1. Dynamic construction of refractive index-dependent vibrations using surface plasmon-phonon polaritons.
- Author
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Zhou, Hong, Ren, Zhihao, Li, Dongxiao, Xu, Cheng, Mu, Xiaojing, and Lee, Chengkuo
- Subjects
PHONONS ,POLARITONS ,INFRARED absorption ,REFRACTIVE index ,MOLECULAR vibration ,MOLECULAR polarizability - Abstract
One of the fundamental hurdles in infrared spectroscopy is the failure of molecular identification when their infrared vibrational fingerprints overlap. Refractive index (RI) is another intrinsic property of molecules associated with electronic polarizability, but with limited contribution to molecular identification in mixed environments currently. Here, we investigate the coupling mode of localized surface plasmon and surface phonon polaritons for vibrational de-overlapping. The coupling mode is sensitive to the molecular refractive index, attributed to the RI-induced vibrational variations of surface phonon polaritons (SPhP) within the Reststrahlen band, referred to as RI-dependent SPhP vibrations. The RI-dependent SPhP vibrations are linked to molecular RI features. According to the deep-learning-augmented demonstration of bond-breaking-bond-making dynamic profiling in biological reaction, we substantiate that the RI-dependent SPhP vibrations effectively disentangle overlapping vibrational modes, achieving a 92% identification accuracy even for the strongly overlapping vibrational modes in the reaction. Our findings offer insights into the realm of light-matter interaction and provide a valuable toolkit for biomedicine applications. Molecular vibrations serve as valuable signatures for the constituent elements and bonding in compounds. Here, using Surface-Enhanced Infrared Absorption spectroscopy, the authors study refractive index dependent vibrations of surface phonon polaritons and surface plasmon platform, targeting dynamic biomonitoring. [ABSTRACT FROM AUTHOR]
- Published
- 2023
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