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Titanium silicalite-1 (TS-1) is a milestone heterogeneous catalyst with single-atom tetrahedral titanium incorporated into silica framework for green oxidation reactions. Although TS-1 catalysts have been industrialized, the strategy of direct hydrothermal synthesis usually produces catalysts with low catalytic activities, which has still puzzled academic and industrial scientists. Post-treatment processes were widely chosen and were proven to be an essential process for the stable production of the high-activity zeolites with hollow structures. However, the reasons why post-treatment processes could improve catalytic activity are still not clear enough. Here, high-performance hollow TS-1 zeolites with nano-sized crystals and nano-sized cavities were synthesized via post-treatment of direct-synthesis nano-sized TS-1 zeolites. The influencing factors of the fabricating processes on their catalytic activities were investigated in detail, including the content of alkali metal ions, the state of titanium centers, hydrophilic/hydrophobic properties, and accessibility of micropores. The post-treatment processes could effectively solve these adverse effects to improve catalytic activity and to stabilize production. These findings contribute to the stable preparation of high-performance TS-1 catalysts in both factories and laboratories. [ABSTRACT FROM AUTHOR]

Hierarchical titanium silicalite-1 (HTS-1) zeolites are an important class of catalytic materials due to their enhanced mass transfer and improved catalytic performance. In this study, HTS-1 zeolites have been successfully prepared by the hydrothermal crystallization of carbon-silica-titania (CST) composites. Compared with the direct carbonization method, the mild carbonization of SiO2-TiO2/Tween 40 xerogel in the presence of sulfuric acid can effectively improve both the content and mesoporous structure of carbon material in the CST composites, which enables carbon materials to better play the role of a mesoporous template during the crystallization process. The resultant zeolite has both ordered micropores and interconnected mesopores and macropores, which are similar to the skeleton of the carbon template trapped in the TS–1 crystals. Moreover, the HTS–1 zeolite displays outstanding catalytic performance in oxidative desulfurization of bulky sulfur compounds. [ABSTRACT FROM AUTHOR]

Hierarchical CuCo 2 O 4 @CoMoO 4 nanowire/nanoplate hybrid nanostructures are successfully grown on Ni foam via simple methods involving hydrothermal and post-annealing treatment. The hybrid electrode exhibits a high areal capacity of 500 μAh/cm 2 at 2 mA/cm 2 and a good cycling stability with 84.1% retention over 2000 cycles at 20 mA/cm 2 . The assembled hybrid supercapacitor device based on CuCo 2 O 4 @CoMoO 4 and activated carbon as the positive and negative electrodes achieves a maximum energy density of 49 Wh/kg at a power density of 318 W/kg, showing the great potential of this hybrid materials as advanced electrodes for energy storage devices. [ABSTRACT FROM AUTHOR]