Gao, Mingbin, Li, Hua, Yang, Miao, Gao, Shushu, Wu, Pengfei, Tian, Peng, Xu, Shutao, Ye, Mao, and Liu, Zhongmin
Mass transfer of guest molecules in nanoporous crystalline materials has gained attention in catalysis, separation, electrochemistry, and other fields. Two mechanisms, surface barriers and intracrystalline diffusion, dominate the mass transport process. Lack of methods to separately quantify these two mechanisms restricts further understanding and thus rational design and efficient application of nanoporous materials. Here we derive an approximate expression of uptake rate relying solely on surface permeability, offering an approach to directly quantify surface barriers and intracrystalline diffusion. By use of this approach, we study the diffusion in zeolitic materials, and find that the intracrystalline diffusivity is intrinsic to the topological structure of host materials at low molecular loading for the given guest molecules, while the surface permeability is sensitive to the non-ideality of a crystalline surface owing to the physical and chemical properties of the crystalline surface, host–guest interaction at the surface, and change of the environment. Mass transfer of guest molecules in nanoporous crystalline materials is dominated by surface barriers and intracrystalline diffusion. Here the authors derive an approximate expression of uptake rate relying solely on surface permeability, offering an approach to directly quantify both effects. [ABSTRACT FROM AUTHOR] more...