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International audience; The Planetary Terrestrial Analogues Library (PTAL) is a dedicated lithological collection that currently consists of 102 terrestrial rock samples selected to be possible Mars analogues. The ultimate goal is improving future remote mineralogical and petrological analysis on Mars and other planetary bodies based on selected analysis such as Near- Infrared Reflectance Spectroscopy (NIR), Raman spectroscopy, Laser Induced Breakdown Spectroscopy (LIBS) and X-ray diffraction (XRD). Most international standards applied in the remote martian mineralogical and petrological analysis have so far been based on single, pure mineral analysis, with minimal interferences from other naturally occurring minerals. Here we present detailed lithological sample evaluations based on field appearance along with optical and XRD analysis of key terrestrial rock types. The detailed mineralogical and petrological descriptions give good basis for more complete lithological understanding. In combination with NIR, LIBS and Raman analysis of the very same samples PTAL aims at improving mineralogical and petrographical information from future rovers on Mars e.g. NASA's Mars2020-Perseverance and ESA and Roscosmos's ExoMars - Rosalind Franklin. The PTAL sample collection covers exclusively collected volcanic, magmatic and various sedimentary rocks and regoliths from well-known locations all over the world. These samples have a general composition comparable to what is currently known from Mars. The strength of this sample collection is its origin as common whole rock samples, in which minerals occur in their natural settings. It thereby allows studying possible detection interferences and a comparison of the sensitivity of the different techniques. The collection, in addition, forms the base for various alteration studies to better understand and explain alteration and weathering conditions on Mars. The complete results and sample preparations will be available to all scientists interested.

Producción Científica, The 2020s could be called, with little doubt, the "Mars decade". No other period in space exploration history has experienced such interest in placing orbiters, rovers and landers on the Red Planet. In 2021 alone, the Emirates' first Mars Mission (the Hope orbiter), the Chinese Tianwen-1 mission (orbiter, lander and rover), and NASA's Mars 2020 Perseverance rover reached Mars. The ExoMars mission Rosalind Franklin rover is scheduled for launch in 2022. Beyond that, several other missions are proposed or under development. Among these, MMX to Phobos and the very important Mars Sample Return can be cited. One of the key mission objectives of the Mars 2020 and ExoMars 2022 missions is the detection of traces of potential past or present life. This detection relies to a great extent on the analytical results provided by complementary spectroscopic techniques. The development of these novel instruments has been carried out in step with the analytical study of terrestrial analogue sites and materials, which serve to test the scientific capabilities of spectroscopic prototypes while providing crucial information to better understand the geological processes that could have occurred on Mars. Being directly involved in the development of three of the first Raman spectrometers to be validated for space exploration missions (Mars 2020/SuperCam, ExoMars/RLS and RAX/MMX), the present review summarizes some of the most relevant spectroscopy-based analyses of terrestrial analogues carried out over the past two decades. Therefore, the present work describes the analytical results gathered from the study of some of the most distinctive terrestrial analogues of Martian geological contexts, as well as the lessons learned mainly from ExoMars mission simulations conducted at representative analogue sites. Learning from the experience gained in the described studies, a general overview of the scientific outcome expected from the spectroscopic system developed for current and forthcoming planetary missions is provided., Ministerio de Economía, Industria y Competitividad (grants PID2019-107442RB-C31 and RDE2018-102600-T), Consejo Europeo de Investigación (grant 687302)

Although the present environmental conditions on Mars prohibit the generation of significant volumes of liquid water, observations of several very young landforms, such as gullies and recurrent slope lineae, have been interpreted as signals for aqueous processes. To explore the range of conditions under which such features can be formed on Earth, a field site in northern Victoria Land, East Antarctica, was geomorphologically investigated. Despite the small size of the icefree area, the site displays gullies, water tracks and other traces of liquid water. The gullies show clear evidence of sediment transport by debris flows, and are typical of paraglacial processes on steep slopes in a recently deglaciated area. Water tracks appear in different forms, and seem to recur seasonally in the austral summer. Melting of snow and surface glacier ice is the major water source for both debris flows and water tracks. The observations presented here highlight the potential for hyperarid polar deserts to generate morphogenetically significant amounts of meltwater. The gullies are morphologically analogous to Martian gullies, and water tracks on steep slopes appear very similar to recurrent slope lineae. The observations suggest that even small icefree sites in continental Antarctica may enable observations which can serve as a basis for working hypotheses in Mars analogue studies, and future field work should consider more areas in Antarctica in addition to the McMurdo Dry Valleys to search for Mars analogue landforms.

