20 results on '"G. A. Buzanov"'
Search Results
2. Complexes of Zinc(II)- and Copper(II) Perchlorates with Nicotinamide: Synthesis, Structure, Cytotoxicity
- Author
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N. S. Rukk, N. S. Kabernik, G. A. Buzanov, L. G. Kuzmina, G. A. Davydova, S. K. Belus, and E. I. Kozhukhova
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Inorganic Chemistry ,Materials Science (miscellaneous) ,Physical and Theoretical Chemistry - Published
- 2022
3. Phase Equilibria in the Eu–Mn–O System
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G. A. Buzanov and G. D. Nipan
- Subjects
Inorganic Chemistry ,Materials Science (miscellaneous) ,Physical and Theoretical Chemistry - Published
- 2022
4. Hydride Intercalation of Lithium into Ni3GaTe2
- Author
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G. A. Buzanov, E. A. Stroganova, A. Yu. Bykov, K. Yu. Zhizhin, and N. T. Kuznetsov
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Inorganic Chemistry ,Materials Science (miscellaneous) ,Physical and Theoretical Chemistry - Abstract
Abstract In order to expand the methods of lithium intercalation into layered multicomponent matrices, the reaction of lithium hydride with layered telluride Ni3GaTe2 through the stage of formation of mechanocomposites has been studied. Intercalation compounds LixNi3GaTe2 (0 ≤ x ≤ 0.3) have been shown to form when annealing mechanocomposites of the matrix and intercalating agent (LiH) in argon. The channels of hydride ion conversion have been studied and transformations involving the matrix have been described at various temperatures and molar ratios of the matrix and intercalating agent.
- Published
- 2022
5. Synthesis and Thermal Reduction of Complexes [NiLn][B10H10] (L = DMF, H2O, n = 6; L = N2H4, n = 3): Formation of Solid Solutions Ni3C1 –xВx
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V. M. Retivov, Varvara V. Avdeeva, Lyudmila V. Goeva, N. T. Kuznetsov, Elena A. Malinina, and G. A. Buzanov
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Chemistry ,Materials Science (miscellaneous) ,Thermal decomposition ,chemistry.chemical_element ,Infrared spectroscopy ,Atmospheric temperature range ,010402 general chemistry ,010403 inorganic & nuclear chemistry ,01 natural sciences ,0104 chemical sciences ,Inorganic Chemistry ,Nickel ,Elemental analysis ,Physical and Theoretical Chemistry ,Inert gas ,Powder diffraction ,Nuclear chemistry ,Solid solution - Abstract
Nickel(II) complexes of the composition [NiLn][B10H10] (L = DMF, H2O, n = 6; L = N2H4, n = 3) have been synthesized and studied. The thermal reduction of the complexes has been studied in the temperature range 20–800°C in air and in an inert atmosphere. Precursor complexes and their reduction products have been identified by elemental analysis, X-ray powder diffraction, and IR spectroscopy. The physicochemical study of the thermolysis product of complex [Ni(DMF)6][B10H10] shows that scarcely studied solid solutions of the composition Ni3C1 –xВx are formed.
- Published
- 2020
6. Solid-State Synthesis of Lithium-Substituted Spinels Mg1 – xLixMnO3 – δ
- Author
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K. Yu. Zhizhin, G. A. Buzanov, N. T. Kuznetsov, and N. P. Simonenko
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Materials science ,Chemical substance ,Magnesium ,Materials Science (miscellaneous) ,Inorganic chemistry ,Lithium carbonate ,chemistry.chemical_element ,010402 general chemistry ,010403 inorganic & nuclear chemistry ,01 natural sciences ,0104 chemical sciences ,law.invention ,Inorganic Chemistry ,chemistry.chemical_compound ,chemistry ,Magazine ,law ,Lithium ,Physical and Theoretical Chemistry ,Science, technology and society ,Ball mill ,Solid solution - Abstract
Solid solutions based on MgMnO3 – δ in which magnesium is partially substituted for by lithium were produced by solid-phase synthesis by air annealing of mechanocomposites obtained by mechanical activation (in a vibration ball mill) of mixtures of high-purity grade precursors: oxides MgO, Mn2O3, and MnO2, and also Li2CO3 and LiOH · H2O. It was shown that using lithium hydroxide monohydrate increases the degree of substitution of lithium for magnesium with simultaneous decrease in the synthesis temperature in comparison with using lithium carbonate.
