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Voluminous moderate- to high-magnesian [Mg# = molar Mg/(Mg + Fe2+) = 44–64] andesitic and dacitic rocks with high silica (mostly 61–66 wt%) adakitic affinity (Y = 13–22, Yb = 1.3–2.1, Sr/Y = 18–44, La/Yb = 10–25) and common mafic magmatic enclaves (MMEs) are first reported in the Keçiboyduran stratovolcano (KSV) from the Cappadocia volcanic province (CVP), Central Anatolia, Turkey. We present comprehensive whole-rock geochemistry and Sr–Nd–Pb isotope data, mineral chemical compositions and 40Ar–39Ar ages for KSV samples. Based on the volcanostratigraphy and 40Ar–39Ar dating results, two successive eruption ages of 2.2–1.6 Ma (stage I: amphibole-rich) and 1.6–1.2 Ma (stage II: pyroxene-rich) were established for the KSV, corresponding to the Gelasian and Calabrian stages of Early Pleistocene, respectively. Textural and geochemical evidence indicates that the KSV magnesian andesites–dacites are products of a hybrid magma formed by mixing between mantle-derived mafic and crust-derived felsic magmas with further fractionation and minor contamination during magma storage and ascent. Our new data, combined with previous geological and geophysical results suggest that parental magnesian mafic melts of the KSV rocks originated from a heterogenous mantle source generated through the metasomatism of mantle wedge material by subducted sediment-derived melts, and then partially melted through asthenospheric upwelling in response to slab break-off. The mafic magma underplated the overlying lower crust, resulting in its partial melting to generate crustal felsic magma. Both magmas mixed at lower crustal levels creating MME-rich hybrid magmas. Subsequently, the hybrid magmas were emplaced at different depths of the crust (c. 4–11 and 11–15 km for the stage I and II, respectively), where they crystallized at moderate temperatures (c. 1180–840 °C) and under relatively high oxygen fugacity (LogƒO2 = − 11.4 to − 9.2), water-rich (H2Omelt = 5.6–3.6 wt%) and polybaric (~ 1.2 to 5.1 kbars) conditions, and underwent fractionation of primarily amphibole ± pyroxene causing adakitic affinity. We propose a new petrogenetic model for the early Quaternary magnesian/adakitic andesites/dacites of the CVP in a post-subduction tectonic setting. Our results provide robust evidence for slab break-off of the eastern Cyprus oceanic lithosphere and put further constraints on the tectonic evolution of the eastern Mediterranean collision zone during the Early Quaternary. [ABSTRACT FROM AUTHOR]

The timing of major tectonic events and the driving mechanisms for magma generation during Late Cenozoic convergence and collision between Arabia and Eurasia still remain unknown. The Sakarya Zone (SZ) in northern Turkey is a critical member of this collisional assemblage. In the easternmost part of the SZ, we have recognized a Late Miocene volcanic suite termed the Çağirankaya volcanics which displays characteristic post-collisional geochemical features. Here, we report a new data set of zircon U Pb ages, whole-rock major and trace element, as well as Sr Nd isotope analyses for dacite and andesite samples from the Çağirankaya volcanics. Zircon U Pb ages for a selected dacitic lava sample average 5.16 ± 0.11 Ma (mean square of weighted deviates, MSWD = 0.45, n = 35), confirming a late Miocene age of this volcanic episode. The high-K calc-alkaline andesites and dacites exhibit an adakite-like geochemical signature, and are characterized by high Sr (424 to 552 ppm), Sr/Y ratios (31–43), and low Mg# (42 to 46) values, along with low Y (12–14 ppm) and heavy rare earth element (HREE) concentrations, that resemble those in adakites formed by partial melting of hot oceanic slab during subduction. Isotopic compositions are near bulk Earth (87Sr/86Sr(t) = 0.70482 to 0.70489, ε Nd (t) = +1.08 to +1.33), which rules out a solely asthenospheric origin. Elevated Nb/Ta (14 to 17) and K 2 O/Na 2 O (0.6–1.0) imply a juvenile mafic lower crustal source composed of ~20% garnet-bearing amphibolite. Geochemical modeling suggests that adakite-like parental melts were generated in the absence of subduction and without large-scale delamination of lower continental crust. Instead, our findings suggest that Late Miocene adakite-like volcanic rocks in the SZ formed in a post-collisional intra-continental setting, which experienced far-field extension after the subducted slab of the southern Neotethyan branch became detached in the collision zone. Asthenospheric upwelling and underplating of basaltic magma provided the heat for partial melting of lower crustal amphibolite, forming minor amounts of adakite-like melts in the SZ. • The Çağirankaya volcanics erupted in Late Miocene in the Sakarya Zone. • They exhibit adakite-like geochemical signature. • All characteristics suggest that they were derived from a juvenile lower crust. • Upwelling of hot asthenosphere due to far-field forces caused partial melting. • Adakitic melt do not require contemporaneous subduction of a hot oceanic slab. [ABSTRACT FROM AUTHOR]

