of two effects, namely the dehydrogenation effect and the improvement of the metal–semiconductor interface caused by high temperatures. [ABSTRACT FROM AUTHOR]

This article explores the main mechanisms that can generate damage in polymers and polymer-based materials used for hydrogen storage and distribution infrastructures. All of these mechanisms are driven by the permeability process that is enhanced by the operating temperature and pressure conditions. Hydrogen storage and delivery systems typically work under high pressure and a relatively wide range of temperatures, especially during the filling and emptying processes. Therefore, it is of great interest to better understand how this phenomenon can influence the integrity of polymer-based hydrogen infrastructures in order to avoid catastrophic events and to better design/investigate new optimized solutions. The first part of this paper discusses the main storage and delivery solutions for gas and liquid hydrogen. Then, the physics of the permeability is investigated with a focus on the effect of pressure and temperature on the integrity of polymers working in a hydrogen environment. Finally, the main mechanisms that mostly induce damage in polymers operating in a hydrogen environment and that influence their mechanical properties are explored and discussed. Particular focus was placed on the rapid gas decompression and aging phenomena. In addition, some of the limits that still exist for a reliable design of polymer-based storage and delivery systems for hydrogen are pointed out. [ABSTRACT FROM AUTHOR]

With their rich surface chemistry, high electrical conductivity, variable bandgap, and thermal stability, 2D materials have been developed for effective electrochemical energy conversion systems over the past decade. Due to the diversity brought about by the use of transition metals and C/N pairings, the 2D material MXene has found excellent applications in many fields. Among the various applications, many breakthroughs have been made in electrocatalytic applications. Nevertheless, related studies on topics such as the factors affecting the material properties and safer and greener preparation methods have not been reported in detail. Therefore, in this paper, we review the relevant preparation methods of MXene and the safer, more environmentally friendly preparation techniques in detail, and summarize the progress of research on MXene-based materials as highly efficient electrocatalysts in the electrocatalytic field of hydrogen precipitation reaction, nitrogen reduction reaction, oxygen precipitation reaction, oxygen reduction reaction, and carbon dioxide reduction reaction. We also discuss the technology related to MXene materials for hydrogen storage. The main challenges and opportunities for MXene-based materials, which constitute a platform for next-generation electrocatalysis in basic research and practical applications, are highlighted. This paper aims to promote the further development of MXenes and related materials for electrocatalytic applications. [ABSTRACT FROM AUTHOR]

As the need for clean and sustainable energy sources grows rapidly, green hydrogen and ammonia have become promising sources of low-carbon energy and important key players in the transition to green energy. However, production and storage problems make it hard to use them widely. The goal of this review paper is to give a complete overview of the latest technology for the manufacture and storage of hydrogen and ammonia. This paper deals with hydrogen and ammonia synthesis and storage. It examines the most recent technological breakthroughs in areas such as electrolysis, reforming, C-ZEROS, HYSATA, DAE, sulfide, and SRBW, as well as novel storage techniques, such as solid-state storage, plasma kinetics, and POWERPASTE. This article examines the history of ammonia production and discusses some of the newer and more sustainable techniques for producing ammonia, such as electrochemical and biological approaches. This study also looks at how artificial intelligence (AI) and additive manufacturing (AM) could be used to revolutionize the way green hydrogen and ammonia are produced, with an emphasis on recent breakthroughs in AI-assisted catalyst design and 3D-printed reactors, as well as considering major investments in the shift to green energy, such as Moroccan government programs, and how they may affect future hydrogen and ammonia production. [ABSTRACT FROM AUTHOR]

