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Complex organic molecules (COMs) may have played a role in the formation of life in the early Earth (Herbst & van Dishoeck (2009)). Here we present the formation of NH2CHO and CH3CHO upon vacuum-ultraviolet (VUV) irradiation of CO:NH3 and CO:CH4 ice mixtures, simulating the UV processing of interstellar ices in the interior of dense clouds. We have found that the conversion from ${\rm{N}}{{\rm{H}}_{\dot 2}}$ radicals to NH2CHO is 4–15 times higer than that from ${\rm{N}}{{\rm{H}}_{\dot 3}}$ to CH3CHO, probably due to the competing formation of larger hydrocarbons in the latter case. [ABSTRACT FROM AUTHOR]

The gas and dust rich disks around young stars are the formation sites of planets. Observations of molecular trace species have great potential as probes of the disk structures and volatile compositions that together regulate planet formation. The disk around young star TW Hya has become a template for disk molecular studies due to a combination of proximity, a simple face-on geometry and richness in volatiles. It is unclear, however, how typical the chemistry of the TW disk is. In this proceeding, we review lessons learnt from exploring the TW Hya disk chemistry, focusing on the CO snowline, and on deuterium fractionation chemistry. We compare these results with new ALMA observations toward more distant, younger disks. We find that while all disks have some chemical structures in common, there are also substantial differences between the disks, which may be due to different initial conditions, structural or chemical evolutionary stages, or a combination of all three. [ABSTRACT FROM AUTHOR]

Water ice is the dominant constituent of icy grain mantles in the interstellar medium, and as such one of the most abundant species during all stages of star and planet formation. Its formation through atom addition reactions on grain surfaces, its destruction through different desorption channels, and its influence on the chemistry and desorption efficiencies of other species in icy grain mantles have all been the objects of intense study. This contribution reviews our current understanding of these processes, and the laboratory experiments that have been instrumental in establishing the existing paradigm. [ABSTRACT FROM PUBLISHER]

The distributions of deuterated molecules in protoplanetary disks are expected to depend on themolecular formation pathways. We use observations of spatially resolved DCN emission from the disk around TW Hya, acquired during ALMA science verification with a ~3“ synthesized beam, together with comparable DCO+ observations from the Submillimeter Array, to investigate differences in the radial distributions of these species and hence differences in their formation chemistry. In contrast to DCO+, which shows an increasing column density with radius, DCN is better fit by a model that is centrally peaked. We infer that DCN forms at a smaller radii and thus at higher temperatures than DCO+. This is consistent with chemical network model predictions of DCO+ formation from H2D+ at T < 30 K and DCN formation from additional pathways involving CH2D+ at higher temperatures. We estimate a DCN/HCN abundance ratio of ~0.017, similar to the DCO+/HCO+ abundance ratio. Deuterium fractionation appears to be efficient at a range of temperatures in this protoplanetary disk. These results suggest caution in interpreting the range of deuterium fractions observed in solar system bodies, as multiple formation pathways should be taken into account. [ABSTRACT FROM AUTHOR]

We present millimeter-wave observations of several molecular ions in the disk around the pre-main-sequence star DM Tau and use these to investigate the ionization fraction in different regions of the disk. New Submillimeter Array (SMA) observations of H2D+ J = 11.0-11.1, N2H+ J = 4-3, and CO J = 3-2 are presented. H2D+ and N2H+ are not detected and using the CO 3-2 disk size the observations result in an upper limit of <0.47 K km s-1 for both lines, a factor of 2.5 below previous single-dish H2D+ observations. Assuming LTE, a disk midplane temperature of 10-20 K and estimates of the H2D+ o/p ratio, the observed limit corresponds to Due to image rights restrictions, multiple line equation(s) cannot be graphically displayed. We adopt a parametric model for the disk structure from the literature and use new IRAM 30 m telescope observations of the H13CO+ J = 3-2 line and previously published SMA observations of the N2H+ J = 3-2, HCO+ J = 3-2, and DCO+ J = 3-2 tines to constrain the ionization fraction, xi, in three temperature regions in the disk where theoretical considerations suggest different ions should dominate: (1) a warm, upper layer with T >20 K where CO is in the gas phase and HCO+ is most abundant, where we estimate xi ≃ 4 x 10-10; (2) a cooler molecular layer with T = 16-20 K where N2H+ and DCO+ abundances are predicted to peak, with xi ≃ 3 x 10-11; and (3) the cold, dense midplane with T <16 K where Due to image rights restrictions, multiple line equation(s) cannot be graphically displayed and its deuterated isotopologues are the main carriers of positive charge, with xi < 3 x 10-10. While there are considerable uncertainties, these estimates are consistent with a decreasing ionization fraction into the deeper, colder, and denser disk layers. Stronger constraints on the ionization fraction in the disk midplane will require not only substantially more sensitive observations of the H2D+ 11.0-11.1 line, but also robust determinations of the o/p ratio, observations of D2H+, and stronger constraints on where N2 is present in the gas phase. [ABSTRACT FROM AUTHOR]

