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In the Wadi Um Had area, Central Eastern Desert, Egypt, NE-trending metapelitic and molasse-type successions are exposed. The metasediments bear the geochemical signature of a first depositional cycle in two distinct continental island arc settings that derived from incipiently-to moderately-weathered intermediate to felsic sources under generally warm and humid conditions. The metapelitic succession records three distinct episodes of metamorphism, M1–M3, whereas the molasse-type succession records only the last metamorphic episode, M3. M1/D1 records an amphibolite facies tectono-metamorphic event that has been dated at 625 ± 5 Ma, whereas M2/D2 records a greenschist facies subduction-related event. Collision of the two domains during a NE–SW shortening D3, culminated in formation of the macroscopic NW–SE-trending folds. D2 and D3 correlate with the gneiss-forming event, which is constrained at

The igneous rocks of the Wadi Hamad area are exposed in the northernmost segment of the Arabian–Nubian Shield (ANS). These rocks represent part of crustal section of Neoproterozoic continental island arc which is intruded by late to post-collisional alkali feldspar granites. The subduction-related intrusives comprise earlier gabbro–diorites and later granodiorites–granites. Subduction setting of these intrusives is indicated by medium- to high-K calc-alkaline affinity, Ta–Nb troughs on the spider diagrams and pyroxene and biotite compositions similar to those crystallized from arc magmas. The collisional alkali feldspar granites have high-K highly fractionated calc-alkaline nature and their spider diagrams almost devoid of Ta–Nb troughs. The earlier subduction gabbro–diorites have lower alkalis, LREE, Nb, Zr and Hf values compared with the later subduction granodiorites–granites, which display more LILE-enriched spider diagrams with shallower Ta–Nb troughs, reflecting variation of magma composition with arc evolution. The later subduction granitoids were generated by lower degree of partial melting of mantle wedge and contain higher arc crustal component compared with the earlier subduction gabbro–diorites. The highly silicic alkali feldspar granites represent extensively evolved melts derived from partial melting of intermediate arc crustal sources during the collisional stage. Re-melting of arc crustal sources during the collisional stage results in geochemical differentiation of the continental arc crust and the silicic collisional plutonism drives the composition of its upper part towards that of mature continental crust.

A suite of Neoproterozoic island arc volcanic and plutonic rocks are exposed in the Hamash area of the south Eastern Desert of Egypt. The volcanic assemblage includes metabasalt, a group of andesites with subordinate basalts (the Hamash Volcanics), and felsic volcanic porphyry. The plutonic rocks include a diorite-tonalite series, fine-grained granite, and granite porphyry. The volcanic rocks are generally sub-alkaline and feature a strong depletion in Nb and Ta. The metabasalt belongs to the low-K tholeiitic series and has nearly flat rare-earth element patterns. Its compositional characteristics indicate generation by partial melting of a depleted mantle source in an immature oceanic island arc setting. On the other hand, the basalt, andesite and felsic volcanic porphyry have low- to medium-K calc-alkaline affinity and are enriched in light rare-earth elements and large ion lithophile elements. Their parental magmas likely formed by fluid-assisted partial melting of a less depleted mantle source with major subduction input, in a mature island arc setting. The andesite cannot be derived from the basalt by fractional crystallization; their parental magmas likely represent different degrees of melting underneath crust of different thickness. Estimation of the arc crustal thickness during formation of these rocks yields ~ 5 km for the metabasalt, ~20 km for the Hamash basalt, and ~ 30 km for the Hamash andesite, consistent with a progression in maturity of the arc over time. The geochemical characteristics of the diorite-tonalite series suggest that it represents an intrusive equivalent of the medium-K calc-alkaline Hamash andesite, and the fine-grained granite represents residual liquid after continued fractionation of the parental magma of the andesite and diorite-tonalite. We present thermodynamic fractionation models that constrain the conditions of fractionation for the andesite, diorite-tonalite, and fine-grained granite suite. The compositional similarity of the granite and rhyolite porphyries, especially their SiO2 and Al2O3 contents and Y/Nb ratios, indicate generation by partial melting of similar crustal sources, although greater assimilation of upper crust is evident in elevated Rb/Sr ratios and K2O and light rare-earth element concentrations in the granite porphyry. We conclude that the magmatic rocks of the Hamash area represent an arc crustal section that records the evolution of a Neoproterozoic oceanic island arc. The arc was later caught up in the assembly of the northern Arabian-Nubian Shield.