- Published
- 2019
7. Solid State Synthesis and Reversible Oxygen Capacity of Li/Mg Overstoichiometric Solid Solutions Based on the Spinel MgMnO3 – δ
- Author
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K. Yu. Zhizhin, G. A. Buzanov, N. P. Simonenko, and N. T. Kuznetsov
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Materials science ,Materials Science (miscellaneous) ,Inorganic chemistry ,Spinel ,engineering.material ,Redox ,Methane ,Catalysis ,Inorganic Chemistry ,chemistry.chemical_compound ,chemistry ,Homogeneity (physics) ,engineering ,Titration ,Physical and Theoretical Chemistry ,Chemical looping combustion ,Solid solution - Abstract
Series of spinel solid solutions with a specified cation composition, Mg1 +xMnO3 – δ and, for the first time, MgLixMnO3 – δ, potential materials of catalytic systems for oxidation reactions such as oxidative conversion of methane and chemical looping combustion process were prepared by solid-state syntheses from mechanocomposites obtained by milling of ultra-high purity precursors (MgO, Mn2O3, MnO2, and Li2CO3). Their homogeneity region was found to be up to 1573 K at p(O2) = 0.21 atm. For both series of solid solutions, the synthesis from Mn2O3 and MnO2 in air was investigated by the TG-DSC method and the oxygen content in the resulting materials was determined (TG-DSC, titration). The products of extensive reduction of spinels Mg1 +xMnO3 – δ and MgLixMnO3–δ with an Ar + 4.8% H2 mixture were investigated. Parameters of conversion of the reduction products to the initial single-phase spinels on treatment with air were determined. The obtained materials showed good reproducibility of reversible oxygen capacity over 20 reduction–oxidation cycles.
- Published
- 2019
8. Synthesis and Physicochemical Properties of Binary Cobalt(II) Borides. Thermal Reduction of Precursor Complexes [CoLn][B10H10] (L = H2O, n = 6; N2H4, n = 3)
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I. V. Kozerozhets, Lyudmila V. Goeva, N. N. Efimov, G. A. Buzanov, N. T. Kuznetsov, Elena A. Malinina, and Varvara V. Avdeeva
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Annealing (metallurgy) ,Materials Science (miscellaneous) ,Significant difference ,Infrared spectroscopy ,chemistry.chemical_element ,010402 general chemistry ,010403 inorganic & nuclear chemistry ,01 natural sciences ,0104 chemical sciences ,Inorganic Chemistry ,chemistry ,Magnetochemistry ,Elemental analysis ,Thermal ,Physical and Theoretical Chemistry ,Inert gas ,Cobalt ,Nuclear chemistry - Abstract
Complexes [CoLn][B10H10], where L = H2O, n = 6; L = N2H4, n = 3, have been synthesized and characterized. The possibility of their use as precursors for the synthesis of binary cobalt(II) borides has been shown. Cobalt(II) borides have been obtained by thermal reduction of precursor complexes in an inert atmosphere at 650 and 900°C. The purity and homogeneity of the precursors and their reduction products have been determined by elemental analysis, powder X-ray diffraction, and IR spectroscopy; magnetochemistry of precursors and their annealing products has been studied. The morphology of the final products has been studied. It has been found that the reduction products are structured oxide-boride and nitride-boride phases. The magnetochemical study of the phases showed a significant difference in their magnetic behavior.
- Published
- 2019
9. Hydride Intercalation of Lithium into the Spinel MgMnO3 – δ
- Author
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K. Yu. Zhizhin, G. A. Buzanov, and N. T. Kuznetsov
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Materials science ,Hydride ,Materials Science (miscellaneous) ,Spinel ,Intercalation (chemistry) ,Inorganic chemistry ,chemistry.chemical_element ,engineering.material ,010402 general chemistry ,010403 inorganic & nuclear chemistry ,01 natural sciences ,0104 chemical sciences ,Ion ,Inorganic Chemistry ,chemistry.chemical_compound ,chemistry ,Lithium hydride ,visual_art ,visual_art.visual_art_medium ,engineering ,Lithium ,Ceramic ,Physical and Theoretical Chemistry ,Solid solution - Abstract
Lithium-rich superstoichiometric solid solutions MgLixMnO3 – δ were obtained by intercalation into the spinel MgMnO3 – δ using lithium hydride LiH as an intercalating agent through the stage of the formation of mechanocomposites. The accompanying chemical transformations involving the hydride ion were studied. Conventional ceramic synthesis methods and alternative intercalating agents were analyzed. It was shown that hydride intercalation produces pure samples of single-phase spinels with high lithium content (MgLi0.75MnO3), which is three times higher than that reachable by conventional ceramic synthesis methods.
