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The presence of pharmaceutical compounds in the whole environment is a growing concern. These compounds might be present in the effluents of wastewater treatment plants and, hence, irrigation with treated sewage may be a source of groundwater pollution. The volcanic aquifer that lies NE of Gran Canaria (Spain) was studied to address the relationship of the occurrence of pharmaceutical compounds and a golf course that has been irrigated with regenerated water since 1973. Of the 14 analyzed groundwater samples, five wells were chosen to perform annual monitoring. Irrigation water and soil leachate were also evaluated. The target analytes were atenolol, metamizole, fluoxetine, ibuprofen, nicotine, permethrin, caffeine, and their metabolite paraxanthine. The environmental risk is limited as the concentrations of the pharmaceuticals measured in the sampled wells were always below 60 ng·L−1 (lower than the detected caffeine and nicotine concentrations). Wide variations for the same wells were measured among sampling campaigns, and also among the different wells. The study points to the importance of sample conservation during transport and the need to perform analyses immediately, or to follow an in-situ extraction procedure to carry concentrated samples under better conditions. [ABSTRACT FROM AUTHOR]

In the Canary Islands, there is a hydrological imbalance between water consumption and renewable water availability. To provide more water resources, reverse osmosis (RO) from seawater is used. As boron (B) contents in irrigation water higher than 0.7 mg/L may be dangerous for sensible plants, B concentration in RO water (ROW) may be one of the key factors of irrigation sustainability. Some orchards have been studied after they have used drip irrigation using different water qualities for 30 years. B in water, soils, and banana leaves was determined to check the sustainability of ROW irrigation. When irrigating with ROW, in which B concentration varies between 1.0 and 1.4 mgB/L, B content in banana soils seems to be stabilized at 5–7 mg/kg, and no toxicity has been observed in banana leaves. The proper water and soil management used by the local farmers probably prevent the accumulation of higher B levels in soils. Considering water consumption of 9000 m3∙ha−1∙year−1, 8−11 kgB∙ha−1∙year−1 is applied to the soil. The banana plant removes approximately 1 kgB∙ha−1∙year−1; therefore, only 10% of the total B added gets exported. This raises the following question: is it better to use membranes that are able to reduce B in ROW, increase the leaching fraction, or blend water? [ABSTRACT FROM AUTHOR]

Irrigation with reclaimed water (R) is necessary to guarantee the sustainability of semi-arid areas. Results obtained during a two years monitoring network (2009–2011) in Gran Canaria are presented, including the analysis of chemical parameters, N and S isotopes, priority substances (2008/105/EC, 2013/39/EU), other organic contaminants and heavy metals in groundwater and R used to irrigate a golf course. The aims of this work are to evaluate the contamination in a volcanic aquifer, relate the presence of organic contaminants and heavy metals with the hydrogeochemistry and identify pollution sources in the area. No priority substance exceeded the EU thresholds for surface water, although seventeen were detected in R. The most frequent compounds were hexachlorobenzene, chlorpyrifos ethyl, fluorene, phenanthrene and pyrene. These compounds were detected at low concentration, except chlorpyrifos. Chlorpyrifos ethyl, terbuthylazine, diuron, terbutryn, procymidone, atrazine and propazine exceeded the European threshold concentration for pesticides in groundwater (100 ng L − 1 ). Therefore, the priority substances chlorpyrifos ethyl and diuron must be included in monitoring studies. The priority pesticides chlorfenvinphos and diazinon were always detected in R but rarely in groundwater. Besides, the existence of contaminants not related to the current R irrigation has been identified. Absence of environmental problems related to heavy metals can be expected. The relationship among contaminant presence, hydrogeochemistry, including the stable isotopic prints of δ 18 O, δ 15 N and δ 34 S and preferential recharge paths has been described. The coastal well shows high values of EC, nitrate, a variable chemistry, and 50% of organic contaminants detected above 100 ng L − 1 . The well located in the recharge area presents a stable hydrochemistry, the lowest value of δ 15 N and the lowest contaminants occurrence. The area is an example of a complex volcanic media with several sources of contaminants such as leakages from septic tanks and sewerage, agriculture practices, irrigation with reclaimed water or urban runoff. [ABSTRACT FROM AUTHOR]

Abstract: In semiarid regions, reclaimed water can be an important source of emerging pollutants in groundwater. In Gran Canaria Island, reclaimed water irrigation has been practiced for over thirty years and currently represents 8% of water resources. The aim of this study was to monitor contaminants of emerging concern and priority substances (2008/105/EC) in a volcanic aquifer in the NE of Gran Canaria where the Bandama Golf Course has been sprinkled with reclaimed water since 1976. Reclaimed water and groundwater were monitoring quarterly from July 2009 to May 2010. Only 43% of the 183 pollutants analysed were detected: 42 pharmaceuticals, 20 pesticides, 12 polyaromatic hydrocarbons, 2 volatile organic compounds and 2 flame retardants. The most frequent compounds were caffeine, nicotine, chlorpyrifos ethyl, fluorene, phenanthrene and pyrene. Concentrations were always below 50ngL−1, although some pharmaceuticals and one pesticide, cholrpyrifos ethyl, were occasionally detected at higher concentrations. This priority substance for surface water exceeded the maximum threshold (0.1μgL−1) for pesticide concentration in groundwater (2006/118/EC). Sorption and degradation processes in soil account for more compounds being detected in reclaimed water than in groundwater, and that some contaminants were always detected in reclaimed water, but never in groundwater (flufenamic acid, propyphenazone, terbutryn and diazinon). Furthermore, erythromycin was always detected in reclaimed water (exceeding occasionally 0.1μgL−1), and was detected only once in groundwater. In contrast, some compounds (phenylephrine, nifuroxazide and miconazole) never detected in reclaimed water, were always detected in groundwater. This fact and the same concentration range detected for the groups, regardless of the water origin, indicated alternative contaminant sources (septic tanks, agricultural practices and sewerage breaks). The widespread detection of high adsorption potential compounds, and the independence of concentration with origin and depths, indicates the existence of preferential flows phenomena as potential contamination route in volcanic fractured materials. [Copyright &y& Elsevier]