1. 'Naked' Magnetically Recyclable Mesoporous Au-γ-Fe2O3 Nanocrystal Clusters: A Highly Integrated Catalyst System.
- Author
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Shang, Lu, Liang, Yunhui, Li, Mengzhu, Waterhouse, Geoffrey I. N., Tang, Pei, Ma, Ding, Wu, Li‐Zhu, Tung, Chen‐Ho, and Zhang, Tierui
- Subjects
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MESOPOROUS materials , *NANOCRYSTAL synthesis , *GOLD cluster synthesis , *IRON oxide nanoparticles , *CATALYTIC activity - Abstract
Naked magnetically recyclable mesoporous Au-γ-Fe2O3 clusters, combining the inherent magnetic properties of γ-Fe2O3 and the high catalytic activity of Au nanoparticles (NPs), are successfully synthesized. Hydrophobic Au-Fe3O4 dimers are first self-assembled to form sub-micrometer-sized Au-Fe3O4 clusters. The Au-Fe3O4 clusters are then coated with silica, calcined at 550 °C, and finally alkali treated to dissolve the silica shell, yielding naked-Au-γ-Fe2O3 clusters containing Au NPs of size 5-8 nm. The silica protection strategy serves to preserve the mesoporous structure of the clusters, inhibit the phase transformation from γ-Fe2O3 to α-Fe2O3, and prevent cluster aggregation during the synthesis. For the reduction of p-nitrophenol by NaBH4, the activity of the naked-Au-γ-Fe2O3 clusters is ≈22 times higher than that of self-assembled Au-Fe3O4 clusters. Moreover, the naked-Au-γ-Fe2O3 clusters display vastly superior activity for CO oxidation compared with carbon-supported Au-γ-Fe2O3 dimers, due to the intimate interfacial contact between Au and γ-Fe2O3 in the clusters. Following reaction, the naked-Au-γ-Fe2O3 clusters can easily be recovered magnetically and reused in different applications, adding to their versatility. Results suggest that naked-Au-γ-Fe2O3 clusters are a very promising catalytic platform affording high activity. The strategy developed here can easily be adapted to other metal NP-iron oxide systems. [ABSTRACT FROM AUTHOR]
- Published
- 2017
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