Cadomian realms have recently received much attention in the Alpine–Mediterranean orogenic belts, with discontinuous outcrops extending from the Alps to the İstanbul Zone, Menderes Massif, Taurides in Turkey and Iran as well. However, they have not been identified in the Sakarya Zone, northern Turkey to date. Here, we present, for the first time, zircon U Pb geochronology, zircon Hf-isotopes and trace elements as well as whole-rock geochemistry and Nd-isotopes from the Karameşe metagranitoid in the Yusufeli (Artvin) area, NE Turkey. The zircon U Pb age data demonstrate that the Karameşe metagranitoid intruded into the Precambrian basement units in the Early Cambrian (ca. 534–530 Ma). Zircon overgrowths in the Karameşe metagranitoid interpreted as a result of metamorphic overprint yielded ages of 328 Ma. This age indicates that the Sakarya Zone experienced the Variscan metamorphic events at 328 Ma. The Early Cambrian metagranitoid shows that some rocks in the basement of the Sakarya Zone date back to Precambrian in age. The Karameşe metagranitoid is an S-type granite, with high modal content of muscovite (~10%). The samples show highly peraluminous [A/CNK = molar Al 2 O 3 /(CaO + K 2 O + Na 2 O) = 1.34–1.58] and medium-K calc-alkaline geochemical affinities. The Karameşe metagranitoid displays low REE concentrations and a slight positive Eu anomaly and show slightly light REEs and LILEs enrichments, and HFSEs depletions. The samples have negative ε Nd (t) of −4.76 to −2.90 and ε Hf (t) of −4.75 to −1.08 values. These geochemical-isotopic characteristics reveal that the Karamaşe metagranitoid originated through fluid-absent muscovite dehydration melting of heterogeneous metasedimentary source rocks (mostly greywacke), with a minor input of juvenile mafic melt. We argue that the Early Paleozoic metagranitoids along the eastern Sakarya Zone is an expression of crustal thinning in the Cadomian orogenic belt in northern Gondwana, with the tectonic turnover from convergent margin to crustal extension possibly induced by break-off of Tornquist oceanic lithosphere which is a branch of Iapetus Ocean during Early Cambrian. [Display omitted] • Cambrian S-type granites have been reported for the first time in Sakarya Zone. • The S-type granites originated from the melting of a metasedimentary source. • Variscan metamorphism overprinted the Early Cambrian magmatism. • Our data reveal that the S-type granites were formed in a post-collision setting. [ABSTRACT FROM AUTHOR]

Late Mesozoic evolution of the Neotethys Ocean is critical and still remains unclear along the entire Sakarya Zone (SZ), Turkey, because previous interpretations of the Middle to Late Jurassic rifting of the SZ have not been consensually accepted. We identified, for the first time, the Early Cretaceous dykes intruded into the Late Jurassic and Late Carboniferous bodies in the Çamlıkaya (Erzurum) area in the SZ. Here, we present a data set of new field observations, 40Ar/39Ar geochronology, whole-rock geochemical and Sr–Nd isotopes to find out the tectonic setting of previously undated basic to intermediate igneous rocks. 40Ar/39Ar technique on the groundmass separations yielded the plateau ages of 128.78 ± 1.02 to 122.89 ± 0.82 Ma. The investigated dykes are compositionally divided into two sub-groups: calc-alkaline lamprophyres (CAL) and high-Nb alkaline basalts (HNB). They show enrichment in large ion lithophile elements (LILE: e.g., Rb, Ba, K) and depletion in high field strength elements (HFSE: Nb and Ti) as well as moderate fractionation of light rare earth elements relative to heavy rare earth elements. The HNB have high Mg# (47–66), and relatively unradiogenic Sr 87Sr/86Sr(t) = 0.70385 to 0.70510] and Nd [ε Nd (t) = +0.5 to +5.3] isotopic composition, whereas the CAL possess moderate to high Mg# (32–72), and relatively high Sr 87Sr/86Sr(t) = 0.70586 to 0.71379] and Nd [ε Nd (t) = +1.5 to −9.9] isotopic