1. Spectrally Stable and Efficient Pure Red CsPbI3 Quantum Dot Light-Emitting Diodes Enabled by Sequential Ligand Post-Treatment Strategy
- Author
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Hong-Bin Yao, Jun-Nan Yang, Kuang-Hui Song, Tian Chen, Li-Zhe Feng, Yong-Hui Song, Ji-Song Yao, Xue-Chen Ru, Yi-Feng Lan, and Qian Zhang
- Subjects
Materials science ,business.industry ,Band gap ,Mechanical Engineering ,Bioengineering ,General Chemistry ,Condensed Matter Physics ,law.invention ,Wavelength ,Semiconductor ,Quantum dot ,law ,Optoelectronics ,General Materials Science ,Quantum efficiency ,business ,Light-emitting diode ,Perovskite (structure) ,Diode - Abstract
Metal halide perovskites are promising semiconductors for next-generation light-emitting diodes (LEDs) due to their high luminance, excellent color purity, and handily tunable band gap. However, it remains a great challenge to develop perovskite LEDs (PeLEDs) with pure red emission at the wavelength of 630 nm. Herein, we report a spectrally stable and efficient pure red PeLED by employing sequential ligand post-treated CsPbI3 quantum dots (QDs). The synthesized CsPbI3 QDs with a size of ∼5 nm are treated in sequential steps using the ligands of 1-hydroxy-3-phenylpropan-2-aminium iodide (HPAI) and tributylsulfonium iodide (TBSI), respectively. The CsPbI3 QD films exhibit improved optoelectronic properties, which enables the fabrication of a pure red PeLED with a peak external quantum efficiency (EQE) of 6.4% and a stable EL emission centered at the wavelength of 630 nm. Our reported sequential ligand post-treatment strategy opens a new route to improve the stability and efficiency of PeLEDs based on QDs.
- Published
- 2021
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