- Published
- 2019
10. Zinc(II) and cadmium(II) halide complexes with caffeine: Synthesis, X-ray crystal structure, cytotoxicity and genotoxicity studies
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N. S. Rukk, G. A. Davydova, Alena Yu. Skryabina, Svetlana K. Belus, Elena A. Mironova, Andrej N. Streletskii, Lyudmila G. Kuzmina, Ravshan S. Shamsiev, Vasilii M. Retivov, Valeriya N. Krasnoperova, Galina A. Vorob'eva, Evgeniya I. Kozhukhova, G. A. Buzanov, Artem M. Ermakov, and Pavel A. Volkov
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010405 organic chemistry ,Chemistry ,Hydrogen bond ,Tetrahedral molecular geometry ,chemistry.chemical_element ,Infrared spectroscopy ,Zinc ,Crystal structure ,010402 general chemistry ,01 natural sciences ,0104 chemical sciences ,Inorganic Chemistry ,chemistry.chemical_compound ,Crystallography ,Cadmium iodide ,Materials Chemistry ,Proton NMR ,Molecule ,Physical and Theoretical Chemistry - Abstract
Molecular complexes [Zn(caf)(H2O)I2] (I), [Zn(caf)(H2O)Cl2] (IV), and the polymeric ones {[Cd(H2O)2I2](caf).2H2O}n (II) and {[Cd(H2O)2Br2](caf).2H2O}n (III) consisting of infinite Cd-containing chains with bridging halide ions and water molecules in trans-position and connected with each other due to hydrogen bonding with participation of caffeine (caf) and water molecules, were prepared and characterized by the powder and single crystal X-ray diffraction, IR vibrational spectroscopy, 1H NMR, ESI-MS spectroscopy, thermal analysis and DFT calculations. It was found that the complexes (I) and (IV) are characterized by tetrahedral geometry, the caffeine molecule being coordinated by the central atom via its N9 atom. The preferability of complex formation was evaluated by quantum-chemical calculations. Cyto- and genotoxicity of the compounds have been investigated and discussed in comparison with that of [Zn(AP)2I2] (1) and [Cd(AP)6][Cd(AP)I3]2 (2). It was demonstrated that the prepared complexes, primarily that of cadmium iodide with caffeine (II), are the promising ones for further studies both in vitro and in vivo.
- Published
- 2019
11. Preparation and Characterization of MgH2 Mechanocomposites with Mg2NiH0.3 + Mg2NiH4 – δ Two-Phase Mixture
- Author
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N. P. Simonenko, N. T. Kuznetsov, N. N. Mal’tseva, K. Yu. Zhizhin, and G. A. Buzanov
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Content area ,Magnesium ,Materials Science (miscellaneous) ,Intercalation (chemistry) ,chemistry.chemical_element ,02 engineering and technology ,010402 general chemistry ,021001 nanoscience & nanotechnology ,01 natural sciences ,0104 chemical sciences ,Inorganic Chemistry ,chemistry ,Phase (matter) ,High magnesium ,Physical and Theoretical Chemistry ,0210 nano-technology ,Solid solution ,Nuclear chemistry - Abstract
The thermal behavior of MgH2 mechanocomposites with Mg2NiH4 – δ + Mg2NiH0.3 two-phase mixture and phase equilibria in the system Mg–Ni–H involving MgH2 were studied by powder X-ray diffraction and TG–DSC. The graphic representation of phase equilibria involving MgH2 and Mg2NiH4 – δ and Mg2NiHx (0 < x < 0.3) solid solutions in the practically important field with high magnesium content area was revised. The possibility of MgH2 mechanocomposites with Mg2NiH4 – δ and Mg2NiHx for use as magnesium intercalating agents and alternative intercalating agents—organomagnesium compounds were considered.
