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Trace element analysis of sediments from archaeological sites is a valuable method to investigate the anthropic impact and obtain information on the functions of different areas and changes in human activities. One of the most used and effective techniques to carry out this kind of analysis is inductively coupled plasma–mass spectrometry. This technique needs a previous dissolution of the sample by acid attack, but the development of the best method is still a discussed issue. In the present work, total and partial digestion methods were carried out in sediment samples of Cueva de la Cocina (Dos Aguas, Spain), and trace elements were measured and statistically compared. Major elements, soil organic matter amount, and pH data were used to evaluate the main drivers of trace element contents. The differences between the results from the two methods were highlighted. Total digestion is more effective for aluminosilicates and heavy minerals, although the partial digestion results suggested that, in most cases, the difference between the two methods is irrelevant for archaeological interpretations. Furthermore, in some cases, the total digestion of the mineral phases related to the geological contribution could mask the anthropic elemental signals. [ABSTRACT FROM AUTHOR]

The present work represents the first attempt using an archaeometric approach to characterize the potential chert outcrops and retrace the provenance of the chert raw materials in the Mesolithic and Neolithic contexts of the Eastern Iberia central site of Cueva de la Cocina (Dos Aguas, Valencia). Therefore, a research project aimed at identifying and characterizing potential sources in the surroundings of the site was carried out, as a first step, to test some hypotheses related to raw material provenance. Elemental profiles of several archaeological artifacts and of geological samples collected in different local and nonlocal outcrops were obtained using X‐ray fluorescence spectroscopy and inductively coupled plasma mass spectrometry. These chemical data were processed using multivariate statistics to investigate the possible links between the outcrops and archaeological artifacts. Preliminary results point to the use of local raw materials and also the presence of rocks outcropping in a perimeter of more than 50 km around Cueva de la Cocina, opening a new window to investigate the socioecological dynamics of the last hunter‐gatherer and the first farmer inhabitants from a diachronic point of view in this region. [ABSTRACT FROM AUTHOR]

A novel indirect chronology method has been developed to identify Sagunto Castle construction periods. The method is based on the use of inductively coupled plasma mass spectrometry (ICP-MS) to determine rare earth elements (REE) and other trace elements in mortars. Additionally, a no destructive geochemical analysis based on X-ray fluorescence (XRF) was employed for major elements determination. Collected chemical data were processed through Principal Component Analysis (PCA) to highlight any differences among the mortars belonging to different buildings and construction periods. The results show that PCA analysis permits to discriminate construction periods according to mortar sample REE contents. Major elements and trace elements show just coarse differences related to the mortar composition. The proposed method permitted to clarify important issues about wall stratigraphy and its effectiveness on a novel indirect chronology developed method. [ABSTRACT FROM AUTHOR]

A methodology based on the mineral analysis determination has been developed to identify the origin of dolerite stone outcrops collected to fabricate lithic objects during the Prehistoric period. The method is based on the use of inductively coupled plasma mass spectrometry (ICP-MS) to analyse rare earth elements (REE) and trace elements. Additionally a no destructive geochemical analysis based on X-ray fluorescence (XRF) was employed for major elements analysis. The aforementioned methodologies were applied to samples from different archaeological fields or natural outcrops located in the Mediterranean area of Spain, between Valencia and Alicante. Principal component analysis (PCA) was employed to interpret the dolerite geological provenance. These preliminary results show that statistical analysis permits to distinguish stone sample origins according to their REE profile at regional level and that Ti/Fe major element relation perhaps shows just coarse differences between samples collected on the extreme north and south of the studied region. The proposed method could be useful to discriminate the regional origin of lithic objects belonging to dolerite rocks and to interpret the primary material transport and exchange of lithic materials in Valencian Prehistory. [ABSTRACT FROM AUTHOR]

An innovative multi-analytical approach for the classification of ancient pottery sherds was tested. Twenty Roman amphorae fragments belonging to different known typologies and twenty-seven unclassified ones from a complex Sagunto Archaeological Museum (Spain) collection were studied by multielement analysis (X-ray fluorescence spectroscopy and inductively coupled plasma mass spectrometry), Fourier-transform near infrared spectroscopy and voltammetry of immobilized microparticles employing a minimal amount of sample. Chemometric analysis based on principal component analysis allowed the identification of most of the unclassified samples, proving the importance and reliability of the developed methodological approach for ceramic classification insights. Image 1 • A multi-analytical approach for ancient ceramic study was tested for the first time. • Amphorae fragments from Sagunto Archaeological Museum were collected. • Classified and unclassified samples were analysed by XRF, ICP-MS, FT-NIR and VIMP. • Most samples were classified by cross-referencing data from different techniques. • Strengths and weaknesses of the single techniques were pointed out. [ABSTRACT FROM AUTHOR]