1. Unraveling optical degradation mechanism of β-Ga2O3 by Si4+ irradiation: A combined experimental and first-principles study.
- Author
-
Huang, Yuanting, Xu, Xiaodong, Yang, Jianqun, Yu, Xueqiang, Wei, Yadong, Ying, Tao, Liu, Zhongli, Jing, Yuhang, Li, Weiqi, and Li, Xingji
- Subjects
IRRADIATION ,X-ray photoelectron spectroscopy ,PHOTOELECTRIC devices ,ELECTRONIC equipment ,SPACE environment ,RAMAN spectroscopy - Abstract
Wide bandgap β-Ga
2 O3 is an ideal candidate material with broad application prospects for power electronic components in the future. Aiming at the application requirements of β-Ga2 O3 in space photoelectric devices, this work studies the influence of 40 MeV Si ion irradiation on the microstructure and optical properties of β-Ga2 O3 epi-wafers. Raman spectroscopy analysis confirms that Si ion irradiation destroys the symmetric stretching mode of tetrahedral–octahedral chains in β-Ga2 O3 epi-wafers, and the obtained experimental evidence of irradiation leads to the enhanced defect density of VO and VGa –VO from x-ray photoelectron spectroscopy. Combined with first-principles calculations, we conclude that most configurations of VO and VGa –VO are likely non-radiative, leading to quenching of experimental photoluminescence intensity. Unraveling optical degradation mechanism and predicting the optical application of β-Ga2 O3 devices in the space environment by combining ground irradiation experiments with first-principles calculations still be one of the focuses of research in the future. [ABSTRACT FROM AUTHOR]- Published
- 2023
- Full Text
- View/download PDF