composition. Early Cretaceous high-angle subduction triggered upwelling of the asthenosphere at 126 Ma, which likely generated a heat anomaly. This anomaly has probably induced melting of the oceanic slab and the metasomatized mantle to form the CAL and HNB. The HNB were generated by low degrees of melting of mantle domain that was previously reacted by oceanic slab-related adakitic melts at the depths of the garnet stability field (≥70 km). However, the CAL were probably formed at shallower mantle levels within the garnet-amphibole field by a relatively higher degree of melting of the mantle, also modified by subducted slab sediments. A new field, age, and petrochemical data from the Early Cretaceous dykes, combined with the presence of Aptian deep-water sediments to the north and the Late Jurassic-Early Cretaceous platform carbonates deposited in the passive margin setting along the entire SZ, imply the initiation of active-margin magmatism in the SZ. We suggest that the coexistence of the Early Cretaceous CAL and HNB points to the formation of an Andean-type active margin above a north-dipping Neotethyan oceanic slab. Their emplacement ages are associated with the inception of the magmatic arc structure and refer to a significant geodynamic turnover from passive-margin to active-margin tectonics along the SZ. • Ar–Ar dating suggest presence of an Early Cretaceous volcanism in the Sakarya Zone. • The CALs and HNBs were originated from an enriched mantle wedge. • All geochemical features indicate that they formed in a subduction setting. • All data refer a geodynamic shift from passive- to active-margin tectonics. [ABSTRACT FROM AUTHOR]

The Rheic Ocean is the most significant Paleozoic ocean that detached peri-Gondwana terranes from the northern Gondwana margin throughout the closure of the Iapetus Ocean. The suture of the Rheic Ocean spreads from Mexico to the Middle East, and the timing of its final closure is well-documented by the rocks formed in the Variscan-Alleghanian-Ouachita orogeny which led to the formation of the supercontinent Pangaea. However, as robust paleomagnetic and quantitative data are mostly lacking, the onset and evolution of the subduction of the Rheic Ocean are highly speculative, and they require further confirmation. Recently, the well-preserved metagranitoids along the western Sakarya Zone (SZ) in Anatolia have been identified, and they provide new data that improve our knowledge on the evolution of the Early Paleozoic Rheic Ocean along the northern Gondwana. Here, we present new geochronological, in situ zircon Hf isotope, and whole-rock geochemical analyses of these metagranitoids from the western SZ to enhance our understanding of the subduction processes of the Rheic Ocean. LA-ICP-MS zircon U-Pb dating demonstrated that the Bozüyük and Borçak metagranitoids from the western SZ were emplaced during the Silurian to Early Devonian (431 ± 2.7 to 403 ± 3.5 Ma). The both granitoids have medium- to high-K, calc-alkaline magmatic character, and exhibit peraluminous to slightly metaluminous geochemical signature. They show a typical arc pattern in terms of trace elements and have a uniform, moderate negative ε Hf (t) of −3.2 to −9.7, with Mesoproterozoic Hf depleted mantle model ages (T DM1 = 1.2 to 1.4 Ga). The geochemical and isotopic characteristics are not consistent with those of depleted mantle melts and melts derived from the crustal rocks in an intracontinental environment. Instead, the parental magma is likely generated from the partial melting of a homogeneous and enriched mantle wedge source. We propose that the Silurian to Early Devonian arc-related magmatism is associated with a northward subduction episode of the Rheic Oceanic lithosphere beneath the peri-Gondwana terranes. Hence, we consider that the opening of Paleotethys Ocean formed in a back-arc basin of subduction in Andean style to the north rather than a continental rift to the south in response to south-directed and short-lived supra-subduction zone (SSZ)-type subduction during the Silurian to Early Devonian. Unlabelled Image • Silurian to Early Devonian magmatism were recognized in the Sakarya Zone. • The metagranitoids originated from an enriched mantle domain. • Asthenospheric upwelling due to slab roll-back caused partial melting of mantle. • All the geochemical features indicate that they formed in a subduction setting. • The closure of Rheic Ocean triggered opening of Paleotethys in back-arc to north. [ABSTRACT FROM AUTHOR]