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Your search keyword '"Truscott, Byron J."' showing total 3 results
Start Over Author "Truscott, Byron J." Topic iridium compounds
3 results on '"Truscott, Byron J."'

1. Exploring the Limits of Catalytic Ammonia–BoraneDehydrogenation Using a Bis(N-heterocyclic carbene) Iridium(III) Complex.

Author

Nelson, David J., Truscott, Byron J., Egbert, Jonathan D., and Nolan, Steven P.

Subjects
*AMMONIA, *BORANES, *DEHYDROGENATION, *IRIDIUM compounds, *METAL complexes, *CATALYSIS
Abstract

Ammoniaborane dehydrogenation can be catalyzed by a number of organometallicspecies. [Ir(κ2-ItBu)2][PF6] (ItBu = 1,3-bis(tert-butyl)imidazol-2-ylidene) is the most active catalystfor this process that has been reported to date. We explore hereinthe absolute limits of the use of this and related complexes, including[Ir(κ2-ItBu)2][BArF4], [Ir(H)2(ItBu)2][BArF4], and[Ir(κ2-ItBu)2(NH3)][BArF4] (BArF4= tetrakis(3,5-bis(trifluoromethyl)phenyl)borate). [ABSTRACT FROM AUTHOR]

Published
2013
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2. CO2 fixation employing an iridium(i)-hydroxide complex.

Author

Truscott, Byron J., Nelson, David J., Slawin, Alexandra M. Z., and Nolan, Steven P.

Subjects
*IRIDIUM compounds, *IRIDIUM, *CHEMICAL bonds, *CARBONATES, *CARBAMATES
Abstract

The reactivity of a number of IrI complexes towards CO2 is explored using [Ir(NHC)(OH)] as a key synthon. CO2 insertion into Ir–O and Ir–N bonds proved facile, yielding a number of IrI-carbonates and -carbamates. Most importantly, reaction between CO2 and IrI–OH led to isolation of the novel [{IrI}2-(μ-κ1:κ2-CO3)] complex. [ABSTRACT FROM AUTHOR]

Published
2014
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