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High frequency monitoring of water quality and stable isotopes quantify large hydrological and geochemical differences across a rural to urban land use gradient that includes three watersheds and two of their subbasins. Following precipitation events, floods on a rural stream feature hydrographs with low peak discharges and long lag times, high baseflow contributions, and small geochemical variations. In contrast, the flows of an urban stream and its tributary respond in a flashy manner, with average lag times decreasing by at least 55% compared to the rural stream. We also observed that baseflow contributions during floods decreased by an average of 40% in the urban streams. Importantly, we find that reduced baseflow as a function of increasing impervious surface area is not a linear trend among the streams, and suburban streams are less impacted than would be predicted by impervious surface area alone. The urban streams also exhibit large variations in water quality parameters during flooding events, often with five times the variability of the rural end-member. These differences are observed among all physical and geochemical characteristics that were monitored, including flow magnitude, stable isotope ratios, temperature, dissolved oxygen (DO), pH, turbidity, specific conductivity, concentrations of Cl − and nutrients, and bacterial loads. The great variability of urban streams following storms is paralleled by their larger diurnal and seasonal oscillations. Collectively, the extreme variations in the physical and geochemical character of urban streams have negative consequences to environmental quality and aquatic life. [ABSTRACT FROM AUTHOR]

Data from the 1803–1806 Lewis and Clark expedition and nineteenth century stage records are used to quantitatively benchmark natural, premanagement hydrology of the lower Missouri River and assess the magnitude and timing of hydrologic change over nearly two centuries. Data show doubling in daily stage variability from the nineteenth century to 2005. Annual maximum stages have, at some sites, become more extreme, and their seasonality is less regular. Observed changes adversely affect riverine habitat and flood levels; their timing, beginning as early as 1900, suggests that channelization is the major driver. [ABSTRACT FROM AUTHOR]

Weldon Spring is consistently enriched in 18 O relative to other karst springs in east-central Missouri and western Illinois, suggesting an evaporated source component. Regional potentiometric head maps of the shallow aquifer suggest that Prairie Lake, an artificial lake built between 1954 and 1982, could represent this component. Isotopic, biological and chemical tracing of the spring conclusively verify the hypothesis that this lake has impacted Weldon Spring. Mixing calculations indicate that Weldon Spring is now comprised of approximately 80% lake water and 20% groundwater. Recent measurements indicate that the discharge rate of the spring is now approximately 10 times the rate prior to the construction of the lake, confirming the augmentation of flow by a new source. Analysis of the isotopic trends indicates that the subsurface travel time is short, and suggests that the conduits connecting the lake and the spring may be progressively enlarging. [ABSTRACT FROM AUTHOR]