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Zr57Cu15Ni10Nb5 (more known as Vit-106) is a promising zirconium-based alloy with a high glass-forming ability, and belongs to the so-called bulk metallic glasses (BMG). Workpieces with a size of around one centimeter in all three dimensions can be obtained from a BMG alloy by casting. However, further increasing the cast size decreases the cooling rate and thus induces crystallization. Selective laser melting (SLM) is a well-known technique to overcome size limitations for BMGs because a workpiece is built by the addition of multiple melt portions in which the cooling rate is kept above the critical one. Currently, BMG parts obtained by SLM suffer from partial crystallization. The present work studies the influence of SLM process parameters on the partial crystallization of Vit-106 by metallography and the influence of the microstructure on mechanical properties by microhardness and wear resistance testing. Submicron crystalline inclusions are observed in an amorphous matrix of a Vit-106 alloy obtained by SLM. The size and the concentration of the inclusions can be controlled by varying the laser scanning speed. It is shown that submicron crystalline inclusions formed in the amorphous matrix during SLM can favorably affect microhardness and wear resistance. [ABSTRACT FROM AUTHOR]

A uniform distribution of power density (energy flux) in a stationary laser beam leads to a decrease in the overheating of the material in the center of the laser beam spot during laser powder bed fusion and a decrease in material losses due to its thermal ablation and chemical decomposition. The profile of the uniform cylindrical (flat-top) distribution of the laser beam power density was compared to the classical Gaussian mode (TEM00) and inverse Gaussian (donut) distribution (airy distribution of the first harmonic, TEM01* = TEM01 + TEM10). Calculation of the Péclet number, which is a similarity criterion characterizing the relationship between convective and molecular processes of heat transfer (convection to diffusion) in a material flow in the liquid phase, shows that the cylindrical (flat-top) distribution (TEM01* + TEM00 mode) is effective in a narrow temperature range. TEM00 shows the most effective result for a wide range of temperatures, and TEM01* is an intermediate in which evaporation losses decrease by more than 2.5 times, and it increases the absolute laser bandwidth when the relative bandwidth decreases by 24%. [ABSTRACT FROM AUTHOR]