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The attenuation of Lyα photons by neutral hydrogen in the intergalactic medium (IGM) at z ≳ 5 continues to be a powerful probe for studying the epoch of reionization. Given a framework to estimate the intrinsic (true) Lyα emission of high- z sources, one can infer the ionization state of the IGM during reionization. In this work, we use the enlarged XQR-30 sample of 42 high-resolution and high signal-to-noise quasar spectra between |$5.8\lesssim \, z\lesssim \, 6.6$| obtained with VLT/X-shooter to place constraints on the IGM neutral fraction. This is achieved using our existing Bayesian QSO reconstruction framework which accounts for uncertainties such as the: (i) posterior distribution of predicted intrinsic Lyα emission profiles (obtained via covariance matrix reconstruction of the Lyα and N  v emission lines from unattenuated high-ionization emission line profiles; C  iv , Si  iv   + O  iv ], and C  iii ]) and (ii) distribution of ionized regions within the IGM using synthetic damping wing profiles drawn from a 1.63 Gpc3 reionization simulation. Following careful quality control, we used 23 of the 42 available QSOs to obtain constraints/limits on the IGM neutral fraction during the tail-end of reionization. Our median and 68th percentile constraints on the IGM neutral fraction are: |$0.20\substack{+0.14 -0.12}$| and |$0.29\substack{+0.14 -0.13}$| at z  = 6.15 and 6.35. Further, we also report 68th percentile upper limits of |$\bar{x}_{\mathrm{H\, {\small I}}{}} \lt 0.21$|⁠ , 0.20, 0.21, and 0.18 at z  = 5.8, 5.95, 6.05, and 6.55. These results imply reionization is still ongoing at |$5.8\lesssim \, z\lesssim \, 6.55$|⁠ , consistent with previous results from XQR-30 (dark fraction and Lyα forest) along with other observational probes considered in the literature. [ABSTRACT FROM AUTHOR]

The final phase of the reionization process can be probed by rest-frame UV absorption spectra of quasars at z ≳ 6, shedding light on the properties of the diffuse intergalactic medium within the first Gyr of the Universe. The ESO Large Programme 'XQR-30: the ultimate XSHOOTER legacy survey of quasars at z ≃ 5.8–6.6' dedicated ∼250 h of observations at the VLT to create a homogeneous and high-quality sample of spectra of 30 luminous quasars at z ∼ 6, covering the rest wavelength range from the Lyman limit to beyond the Mg  ii emission. Twelve quasar spectra of similar quality from the XSHOOTER archive were added to form the enlarged XQR-30 sample, corresponding to a total of ∼350 h of on-source exposure time. The median effective resolving power of the 42 spectra is R ≃ 11 400 and 9800 in the VIS and NIR arm, respectively. The signal-to-noise ratio per 10 km s−1 pixel ranges from ∼11 to 114 at λ ≃ 1285 Å rest frame, with a median value of ∼29. We describe the observations, data reduction, and analysis of the spectra, together with some first results based on the E-XQR-30 sample. New photometry in the H and K bands are provided for the XQR-30 quasars, together with composite spectra whose characteristics reflect the large absolute magnitudes of the sample. The composite and the reduced spectra are released to the community through a public repository, and will enable a range of studies addressing outstanding questions regarding the first Gyr of the Universe. [ABSTRACT FROM AUTHOR]

Intervening C  iv absorbers are key tracers of metal-enriched gas in galaxy haloes over cosmic time. Previous studies suggest that the C  iv cosmic mass density (⁠|$\Omega _{\rm C \, \small {IV}}$|⁠) decreases slowly over 1.5  |$\lesssim \, z\lesssim$|  5 before declining rapidly at z ≳ 5, but the cause of this downturn is poorly understood. We characterize the |$\Omega _{\rm C \, \small {IV}}$| evolution over 4.3 ≲ z ≲ 6.3 using 260 absorbers found in 42 XSHOOTER spectra of z ∼ 6 quasars, of which 30 come from the ESO Large Program XQR-30. The large sample enables us to robustly constrain the rate and timing of the downturn. We find that |$\Omega _{\rm C \, \small {IV}}$| decreases by a factor of 4.8 ± 2.0 over the ∼300 Myr interval between z ∼ 4.7 and ∼5.8. The slope of the column density (log  N) distribution function does not change, suggesting that C  iv absorption is suppressed approximately uniformly across 13.2 ≤ log  N /cm−2 < 15.0. Assuming that the carbon content of galaxy haloes evolves as the integral of the cosmic star formation rate density (with some delay due to stellar lifetimes and outflow travel times), we show that chemical evolution alone could plausibly explain the fast decline in |$\Omega _{\rm C \, \small {IV}}$| over 4.3 ≲ z ≲ 6.3. However, the C  iv /C ii ratio decreases at the highest redshifts, so the accelerated decline in |$\Omega _{\rm C \, \small {IV}}$| at z ≳ 5 may be more naturally explained by rapid changes in the gas ionization state driven by evolution of the UV background towards the end of hydrogen reionization. [ABSTRACT FROM AUTHOR]

