10 results on '"Wang, Fangfang"'
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2. Theoretical understanding of SnS monolayer as Li ion battery anode material.
- Author
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Wang, Fangfang, Yao, Qiushi, Zhou, Liyu, Ma, Zhen, He, Mingxue, and Wu, Fang
- Subjects
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LITHIUM-ion batteries , *MONOMOLECULAR films , *SULFIDES analysis , *ELECTRON donor-acceptor complexes , *BINDING energy , *ANODES - Abstract
Ideal Li-ion battery materials should have a low Li-ion diffusion barrier and a suitable binding energy. Here, first-principles calculations were performed to investigate the potential of SnS monolayer as a Li-ion battery material. Our study reveals that Li ions can be strongly bonded on the SnS monolayer with a binding energy of around 2 eV, and donate electrons into the SnS monolayer. Consequently, Li intercalation of SnS monolayer gives rise to a semiconducting to metallic transition, and leads to a good electrical conductivity. Interestingly, in spite of the existence of strong chemical interaction, the energy barrier (0.45 eV) of Li diffusion on the SnS monolayer is quite low. Moreover, the estimated open circuit voltage is about 1.98 V, which is much better than that of commercial graphite. Thus, given these advantages, it is expected that SnS monolayer will be a promising anode material for Li ion batteries. [ABSTRACT FROM AUTHOR]
- Published
- 2018
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3. Recovery of valuable materials from spent lithium-ion batteries by mechanical separation and thermal treatment.
- Author
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Wang, Fangfang, Zhang, Tao, He, Yaqun, Zhao, Yuemin, Wang, Shuai, Zhang, Guangwen, Zhang, Yu, and Feng, Yi
- Subjects
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GRAPHITE , *LITHIUM-ion batteries , *SPENT catalysts , *SEPARATION (Technology) , *HEAT treatment , *FLOTATION - Abstract
In this paper, a mechanical separation and thermal treatment process is developed to recover valuable metals and graphite from the −0.25 mm crushed products of spent lithium-ion batteries (LiBs). Effect of key parameters for roasting such as the temperature and roasting time are investigated to determine the most efficient conditions for surface modification of the mixed electrode materials by roasting. The roasted mixed electrode materials are separated by flotation operation to recover the cathode material and anode materials respectively. The results show that most of the organic outer layer coated on the surface of the mixed electrode materials can be removed at the temperature of 450 °C for 15 min. After roasting treatment, the original wettability of LiCoO 2 and graphite is regained. The −0.25 mm crushed products of spent LiBs can be separated into LiCoO 2 concentrate and graphite concentrate by flotation process efficiently. The enrichment ratios of Co, Mn, Cu and Al are 1.35, 1.29, 1.25 and 1.19, their recovery rates are 97.66%, 93.66%, 90.14% and 86.29%, respectively. This process proposed for the recovery of valuable materials is simple and of high efficient for the spent lithium-ion batteries recycling industry. [ABSTRACT FROM AUTHOR]
- Published
- 2018
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- View/download PDF
4. Simple synthesis of novel hierarchical porous carbon microspheres and their application to rechargeable lithium-ion batteries.
- Author
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Wang, Fangfang, Song, Ranran, Song, Huaihe, Chen, Xiaohong, Zhou, Jisheng, Ma, Zhaokun, Li, Mochen, and Lei, Qian
- Subjects
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MICROSPHERES , *POROUS materials , *CHEMICAL synthesis , *LITHIUM-ion batteries , *MICROPORES , *MESOPORES , *FORMALDEHYDE , *ANODES - Abstract
Novel hierarchical porous carbon microspheres (HPCM) with quantities of micropores and mesopores have been prepared by an alcohol-in-oil emulsion technique using thermoplastic phenolic formaldehyde resin (PF) as the carbon source and copper nitrate (CN) as the template precursor. The effects of CN loading content on the morphology and structure of HPCM were investigated. The results showed that, when the mass ratio of PF and CN is 1:4, the HPCM not only can maintain hierarchical porous microsphere structure, but also display high electrochemical performance with a reversible capacity of 585 mA h g −1 at a current density of 50 mA g −1 and favorable high-rate performance when used as the anode materials for lithium-ion batteries. [ABSTRACT FROM AUTHOR]