- Published
- 2018
12. Synthesis and Structure of [М(DMF)6][B10H10] (M = Zn(II), Cd(II)) as Precursors for Solid-Phase Synthesis of Trischelate Complexes [М(L)3][B10H10]
- Author
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Elena A. Malinina, Lyudmila V. Goeva, Varvara V. Avdeeva, Svetlana E. Korolenko, G. A. Buzanov, and N. T. Kuznetsov
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Chemistry ,Materials Science (miscellaneous) ,010402 general chemistry ,010403 inorganic & nuclear chemistry ,01 natural sciences ,Medicinal chemistry ,Metal nitrate ,0104 chemical sciences ,Inorganic Chemistry ,Solid-phase synthesis ,Ultraviolet visible spectroscopy ,Molecule ,Reactivity (chemistry) ,Acid–base reaction ,Physical and Theoretical Chemistry ,Isostructural ,Powder diffraction - Abstract
The reactivity of the decahydro-closo-decaborate anion in the complexation of metals being among intermediates acids in the concept of the Pearson’s theory of hard and soft acids and bases is studied systematically in the presence of competitive ligands L. In continuing these studies, we have synthesized Zn(II) and Cd(II) complexes of the composition [М(DMF)6][B10H10] (M = Zn(II), Cd(II)) and studied them by physicochemical analyses (IR and UV spectroscopy, X-ray powder diffraction). The possibility of their use in solid-phase synthesis of the corresponding trischelate complexes [M(Bipy)3][B10H10] has been found. Complexes [М(DMF)6][B10H10] are formed by the reaction between triethylammonium closo-decaborate with metal nitrates in DMF. The compounds are isostructural with the corresponding Co(II) and Ni(II) complexes [М(DMF)6][B10H10]. Specific interactions have been found between the BH groups of the boron clusters and CH groups of the DMF molecules. According to the data of IR and UV spectroscopy, the complexes contain specific B–H···C–H interactions. The corresponding tris-chelate complexes of the metals [M(Bipy)3][B10H10] are also isostructural.
- Published
- 2018
13. Noncovalent interactions in perchlorinated sulfonium and ammonium derivatives of closo-decaborate anion: 35Cl NQR and crystal structure
- Author
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Alexey V. Tkachev, V.A. Semenova, K. Yu. Zhizhin, A. A. Gippius, A. Yu. Bykov, G. A. Buzanov, A.V. Golubev, E. A. Kravchenko, A. S. Kubasov, N. T. Kuznetsov, and S. V. Zhurenko
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chemistry.chemical_classification ,Sulfonium ,Intermolecular force ,Crystal structure ,Carbon-13 NMR ,Ion ,Inorganic Chemistry ,Crystallography ,symbols.namesake ,chemistry.chemical_compound ,chemistry ,Materials Chemistry ,Cluster (physics) ,symbols ,Non-covalent interactions ,Physical and Theoretical Chemistry ,van der Waals force - Abstract
Three salts of perchlorinated sulfonium and ammonium derivatives of tetrabuthylammonium nonachloro-closo-decaborate, (n-Bu4N)2[2-B10Cl9-cyclo-S(CH2)4S-B10Cl9] (1), (n-Bu4N)[2-B10Cl9-cyclo-S(C2H4)2O] (2) and (n-Bu4N)[1-B10Cl9N(n-Pr3)] (3) are synthesized and characterized using IR, 11B, 1H, 13C NMR, X-Ray and 35Cl NQR-spectroscopy. The noncovalent interactions involving chlorine atoms were identified by 35Cl NQR spectra. The results were discussed in comparison with those of X-ray diffraction analysis which are based on measuring contacts shorter than the sum of van der Waals (vdW) radii of atoms. It has been found that the crystal lattice of 2 exhibits dynamic properties strongly different from those of 1 and 3. Whereas the 35Cl NQR spectra of the latters were extremely wide (up to 1200 kHz), the spectrum of 2 demonstrated a narrowing of almost an order of magnitude (up to 120 kHz) which indicated a significant weakening of the tendency for the formation of intermolecular bonds by chlorine atoms of this cluster.