Type IV hydrogen storage cylinders comprise a polymer liner and offer advantages such as lightweight construction, high hydrogen storage density, and good fatigue performance. However, they are also characterized by higher hydrogen permeability. Consequently, it is crucial for the polymer liner material to exhibit excellent resistance to hydrogen permeation. International organizations have established relevant standards mandating hydrogen permeation tests for the liner material of type IV on-board hydrogen storage cylinders. This paper provides a comprehensive review of existing research on hydrogen permeability and the hydrogen permeation test methods for the polymer liner material of type IV on-board hydrogen storage cylinders. By delving into the hydrogen permeation mechanism, a better understanding can be gained, offering valuable references for subsequent researchers in this field. This paper starts by thoroughly discussing the hydrogen permeation mechanism of the liner material. It then proceeds to compare and analyze the hydrogen permeation test methods specified by various standards. These comparisons encompass sample preparation, sample pretreatment, test device, test temperature and pressure, and qualification indicators. Then, this study offers recommendations aimed at enhancing the hydrogen permeation test method for the liner material. Additionally, the influence of test temperature, test pressure, and polymer material properties on the hydrogen permeability of the liner material is discussed. Finally, the influences of the test temperature, test pressure, and polymer material properties on the hydrogen permeability of the liner material are discussed. Future research direction on the hydrogen permeability and hydrogen permeation test method of the liner material of the type IV hydrogen storage cylinder has been prospected. [ABSTRACT FROM AUTHOR]

In contemporary times, the utilization of liquid organic hydrogen carriers (LOHCs) has gained prominence due to their high volumetric storage density and material properties closely resembling conventional fuels. Numerous countries are incorporating LOHCs in hydrogen demonstration initiatives, encompassing applications such as hydrogen refueling stations, hydrogen-powered ships, and trains. This paper conducts a comprehensive review of seventeen LOHC projects, spanning Germany, Europe, and other nations, presenting detailed project specifications. This review includes information on project consortiums, funding sources, covered supply chains, transport modalities, and employed technologies. Through a global evaluation of LOHC projects, this review underscores the promising and competitive nature of LOHCs as a viable option for the large-scale and long-distance storage and transportation of hydrogen. The future development of this field is discussed at in the last section. [ABSTRACT FROM AUTHOR]

This paper proposes a two-level control strategy based on a super-twisting sliding-mode algorithm (STA) to optimally allocate power imbalances in shipboard microgrids (SMGs) while achieving frequency regulation. The strategy employs an STA observer to estimate the unknown power load demand imbalances in finite time. This estimate is then passed to an online high-level optimal control framework to periodically determine the optimal sequence of power reference values for each energy storage device (ESS), minimising the operational cost of the SMG. The online optimised power reference values are interpolated and passed to the low-level STA control strategy to control the output power of each ESS. The efficacy of the proposed methods is demonstrated through numerical simulations conducted on a prototypical model of an SMG equipped with two ESSs, namely batteries and fuel cells with associated hydrogen storage. [ABSTRACT FROM AUTHOR]

Hydrogen is the new age alternative energy source to combat energy demand and climate change. Storage of hydrogen is vital for a nation's growth. Works of literature provide different methods for storing the produced hydrogen, and the rational selection of a viable method is crucial for promoting sustainability and green practices. Typically, hydrogen storage is associated with diverse sustainable and circular economy (SCE) criteria. As a result, the authors consider the situation a multi-criteria decision-making (MCDM) problem. Studies infer that previous models for hydrogen storage method (HSM) selection (i) do not consider preferences in the natural language form; (ii) weights of experts are not methodically determined; (iii) hesitation of experts during criteria weight assessment is not effectively explored; and (iv) three-stage solution of a suitable selection of HSM is unexplored. Driven by these gaps, in this paper, authors put forward a new integrated framework, which considers double hierarchy linguistic information for rating, criteria importance through inter-criteria correlation (CRITIC) for expert weight calculation, evidence-based Bayesian method for criteria weight estimation, and combined compromise solution (CoCoSo) for ranking HSMs. The applicability of the developed framework is testified by using a case example of HSM selection in India. Sensitivity and comparative analysis reveal the merits and limitations of the developed framework. [ABSTRACT FROM AUTHOR]