- Published
- 2015
- Full Text
- View/download PDF
5. Poly-dopamine carbon-coated stable silicon/graphene/CNT composite as anode for lithium ion batteries.
- Author
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Wang, Fangfang, Lin, Song, Lu, Xuesong, Hong, Ruoyu, and Liu, Huiyong
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LITHIUM-ion batteries , *POLYELECTROLYTES , *GRAPHENE , *ANODES , *SILICON , *CARBON nanotubes , *DOPAMINE - Abstract
To buffer the volume expansion of silicon during charge-discharge process, a 3D carbon-coated stable silicon/graphene/CNT (C@Si/GN/CNT/PDA-C) composite was prepared. Si nanoparticles (SiNPs) were first modified by hexadecyl trimethyl ammonium bromide (CTAB) to enhance their stability and dispersibility in water, then uniformly distributed in graphene/carbon nanotubes (GN/CNT) by electrostatic self-assembly, and ultimately encapsulated by carbonized poly-dopamine carbon layer (PDA-C) at high-temperature. PDA-C not only alleviates the volume expansion of Si and inhibits the direct contact of Si with electrolyte, but also acts as a bridge between the conductive GN/CNT and Si to maintain electrode integrity. As an anode material for lithium-ion batteries, the C@Si/GN/CNT/PDA-C exhibits a superior reversible capacity of 1946 mAh g − 1 after 100 cycles with the capacity retention of 68.9% at a current density of 0.1 A g − 1, and over 1306 mAh g − 1 after 100 cycles at 1 A g − 1. The excellent electrochemical performance of C@Si/GN/CNT/PDA-C is attributed to the stable hierarchical structure. [Display omitted] [ABSTRACT FROM AUTHOR]
- Published
- 2022
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6. High-performance anode of lithium ion batteries with plasma-prepared silicon nanoparticles and a three-component binder.
- Author
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Wang, Fangfang, Zhang, Xing, Hong, Ruoyu, Lu, Xuesong, Zhu, Yuan, and Zheng, Ying
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LITHIUM-ion batteries , *PLASMA arcs , *SILICON , *AMORPHOUS silicon , *NON-thermal plasmas , *ANODES , *POLYMERS - Abstract
• The crystalline silicon nanoparticles coated with an amorphous silicon layer (a-coated-c-SiNPs) were continuously prepared by non-thermal plasma pyrolyzing of silane with the help of hydrogen and argon. • The a-Si layer with good tolerance to volume expansion prevented the electrode pulverization, while the c-Si improved the electronic conductivity. The crystallinity of the a-coated-c-SiNPs was controled by the hydrogen etching. • The combination of a-coated-c-SiNPs with a three-component polymer binder (PAA-PVA/SBR) improved the electrochemical performance of Si-based anode. The crystalline silicon nanoparticles coated with an amorphous silicon layer was prepared by continuously pyrolysing the mixture of silane and hydrogen in a non-thermal arc plasma reactor. The hydrogen in the gas mixture effectively controls the thickness of the amorphous silicon layer and further improves the electrochemical performance of the silicon anode. The mechanism of the hydrogen was investigated by experiments. At the same time, a three-component polymer binder was concocted and introduced to tolerate the volume expansion of silicon effectively. Combining the silicon nanoparticles prepared at the optimal conditions with the novel polymer binder, the resulting silicon anode exhibits excellent electrochemical performance of 2120 mAh g−1 at 400 mA g−1 after 100 cycles. [Display omitted] [ABSTRACT FROM AUTHOR]
- Published
- 2021
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7. Vacancy engineering in Co-doped CuS1-x with fast Electronic/Ionic migration kinetics for efficient Lithium-Ion batteries.
- Author
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Yang, Fan, Xu, Liangliang, Gao, Ying, Chen, Changdong, Lu, Caiyun, and Wang, Fangfang
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ELECTRIC batteries , *DOPING agents (Chemistry) , *LITHIUM-ion batteries , *ION energy , *LITHIUM sulfur batteries , *ENERGY conversion , *CHARGE exchange , *GEOLOGICAL carbon sequestration - Abstract
The doping of Co heteroatom in the CuS lattice can optimize the electronic structure of CuS, provide more active sites for the adsorption of lithium ions and form more suitable diffusion paths for rapid transport of Li-ion in Cu 2 S 2 layers, thereby resulting in enhanced cycling performance. [Display omitted] • N -type Co doped CuS 1-x with abundant S vacancies in its structure is firstly used as anode material in lithium-ion batteries. • Cobalt doping simultaneously improves Li ion migration and electron transfer kinetics. • A highly conductive and active sites adjacet to the Co atoms are conducive to more rapid electron transfer and energy conversion. • Co-doped CuS 1-x shows impressive rate capability and long cycling stability as the anode material of lithium-ion batteries. Slow Li ion diffusion kinetics and disordered migration of electrons are two most crucial obstacles to be resolved in electrode material design for higher rate capability of Li-ion batteries. Herein, the Co-doped CuS 1- x with abundant high active S vacancies is proposed to accelerate the electronic and ionic diffusion during the energy conversion process, because contraction of Co-S bond can cause the expansion of atomic layer spacing, thus promoting the Li ion diffusion and directional electron migration parallel to the Cu 2 S 2 plane, and also induce the increasing of active sites to improve the Li+ adsorption and electrocatalytic conversion kinetics. Especially, the electrocatalytic studies and plane charge density difference simulations demonstrate that electron transfer near the Co site is more frequent, which is conducive to more rapid energy conversion and storage. Those S vacancies formed by Co-S contraction in CuS 1- x structure obviously increase Li ion adsorption energy in Co-doped CuS 1- x to 2.21 eV, higher than the 2.1 eV for CuS 1- x and 1.88 eV for CuS. Taking these advantages, the Co-doped CuS 1- x as anode of Li-ion batterie shows an impressive rate capability of 1309 mAh·g−1 at 1A g−1, and long cycling stability (retaining 1064 mAh·g−1 capacity after 500 cycles). This work provides new opportunities for the design of high-performance electrode material for rechargeable metal-ion batteries. [ABSTRACT FROM AUTHOR]
- Published
- 2023
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8. Recovery of LiCoO2 and graphite from spent lithium-ion batteries by Fenton reagent-assisted flotation.