The medium- to high-K calc-alkaline subduction-related Dokhan volcanic rocks of the Wadi Hamad area record two flare-up events during the history of a Neoproterozoic continental island arc, an early pulse dominated by andesite and a later pulse dominated by dacite. The trace element abundances and (La/Yb)_n ratios of the basalts, andesites and dacites all overlap, contrary to the expectations of a single fractional crystallization trend, suggesting the need for three distinct parental magmas for the three groups. The parental magmas of the basalts and andesites were generated by variable degrees of partial melting of subduction-metasomatized mantle, whereas that of the dacites requires mixing of mantle and crustal melts. The andesites and dacites both evolved mostly through fractionation of clinopyroxene and plagioclase, accompanied by apatite and Fe-Ti oxides in the more evolved dacitic rocks. Oscillatory and reverse zoning in clinopyroxene and plagioclase indicates that magma replenishment and mixing played a role in the genesis of the basalts and andesites. Depth-sensitive geochemical parameters show that the earlier andesites evolved at deeper levels in the arc crust compared with the later dacites, but not so deep as to stabilize garnet as a fractionating phase. Estimated values of the arc crust thickness indicate that the crust thickened from ∼35 km to ∼50 km from the time of basalt eruption to the time of andesite eruption, probably implying a high rate of crustal growth. The estimated arc crust thickness during the later subduction flare-up is slightly less than that of the earlier one despite ongoing magmatic addition, implying that arc crust delamination began before the production of the later dacites. The subduction-related geochemical characteristics of the Dokhan volcanic rocks suggest that the terminal collision between East and West Gondwana in the tip of the Nubian Shield occurred at ∼600 Ma.

The Neoproterozoic intrusive rocks of the Wadi Ranga area, Nubian Shield of Egypt, comprise gabbros and granitoids emplaced during oceanic island arc and post-collision stages. The plutonic rocks of the island arc stage include hornblende gabbros (Dabbah pluton), trondhjemite (Abu Ghalaga pluton) and tonalites with subordinate quartz gabbro and quartz diorite (Reidi and Abu Ghusun plutons), whereas the post-collision intrusives include granodiorite and monzogranite (Helifi-Hamata pluton). The gabbros and granitoids of the island arc stage are largely calcic, low-K rocks which have either tholeiitic (gabbro and trondhjemite) or transitional tholeiitic to calcalkaline nature (tonalites). On the other hand, the granitoids of the post-collision stage are medium to high-K calcalkaline rocks. All the investigated granitoids are metaluminous. The spider diagrams, with enrichment in LILE and strong Nb depletion, and the almost flat to slightly LREE-depleted REE patterns of the gabbro and trondhjemite are similar to those of the Wadi Ranga low-K tholeiitic basalts and silicic volcanics, respectively, suggesting that the gabbro and trondhjemite are the plutonic equivalents of the Wadi Ranga immature island arc extrusives, and they were derived from mantle source at the early immature island arc stage. Similar to the trondhjemite, the tonalites show LILE enrichment and strong Nb depletions on the MORB-normalized spider diagrams. However, the tonalites have REE patterns which are enriched in LREE (La/Yb = 1.71–5.54). The derivation of the tonalites through fractionation of the same magma produced the trondhjemite seems unlikely. Therefore, high degree partial melting of juvenile basaltic arc crust is favoured for the origin of tonalites during a late immature island arc stage. The post-collision granitoids show considerable enrichment in LILE and to a lesser extent in HFSE, slight negative Nb anomaly and strong negative P and Ti anomalies relative to N-MORB. Their REE patterns are LREE-enriched (La/Yb = 5–19), with negative Eu anomaly. These characteristics are consistent with origin through lower degrees of partial melting of old basaltic arc crust and subsequent fractional crystallization. The geochemical characteristics of the trondhjemite and tonalites, and the granodiorite–monzogranite classify them as M-type and I-type granitoids, respectively. The partly tholeiitic intrusives of the Wadi Ranga area (South Eastern Desert) have lower K2O, Rb and LREE compared to the M-type calcalkaline intrusives of the North Eastern Desert, implying northwardly dipping subduction zone. The geochemical similarities between the intrusives of Neoproterozoic and Phanerozoic oceanic island arcs imply that they share similar style of subduction, which differs from that of the Archaean. The generation of high SiO2 (up to 74.5 wt%), low K2O (0.56–1.78 wt%) and slightly LREE-depleted trondhjemite in early immature oceanic island arc setting supports the arc origin of the primitive continental crust. Silicic magma production through partial melting of the early arc volcanic rocks during the evolution of the arc and the post-collision stage, drives the middle and upper oceanic arc crust towards a composition closer to that of the continental crust. The present study indicates that the intra-oceanic island arcs continued to play a role in the generation of the continental crust after the Archaean.