1. Construction of multiple electron transfer paths in 1D core-shell hetetrostructures with MXene as interlayer enabling efficient microwave absorption
- Author
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Baojun Wang, Shipeng Wang, Fangzhi Huang, Qiangchun Liu, F.-Q. Liu, Shikuo Li, and Hui Zhang
- Subjects
Nanocomposite ,Materials science ,business.industry ,Attenuation ,Reflection loss ,Heterojunction ,General Chemistry ,Carbon nanotube ,law.invention ,law ,Optoelectronics ,General Materials Science ,business ,Absorption (electromagnetic radiation) ,Microwave ,Nanosheet - Abstract
The exploitation of multicomponent nanocomposites with suitable hierarchical heterostructures is an attractive strategy to obtain high performance microwave absorption materials. In this work, a versatile strategy is proposed for synthesizing 1D hierarchical core-shell structure with Co-ZIF arrays derived carbon nanotubes (CNTs) coupled on cotton fiber (CF)-supported MXene shell (Co/CNTs-MXene@CF). The advantages of Co-ZIF arrays derived CNTs and MXene dielectric layer can be efficiently integrated to realize multiple electron transfer paths by the construction of the well-designed hierarchical structure. The designed heterogeneous composites consist of the interlayer MXene and CNTs grow sequentially from the outermost Co-ZIF nanosheet arrays with appropriate conductivity and abundant heterointerfaces, which can improve the conduction loss and interfacial polarization response. As expected, the elaborate 1D Co/CNTs-MXene@CF heterostructures exhibit the optimal reflection loss of −61.41 dB at 2.52 mm and effective absorption bandwidth reaches 5.04 GHz with a thickness of only 1.5 mm. The experimental results demonstrate that the optimized structure dramatically improves the electromagnetic wave attenuation behavior. This work illuminates a new design strategy for the preparation of multicomponent composites with reasonable hierarchical structure that enables high-performance microwave absorption materials.
- Published
- 2022
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