Ices regulate much of the chemistry during star formation and account for up to 80% of the available oxygen and carbon. In this paper, we use the Spitzer c2d Legacy ice survey, complimented with data sets on ices in cloud cores and high-mass protostars, to determine standard ice abundances and to present a coherent picture of the evolution of ices during low- and high-mass star formation. The median ice composition H2O:CO:CO2:CH3OH:NH3:CH4:XCN is 100:29:29:3:5:5:0.3 and 100:13:13:4:5:2:0.6 toward low- and high-mass protostars, respectively, and 100:31:38:4:-:-:- in cloud cores. In the low-mass sample, the ice abundances with respect to H2O of CH4, NH3, and the component of CO2 mixed with H2O typically vary by <25%, indicative of co-formation with H2O. In contrast, some CO and CO2 ice components, XCN, and CH3OH vary by factors 2-10 between the lower and upper quartile. The XCN band correlates with CO, consistent with its OCN- identification. The origin(s) of the different levels of ice abundance variations are constrained by comparing ice inventories toward different types of protostars and background stars, through ice mapping, analysis of cloud-to-cloud variations, and ice (anti-)correlations. Based on the analysis, the first ice formation phase is driven by hydrogenation of atoms, which results in an H2O-dominated ice. At later prestellar times, CO freezes out and variations in CO freezeout levels and the subsequent CO-based chemistry can explain most of the observed ice abundance variations. The last important ice evolution stage is thermal and UV processing around protostars, resulting in CO desorption, ice segregation, and the formation of complex organic molecules. The distribution of cometary ice abundances is consistent with the idea that most cometary ices have a protostellar origin. [ABSTRACT FROM AUTHOR]

Gas-phase complex organic molecules are commonly detected toward high-mass protostellar hot cores. Detections toward low-mass protostars and outflows are comparatively rare, and a larger sample is the key to investigate how the chemistry responds to its environment. Guided by the prediction that complex organic molecules form in CH3OH-rich ices and thermally or non-thermally evaporate with CH3OH, we have identified three sight lines in the Serpens core--SMM1, SMM4, and SMM4-W--which are likely to be rich in complex organics. Using the IRAM 30 m telescope, narrow lines (FWHM of 1-2 km s-1) of CH3CHO and CH3OCH3 are detected toward all sources, HCOOCH3 toward SMM1 and SMM4-W, and C2H5OH not at all. Beam-averaged abundances of individual complex organics range between 0.6% and 10% with respect to CH3OH when the CH3OH rotational temperature is applied. The summed complex organic abundances also vary by an order of magnitude, with the richest chemistry toward the most luminous protostar SMM 1. The range of abundances compare well with other beam-averaged observations of low-mass sources. Complex organic abundances are of the same order of magnitude toward low-mass protostars and high-mass hot cores, but HCOOCH3 is relatively more important toward low-mass protostars. This is consistent with a sequential ice photochemistry, dominated by CHO-containing products at low temperatures and early times. [ABSTRACT FROM AUTHOR]