- Published
- 2021
14. Decachloro-closo-decaborate anion in copper(II) complexation reactions with N-donor ligands: 35Cl NQR and X-ray studies
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Elena A. Malinina, E. A. Kravchenko, Nikolay T. Kuznetsov, G. A. Buzanov, A. A. Gippius, Anna V. Vologzhanina, S. V. Zhurenko, and Varvara V. Avdeeva
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Diffraction ,Hydrogen ,Chemistry ,Analytical chemistry ,X-ray ,chemistry.chemical_element ,010402 general chemistry ,010403 inorganic & nuclear chemistry ,01 natural sciences ,Copper ,Redox ,0104 chemical sciences ,Ion ,Inorganic Chemistry ,Crystallography ,X-ray crystallography ,Materials Chemistry ,Physical and Theoretical Chemistry ,Spectroscopy - Abstract
Copper(II) complexation reactions with neutral N-donor ligands (Bipy, Phen, NH3) in the presence of the bulky decachloro-closo-decaborate dianion were studied. Copper(II) complexes can be prepared from copper(II) salts or copper(I) salts by redox reactions proceeding in air. The complexes [Cu(Bipy)3][B10Cl10]·2CH3CN (1·2CH3CN), [Cu(Bipy)3][B10Cl10]·2Bipy (1·2Bipy), [Cu(Bipy)2Cl]2[B10Cl10]·2DMF (2·2DMF), [Cu(Phen)2Cl]2[B10Cl10]·DMSO·1.25H2O (3·DMSO·1.25H2O) and [Cu(NH3)4(CH3CN)2][B10Cl10] (4) were prepared and characterized by X-ray diffraction as well as IR and 11B NMR spectroscopies. Complexes 1·2CH3CN, 2·2DMF, and 4 were also studied using 35Cl NQR spectroscopy. Secondary interactions were selected from all the interatomic contacts found in these crystals by X-ray diffraction. Hydrogen N–H⋯Cl–B, C–H⋯Cl–B and p⋯π (B–Cl⋯C) secondary bonds were identified in all the compounds, the spectroscopic data being generally in accordance with the results of the X-ray diffraction.
- Published
- 2017
15. Phase equilibria involving solid solutions in the Li–Mn–O system
- Author
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K. Yu. Zhizhin, G. A. Buzanov, G. D. Nipan, and N. T. Kuznetsov
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Chromatography ,Hydride ,Chemistry ,Materials Science (miscellaneous) ,Analytical chemistry ,02 engineering and technology ,010402 general chemistry ,021001 nanoscience & nanotechnology ,01 natural sciences ,0104 chemical sciences ,Partial oxygen ,Inorganic Chemistry ,Homogeneous ,Phase (matter) ,Physical and Theoretical Chemistry ,0210 nano-technology ,Solid solution ,Phase diagram - Abstract
Phase equilibria involving LiMn2O4-, Li2MnO3-, LiMnO2-, Mn3O4-, and MnO-base solid solutions were studied with varied temperature and partial oxygen pressure. The $${P_{{o_2}}}$$ –T and x–y projections of the P–T–x–y phase diagram of the Li–Mn−O system were constructed, as well as the key x–y isotherms of the Li2O–MnO–MnO2 quasi-ternary system. In some experiments, the authors’ hydride lithiation method was employed to prepare lithium-rich homogeneous three-component nonstoichiometric phases.
- Published
- 2017
16. Phase states of Li(Na,K,Rb,Cs)/W/Mn/SiO2 composite catalysts for oxidative coupling of methane
- Author
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N. T. Kuznetsov, G. D. Nipan, K. Yu. Zhizhin, and G. A. Buzanov
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Materials Science (miscellaneous) ,Composite number ,Analytical chemistry ,Mineralogy ,chemistry.chemical_element ,02 engineering and technology ,Manganese ,010402 general chemistry ,021001 nanoscience & nanotechnology ,01 natural sciences ,0104 chemical sciences ,Catalysis ,Inorganic Chemistry ,Matrix (chemical analysis) ,chemistry.chemical_compound ,Tungstate ,chemistry ,Phase (matter) ,Oxidative coupling of methane ,Crystallite ,Physical and Theoretical Chemistry ,0210 nano-technology - Abstract
This survey analyzes the results of studies into Li(Na,K,Rb,Cs)/W/Mn/SiO2 composites, which are used as catalysts for oxidative coupling of methane (OCM). The focus is on phase states. Our analysis shows that the SiO2 matrix is an active constituent of the composites and not an inert carrier of additives and the OCM heterogeneous process involves alkali-metal tungstate melts, along with polycrystalline manganese oxides. The effects of the cation ratio and synthetic routes on the phase composition of Li(Na,K,Rb,Cs)/W/Mn/SiO2 are assessed.