Producción Científica, The multi analytical study of terrestrial analogues is a useful strategy to deepen the knowledge about the geological and environmental evolution of Mars and other extraterrestrial bodies. In spite of the increasing importance that LIBS, NIR and Raman techniques are acquiring in the field of space exploration, there is a lack web-based platform providing free access to a wide multi-spectral database of terrestrial analogue materials. The Planetary Terrestrial Analogue Library (PTAL) project aims at responding to this critical need by developing and providing free web accessibility to LIBS, NIR and Raman data from more than 94 terrestrial analogues selected according to their congruence with Martian geological contexts. In this framework, the present manuscript provides the scientific community with a complete overview of the over 4500 Raman spectra collected to feed the PTAL database. Raman data, obtained through the complementary use of laboratory and spacecraft-simulator systems, confirmed the effectiveness of this spectroscopic technique for the detection of major and minor mineralogical phases of the samples, the latter being of critical importance for the recognition of geological processes that could have occurred on Mars and other planets. In light of the forthcoming missions to Mars, the results obtained through the RLS ExoMars Simulator offer a valuable insight on the scientific outcome that could derive from the RLS spectrometer that will soon land on Mars as part of the ExoMars rover payload. (13) (PDF) PTAL multi-spectral database of planetary terrestrial analogues: Raman data overview. Available from: https://www.researchgate.net/publication/348675482_PTAL_multi-spectral_database_of_planetary_terrestrial_analogues_Raman_data_overview [accessed Apr 19 2021]., Proyecto MINECO Retos de la Sociedad. Ref. ESP2017-87690-C3-1-R

Small-scale lobes (SSL) observed at the surface of Mars are thought to be the result of solifluction. Hence, their existence has important implications for our understanding of recent climate history, the distribution of thaw liquids and its geomorphic effects, as water is believed not to have been recently stable at the martian surface. These small-scale lobes are limited to sloping terrains and often occur alongside polygonal patterned ground attesting to the presence of ice in the environment. In this study, we perform a comparative 3D morphometric analysis of the lobes on Mars with terrestrial analogues. We use data from High Resolution Imaging Science Experiment (HiRISE) camera in order to create Digital Terrain Models (DTMs) on Mars at 1 m/pix. For the terrestrial analogues, we use DTMs and orthophotos from five periglacial environments with solifluction lobes and from one site with lobate features found in the Atacama Desert. The lobate features in the Atacama Desert are found within features called “zebra stripes”, which are apparently unique to the Atacama and are now generally accepted to be the result of seismic shaking. We show that SSL on Mars overlap morphometrically with terrestrial solifluction lobes, and are less similar to zebra stripe lobes. The majority of martian SSL occur below the angle of repose which demonstrates that a dry fall mechanism cannot be responsible for their formation and that lubrication of the subsurface is required. We found that martian SSL only occur on slopes greater than ~10°, a constraint not observed for terrestrial solifluction lobes nor zebra stripe lobes in Atacama. We hypothesise that this apparent constraint does not result from the lowered gravity on Mars, but instead from differing soil properties and/or thermal regime between Mars and Earth which affects the slope at which creep can initiate. We cannot rule out a role of CO2 sublimation in lobe-formation based on our terrestrial measurements.

We report here hematite-rich concretions observed in the sandstone of the Mesoproterozoic Vindhyan Supergroup of rocks occurring in parts of Bihariya, Uttar Pradesh, northern India. These concretions are similar to `blueberries' from Mars and their terrestrial analogues reported from the Jurassic Navajo Sandstone in Utah, USA. The presence of diagenetically formed hematite concretions gave the first confirmation of the presence of liquid water in the red planet in the past. We report here the detailed morphology, petrography, mineral chemistry, magnetic susceptibility characteristics and spectral radiometric data of hematite-rich concretions observed in the Vindhyan sandstone. These are compared with `blueberries' from Mars and other similar terrestrial analogues reported from different parts of the world. In spite of similarities, these hematite-rich concretions are strikingly distinct in having a nucleus and alternate iron-rich and iron-poor rims unlike other global occurrences. In addition, we document here outcrop scale evidence of possible fluid pathways considered responsible for the development of the concretions.

We present landforms on Svalbard (Norway) as terrestrial analogs for possible Martian periglacial surface features. While there are closer climatic analogs for Mars, e.g., the Antarctic Dry Valleys, Svalbard has unique advantages that make it a very useful study area. Svalbard is easily accessible and offers a periglacial landscape where many differ- ent landforms can be encountered in close spatial proximity. These landforms include thermal contraction cracks, slope stripes, rock glaciers, protalus ramparts, and pingos, all of which have close morphological analogs on Mars. The combination of remote- sensing data, in particular images and digital elevation models, with fi eld work is a promising approach in analog studies and facilitates acquisition of fi rst-hand experi- ence with permafrost environments. Based on the morphological ambiguity of certain landforms such as pingos, we recommend that Martian cold-climate landforms should not be investigated in isolation, but as part of a landscape system in a geological context.