Intervening metal absorption lines in the spectra of z ≳ 6 quasars are fundamental probes of the ionization state and chemical composition of circumgalactic and intergalactic gas near the end of the reionization epoch. Large absorber samples are required to robustly measure typical absorber properties and to refine models of the synthesis, transport, and ionization of metals in the early Universe. The Ultimate XSHOOTER legacy survey of quasars at z ∼ 5.8–6.6 (XQR-30) has obtained high signal-to-noise spectra of 30 luminous quasars, nearly quadrupling the existing sample of 12 high quality z ∼ 6 quasar spectra. We use this unprecedented sample to construct a catalogue of 778 systems showing absorption in one or more of Mg  ii (360 systems), Fe  ii (184), C  ii (46), C  iv (479), Si  iv (127), and N  v (13) which span 2 ≲ z ≲ 6.5. This catalogue significantly expands on existing samples of z ≳ 5 absorbers, especially for C  iv and Si  iv which are important probes of the ionizing photon background at high redshift. The sample is 50 per cent (90 per cent) complete for rest-frame equivalent widths W ≳ 0.03 Å (0.09 Å). We publicly release the absorber catalogue along with completeness statistics and a python script to compute the absorption search path for different ions and redshift ranges. This data set is a key legacy resource for studies of enriched gas from the era of galaxy assembly to cosmic noon, and paves the way for even higher redshift studies with JWST and 30 m-class telescopes. [ABSTRACT FROM AUTHOR]

At low densities, the standard ionization history of the intergalactic medium (IGM) predicts a decreasing temperature of the IGM with decreasing density once hydrogen (and helium) reionization is complete. Heating the high-redshift, low-density IGM above the temperature expected from photoheating is difficult, and previous claims of high/rising temperatures in lowdensity regions of the Universe based on the probability density function (PDF) of the opacity in Ly α forest data at 2 < z < 4 have been met with considerable scepticism, particularly since they appear to be in tension with other constraints on the temperature-density relation (TDR). We utilize here an ultrahigh signal-to-noise spectrum of the Quasi-stellar object HE0940-1050 and a novel technique to study the low opacity part of the PDF. We show that there is indeed evidence (at 90 per cent confidence level) that a significant volume fraction of the underdense regions at z ~ 3 has temperatures as high or higher than those at densities comparable to the mean and above. We further demonstrate that this conclusion is nevertheless consistent with measurements of a slope of the TDR in overdense regions that imply a decreasing temperature with decreasing density, as expected if photoheating of ionized hydrogen is the dominant heating process. We briefly discuss implications of our findings for the need to invoke either spatial temperature fluctuations, as expected during helium reionization, or additional processes that heat a significant volume fraction of the low-density IGM. [ABSTRACT FROM AUTHOR]

In this work, we investigate the abundance and distribution of metals in the intergalactic medium (IGM) at 〈z〉 ≃ 2.8 through the analysis of an ultra-high signal-to-noise ratio UVES spectrum of the quasar HE0940-1050. In the CIV forest, our deep spectrum is sensitive at 3σ to lines with column density down to log NCIV ≃ 11.4 and in 60 per cent of the considered redshift range down to ≃11.1. In our sample, all H I lines with log NHI ≥ 14.8 show an associated C IV absorption. In the range 14.0 ≤ log NHI < 14.8, 43 per cent of H I lines has an associated C IV absorption. At log NHI < 14.0, the detection rates drop to <10 per cent, possibly due to our sensitivity limits and not to an actual variation of the gas abundance properties. In the range log NHI ≥ 14, we observe a fraction of H I lines with detected C IV a factor of 2 larger than the fraction of H I lines lying in the circumgalactic medium (CGM) of relatively bright Lyman-break galaxies hosted by dark matter haloes with 〈M〉 ~ 1012 M☉. The comparison of our results with the output of a grid of photoionization models and of two cosmological simulations implies that the volume filling factor of the IGM gas enriched to a metallicity logZ/Z☉≳-3log⁡Z/Z☉≳-3 should be of the order of ~10-13 per cent. In conclusion, our results favour a scenario in which metals are found also outside the CGM of bright star-forming galaxies, possibly due to pollution by lower mass objects and/or to an early enrichment by the first sources. [ABSTRACT FROM AUTHOR]

We statistically study the physical properties of a sample of narrow absorption line (NAL) systems looking for empirical evidences to distinguish between intrinsic and interveningNALs without taking into account any a priori definition or velocity cut-off. We analyse the spectra of 100 quasars with 3.5 < zem < 4.5, observed with X-shooter/Very Large Telescope in the context of the XQ-100 Legacy Survey. We detect an ~8σ excess in the C IV number density within 10 000 km s-1 of the quasar emission redshift with respect to the random occurrence of NALs. This excess does not show a dependence on the quasar bolometric luminosity and it is not due to the redshift evolution of NALs. It extends far beyond the standard 5000 km s-1 cutoff traditionally defined for associated absorption lines.We propose to modify this definition, extending the threshold to 10 000 km s-1 when weak absorbers (equivalent width < 0.2Å) are also considered. We infer NV is the ion that better traces the effects of the quasar ionization field, offering the best statistical tool to identify intrinsic systems. Following this criterion, we estimate that the fraction of quasars in our sample hosting an intrinsic NAL system is 33 per cent. Lastly, we compare the properties of the material along the quasar line of sight, derived from our sample, with results based on close quasar pairs investigating the transverse direction. We find a deficiency of cool gas (traced by C II) along the line of sight connected to the quasar host galaxy, in contrast with what is observed in the transverse direction. [ABSTRACT FROM AUTHOR]