- Published
- 2016
17. Hydride lithiation of spinels LiMn2O4
- Author
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N. T. Kuznetsov, K. Yu. Zhizhin, G. A. Buzanov, and G. D. Nipan
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010405 organic chemistry ,Annealing (metallurgy) ,Hydride ,Inorganic chemistry ,Spinel ,chemistry.chemical_element ,General Chemistry ,engineering.material ,010402 general chemistry ,01 natural sciences ,Oxygen ,0104 chemical sciences ,chemistry.chemical_compound ,chemistry ,Lithium hydride ,engineering ,Argon atmosphere ,Stoichiometry - Abstract
Undoped lithiation of stoichiometric spinel using lithium hydride LiH up to the composition Li2.25Mn2O4 was performed. A homogeneous material with a given Li: Mn ratio was obtained by mechanochemical activation with sequential annealing of a LiMn2O4–LiH mixture in a high-purity argon atmosphere and then in air or oxygen at 373–553 K.
- Published
- 2016
18. [Co(solv)6][B10H10] (solv = DMF and DMSO) for low-temperature synthesis of borides
- Author
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I. N. Polyakova, Anna V. Vologzhanina, N. B. Generalova, Lyudmila V. Goeva, Elena A. Malinina, Varvara V. Avdeeva, K. Yu. Zhizhin, G. A. Buzanov, and Nikolay T. Kuznetsov
- Subjects
Materials Science (miscellaneous) ,Thermal decomposition ,Inorganic chemistry ,chemistry.chemical_element ,Infrared spectroscopy ,Atmospheric temperature range ,010402 general chemistry ,010403 inorganic & nuclear chemistry ,01 natural sciences ,0104 chemical sciences ,Inorganic Chemistry ,Solvent ,Ultraviolet visible spectroscopy ,chemistry ,Physical chemistry ,Physical and Theoretical Chemistry ,Thermal analysis ,Cobalt ,Powder diffraction - Abstract
The synthesis and structure of complexes [Co(solv)6][B10H10] (solv = DMF and DMSO) have been reported. Both complexes have been prepared in a high yield by the reaction between cobalt(II) salts and closo-decaborates Cat2[B10H10] in the corresponding solvent. The complexes have been characterized by elemental analysis, IR and UV spectroscopy, X-ray powder diffraction, and X-ray crystallography. The thermal properties of the compounds have been studied in the temperature range 20–600°C under argon. The conditions to form cobalt borides have been determined based on the results of thermal analysis, subsequent annealing of the complexes in various conditions, and analysis of IR spectra of the resulting thermolysis products.
- Published
- 2016
19. Hydride compounds of zinc
- Author
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Nikolay T. Kuznetsov, K. Yu. Zhizhin, G. A. Buzanov, and N. N. Mal’tseva
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Inorganic Chemistry ,chemistry.chemical_compound ,chemistry ,Hydride ,Materials Science (miscellaneous) ,Inorganic chemistry ,Compounds of zinc ,chemistry.chemical_element ,Organic chemistry ,Zinc ,Physical and Theoretical Chemistry - Abstract
The chemistry of zinc hydrides, including the main approaches to the synthesis, structure and physicochemical properties of compounds containing zinc-hydrogen bond, is systematized the review.
- Published
- 2014
20. Low-temperature heat capacity and thermal behavior of Zn0.98Co0.02O in the high-temperature region
- Author
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Andrey V. Khoroshilov, K. S. Gavrichev, M. A. Ryumin, N. A. Votinova, T. N. Kol’tsova, G. D. Nipan, A. V. Tyurin, G. A. Buzanov, I. Yu. Pinus, and V. A. Ketsko
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Inorganic Chemistry ,chemistry.chemical_compound ,Chemistry ,Materials Science (miscellaneous) ,Thermal ,Oxide ,Thermodynamics ,Calorimetry ,Physical and Theoretical Chemistry ,Adiabatic process ,Thermal diffusivity ,Heat capacity ,Solid solution - Abstract
The low-temperature heat capacity of Zn 0.98Co0.02O oxide was measured by adiabatic calorimetry. The formation of a solid solution was shown to be accompanied by a change in the entropy by 0.4 J/(K mol). No anomalies in the heat capacity or the thermal behavior confirming the phase transformations found earlier by other methods were observed. A heat capacity anomaly was revealed below 15 K and tentatively attributed to a change in the magnetic properties of the substance.
- Published
- 2009
Catalog
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