- Author
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He, Yaqun, Zhang, Tao, Wang, Fangfang, Zhang, Guangwen, Zhang, Weigang, and Wang, Jie
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ELECTRODE manufacturing , *THERMAL properties of graphite , *CHEMICAL reagents , *FENTON'S reagent , *LITHIUM-ion batteries - Abstract
In this paper, a Fenton reagent assisted flotation process is developed to recover valuable electrode materials LiCoO 2 and graphite from spent lithium-ion batteries (LiBs). At room temperature, effect of key parameters for Fenton reaction such as the ratios of H 2 O 2 /Fe 2+ (40–280) and liquid-solid (25–100) are investigated to determine the most efficient conditions of surface modification of electrode materials by Fenton reagent. The modified electrode materials are separated by flotation operation to recover the cathode material and anode materials respectively. The results show that in the optimum conditions that the Fe 2+ /H 2 O 2 ratio is 1:120, and the liquid-solid ratio is 75:1, most of the organic outer layer coated on the surface of electrode materials can be removed. After modified by Fenton reagent, the original wettability of LiCoO 2 and graphite is regained. The −0.25 mm crushed products of spent LiBs can be separated into LiCoO 2 concentrate and graphite concentrate by flotation process efficiently. [ABSTRACT FROM AUTHOR]
- Published
- 2017
- Full Text
- View/download PDF
9. Graphyne Nanotubes as Promising Sodium-Ion Battery Anodes.
- Author
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Yuan, Yuan, Song, Xiaoxue, Ma, Jiapeng, Chen, Yanqi, Wang, Fangfang, Kang, Baotao, and Lee, Jin Yong
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CARBON foams , *FOAM , *SODIUM ions , *ANODES , *NANOTUBES , *DENSITY functional theory , *LITHIUM-ion batteries - Abstract
Sodium-ion batteries (SIBs) are promising candidates for the replacement of lithium-ion batteries (LIBs) because of sodium's abundant reserves and the lower cost of sodium compared to lithium. This is a topic of interest for developing novel anodes with high storage capacity. Owing to their low cost, high stability, and conductivity, carbon-based materials have been studied extensively. However, sp2-C based carbon materials have low-rate capacities. Intensive density functional theory calculations have been implemented to explore the applicability of α, β, and γ graphyne nanotubes (αGyNTs, βGyNTs, and γGyNTs, respectively) as SIB anodes. Results suggest that (3, 0)-αGyNT, (2, 2)-βGyNT, and (4, 0)-γGyNT have, respectively, maximum Na storage capacities of 1535, 1302, and 1001 mAh/g, which exceeds the largest reported value of carbon materials (N-doped graphene foams with 852.6 mAh/g capacity). It was determined that αGyNTs have the largest storage capacity of the three types because they possess the largest specific surface area. Moreover, the larger pores of αGyNTs and βGyNTs allow easier diffusion and penetration of Na atoms compared to those of γGyNTs, which could result in better rate capacity. [ABSTRACT FROM AUTHOR]
- Published
- 2022
- Full Text
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10. Chemical and process mineralogical characterizations of spent lithium-ion batteries: An approach by multi-analytical techniques.
- Author
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Zhang, Tao, He, Yaqun, Wang, Fangfang, Ge, Linhan, Zhu, Xiangnan, and Li, Hong
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MINERALOGY , *LITHIUM-ion batteries , *HYDROCARBONS , *LASER-induced breakdown spectroscopy , *PARTICLES - Abstract
Highlights: [•] Crushed products can be divided into three parts based on the main composition. [•] A certain kind of hydrocarbon is found coated on the surface of fine particles. [•] A flowsheet to recycle spent LiBs is proposed according to multi-analysis results. [ABSTRACT FROM AUTHOR]
- Published
- 2014
- Full Text
- View/download PDF
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