We compared the morphology of gully sedimentary fans on Svalbard as possible analogs to gullies on Mars in order to constrain whether fl uvial and/or debris-fl ow processes are predominantly responsible for the formation of Martian gullies. Our analysis is based on high-resolution imagery (High Resolution Stereo Camera [HRSC-AX], ~20 cm/pixel) acquired through a fl ight campaign in summer 2008 and ground truth during two expeditions in the summers of 2008 and 2009 in Svalbard, compared to high-resolution satellite imagery (High Resolution Imaging Science Experiment [HiRISE], ~25 cm/pixel) from Mars. On Svalbard, fl uvial and debris-fl ow processes are evident in the formation of gullies, but the morphological characteristics clearly show that the transport and sedimentation of eroded material are predominated by debris fl ows. Most investigated gullies on Mars lack clear evidence for debris-fl ow processes. The Martian gully fan morphology is more consistent with the deposition of small overlapping fans by multiple fl uvial fl ow events. Clear evidence for debris fl ows on Mars was only found in one new location, in addition to a few previously published examples. The occurrence of debrisfl ow processes in the formation of Martian gullies seems to be rare and locally limited. If predominantly fl uvial processes caused the formation of gullies on Mars, then large amounts of water would have been required for their formation because of the relatively low sediment supply in stream and/or hyperconcentrated fl ows. Repeated seasonal or episodic snow deposition and melting during periods of higher obliquity in the recent past on Mars can best explain the formation of the gullies.

Recently reported results from latest Mars Orbiters and Rovers missions are transforming our opinion about the red planet. That dry and inhospitable planet reported in the past is becoming a wetter planet with high probabilities of water existence in the past. Nowadays, some results seem to indicate the presence of water beneath the Mars surface. But also mineralogy studies by NASA Opportunity Rover report iron oxides and hydroxides precipitates on Endurance Crater. Sedimentary deposits have been identified at Meridiani Planum. These deposits must have generated in a dune aqueous acidic and oxidizing environment. Similarities appear when we study Rio Tinto, and acidic river under the control of iron. The discovery of extremophiles on Earth widened the window of possibilities for life to develop in the Universe, and as a consequence on Mars and other planetary bodies with astrobiological interest. The compilation of data produced by the ongoing missions offers an interested view for life possibilities to exist: signs of an early wet Mars and rather recent volcanic activity as well as ground morphological characteristics that seem to be promoted by liquid water. The discovery of important accumulations of sulfates and the existence of iron minerals such as jarosite in rocks of sedimentary origin has allowed specific terrestrial models to come into focus. Río Tinto (Southwestern Spain, Iberian Pyritic Belt) is an extreme acidic environment, product of the chemolithotrophic activity of micro-organisms that thrive in the massive pyrite-rich deposits of the Iberian Pyritic Belt. Some particular protective environments should house the organic molecules and bacterial life forms in harsh environments such as Mars surface supporting microniches inside precipitated minerals or inside rocks. Terrestrial analogues could help us to afford the comprehension of habitability (on other planetary bodies). We are reporting here the multidisciplinary study of some endolithic niches inside salt deposits used by phototrophs for taking advantage of sheltering particular light wavelengths. These acidic salts deposits located in Río Tinto shelter life forms that are difficult to visualize by eye. This interdisciplinary field analogue campaign was conducted in the framework of the CAREX FP7 EC programme., This interdisciplinary field analogue campaign was conducted in the framework of the CAREX FP7 EC programme

Periglacial landforms on Spitsbergen (Svalbard, Norway) are morphologically similar to landforms on Mars that are probably related to the past and/or present existence of ice at or near the surface. Many of these landforms, such as gullies, debris-flow fans, polygonal terrain, fractured mounds and rock-glacier-like features, are observed in close spatial proximity in mid-latitude craters on Mars. On Svalbard, analogous landforms occur in strikingly similar proximity, which makes them useful study cases to infer the spatial and chronological evolution of Martian coldclimate surface processes. The analysis of the morphological inventory of analogous landforms on Svalbard and Mars allows the processes operating on Mars to be constrained. Different qualitative scenarios of landscape evolution on Mars help to better understand the action of periglacial processes on Mars in the recent past.