The climate emergency has prompted rapid and intensive research into sustainable, reliable, and affordable energy alternatives. Offshore wind has developed and exceeded all expectations over the last 2 decades and is now a central pillar of the UK and other international strategies to decarbonise energy systems. As the dependence on variable renewable energy resources increases, so does the importance of the necessity to develop energy storage and nonelectric energy vectors to ensure a resilient whole-energy system, also enabling difficult-to-decarbonise applications, e.g. heavy industry, heat, and certain areas of transport. Offshore wind and marine renewables have enormous potential that can never be completely utilised by the electricity system, and so green hydrogen has become a topic of increasing interest. Although numerous offshore and marine technologies are possible, the most appropriate combinations of power generation, materials and supporting structures, electrolysers, and support infrastructure and equipment depend on a wide range of factors, including the potential to maximise the use of local resources. This paper presents a critical review of contemporary offshore engineering tools and methodologies developed over many years for upstream oil and gas (O&G), maritime, and more recently offshore wind and renewable energy applications and examines how these along with recent developments in modelling and digitalisation might provide a platform to optimise green hydrogen offshore infrastructure. The key drivers and characteristics of future offshore green hydrogen systems are considered, and a SWOT (strength, weakness, opportunity, and threat) analysis is provided to aid the discussion of the challenges and opportunities for the offshore green hydrogen production sector. [ABSTRACT FROM AUTHOR]

The overuse of fossil fuels has caused a serious energy crisis and environmental pollution. Due to these challenges, the search for alternative energy sources that can replace fossil fuels is necessary. Hydrogen is a widely acknowledged future energy carrier because of its nonpolluting properties and high energy density. To realize a hydrogen economy in the future, it is essential to construct a comprehensive hydrogen supply chain that can make hydrogen a key energy carrier. This paper reviews the various technologies involved in the hydrogen supply chain, encompassing hydrogen production, storage, transportation, and utilization technologies. Then, the challenges of constructing a hydrogen supply chain are discussed from techno-economic, social, and policy perspectives, and prospects for the future development of a hydrogen supply chain are presented in light of these challenges. [ABSTRACT FROM AUTHOR]

Hydrogen storage is a crucial factor that limits the development of hydrogen energy. This paper proposes using a split liner for the inner structure of a hydrogen storage cylinder. A self-tightening seal is employed to address the sealing problem between the head and the barrel. The feasibility of this structure is demonstrated through hydraulic pressure experiments. The influence laws of the O-ring compression rate, the distance from the straight edge section of the head to the sealing groove, and the thickness of the head on the sealing performance of gas cylinders in this sealing structure are revealed using finite elements analysis. The results show that when the gas cylinder is subjected to medium internal pressure, the maximum contact stress on the O-ring extrusion deformation sealing surface is greater than the medium pressure. There is sufficient contact width, that is, the arc length of the part where the stress on the O-ring contact surface is greater than the medium pressure, so that it can form a good sealing condition. At the same time, increasing the compression ratio of the O-ring and the head's thickness will help improve the sealing performance, and reducing the distance from the straight edge section of the head to the sealing groove will also improve the sealing performance. [ABSTRACT FROM AUTHOR]

In order to meet the hydrogen refueling demand of fuel cell vehicles and reduce the cost of HRS operation process, it is necessary to study the hydrogen refueling process of cascade hydrogen storage system of hydrogen refueling station. In this paper, a thermodynamic model of the hydrogen refueling process for fuel cell vehicles is established, and the effect of the variation of these thermodynamic parameters on the specific energy consumption and utilization rate of the hydrogen refueling process is investigated in terms of the pressure ratio and capacity of the hydrogen storage tank, which is the core of the hydrogen refueling station, consisting of multiple hydrogen storage tanks. The results show that the specific energy consumption and hydrogen utilization of the hydrogen refueling station decreases as the ratio of the nominal pressure of the medium-pressure stage to the nominal pressure of the high-pressure stage increases over the course of the pressure ratio change. In addition, the capacity variation is only slightly changed as a result of the pressure ratio variation. Therefore, the lowest ratio of specific energy consumption can be found by fixing the utilization rate and by changing the pressure ratio. For example, in this paper, if the total mass of hydrogen in the station is 600 kg and the hydrogen utilization rate is required to be not less than 12 %, the optimal pressures for each level are 50.2 MPa, 65 MPa and 86.7 MPa. • A thermodynamic model of the hydrogen filling process for fuel cell vehicles is established. • The pressure ratio and capacity of cascade hydrogen storage systems were analyzed. • Specific energy consumption and hydrogen utilization are used as evaluation indicators. • The optimal pressures for each level are 50.2 MPa, 65 MPa and 86.7 MPa. [ABSTRACT FROM AUTHOR]