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1. Selective Reductive Cleavage of Inert Aryl CO Bonds by an Iron Catalyst.

Author

Ren, Yunlai, Yan, Mengjie, Wang, Jianji, Zhang, Z. Conrad, and Yao, Kaisheng

Subjects
*IRON catalysts, *CARBON cycle, *SCISSION (Chemistry), *AROMATIC compounds, *LIGNINS, *HIGH temperatures
Abstract

Breaking point: An effective reductive cleavage of inert aryl CO bonds with an inexpensive iron catalyst has been developed. During this process, the reduction of the arene rings was not observed. This catalytic system also enabled the selective cleavage of the β‐O‐4 linkage of lignin model compounds under an atmosphere of hydrogen, thus offering an opportunity for the depolymerization of lignin. [ABSTRACT FROM AUTHOR]

Published
2013
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