This is the second in a series of papers based on data from DISCS, a Submillimeter Array observing program aimed at spatially and spectrally resolving the chemical composition of 12 protoplanetary disks. We present data on six Southern sky sources-TM Lup, SAO 206462 (HD 135344b), HD 142527, AS 209, AS 205, and V4046 Sgr-which complement the six sources in the Taurus star-forming region reported previously. CO 2-1 and HCO+ 3-2 emission are detected and resolved in all disks and show velocity patterns consistent with Keplerian rotation. Where detected, the emission from DCO+ 3-2, N2H+ 3-2, H2CO 303 202 and 414 - 313, HCN 3-2, and CN 233/4/2 - 122/3/1 are also generally spatially resolved. The detection rates are highest toward the M and K stars, while the F star SAO 206462 has only weak CN and HCN emission, and H2CO alone is detected toward HD 142527. These findings together with the statistics from the previous Taurus disks support the hypothesis that high detection rates of many small molecules depend on the presence of a cold and protected disk midplane, which is less common around F and A stars compared to M and K stars. Disk-averaged variations in the proposed radiation tracer CN/HCN are found to be small, despite a two orders of magnitude range of spectral types and accretion rates. In contrast, the resolved images suggest that the CN/HCN emission ratio varies with disk radius in at least two of the systems. There are no clear observational differences in the disk chemistry between the classical/full T Tauri disks and transitional disks. Furthermore, the observed line emission does not depend on the measured accretion luminosities or the number of infrared lines detected, which suggests that the chemistry outside of 100 AU is not coupled to the physical processes that drive the chemistry in the innermost few AU. [ABSTRACT FROM AUTHOR]

It has been a long standing problem in astrochemistry to explain how molecules can form in a highly dilute environment such as the interstellar medium. In the last decennium more and more evidence has been found that the observed mix of small and complex, stable and highly transient species in space is the cumulative result of gas phase and solid state reactions as well as gas-grain interactions. Solid state reactions on icy dust grains are specifically found to play an important role in the formation of the more complex “organic” compounds. In order to investigate the underlying physical and chemical processes detailed laboratory based experiments are needed that simulate surface reactions triggered by processes as different as thermal heating, photon (UV) irradiation and particle (atom, cosmic ray, electron) bombardment of interstellar ice analogues. Here, some of the latest research performed in the Sackler Laboratory for Astrophysics in Leiden, the Netherlands is reviewed. The focus is on hydrogenation, i.e., H-atom addition reactions and vacuum ultraviolet irradiation of interstellar ice analogues at astronomically relevant temperatures. It is shown that solid state processes are crucial in the chemical evolution of the interstellar medium, providing pathways towards molecular complexity in space. [ABSTRACT FROM PUBLISHER]

Icy grain mantles are commonly observed through infrared spectroscopy toward dense clouds, cloud cores, protostellar envelopes and protoplanetary disks. Up to 80% of the available oxygen, carbon and nitrogen are found in such ices; the most common ice constituents – H2O, CO2 and CO – are second in abundance only to H2 in many star forming regions. In addition to being a molecular reservoir, ice chemistry is responsible for much of the chemical evolution from H2O to complex, prebiotic molecules. Combining the exisiting ISO, Spitzer, VLT and Keck ice data results in a large sample of ice sources (~80) that span all stages of star formation and a large range of protostellar luminosities (<0.1–105 L⊙). Here we summarize the different techniques that have been applied to mine this ice data set on information on typical ice compositions in different environments and what this implies about how ices form and evolve during star and planet formation. The focus is on how to maximize the use of empirical constraints from ice observations, followed by the application of information from experiments and models. This strategy is used to identify ice bands and to constrain which ices form early during cloud formation, which form later in the prestellar core and which require protostellar heat and/or UV radiation to form. The utility of statistical tests, survival analysis and ice maps is highlighted; the latter directly reveals that the prestellar ice formation takes place in two phases, associated with H2O and CO ice formation, respectively, and that most protostellar ice variation can be explained by differences in the prestellar CO ice formation stage. Finally, special attention is paid to the difficulty of observing complex ices directly and how gas observations, experiments and models help in constraining this ice chemistry stage. [ABSTRACT FROM PUBLISHER]

NH3 and CH3OH are key molecules in the chemical networks leading to the formation of complex N- and O-bearing organic molecules. However, despite a number of recent studies, there is still a lot to learn about their abundances in the solid state and how they relate to those of other N/O-bearing organic molecules or to NH3 and CH3OH abundances in the gas phase. This is particularly true in the case of low-mass young stellar objects (YSOs), for which only the recent advent of the Spitzer Space Telescope has allowed high sensitivity observations of the ices in their enveloppes. We present a combined study of Spitzer data (obtained within the Legacy program “From Molecular Cores to Planet-Forming Disks”, c2d) and laboratory spectra, leading to the detections of NH3 and CH3OH in the ices of low-mass protostars. We investigate correlations with other ice features and conclude with prospects on further studies linking these two precursors of complex organic molecules with their gas-phase products. [ABSTRACT FROM PUBLISHER]