1. Supramolecular repair of hydration lubrication surfaces
- Author
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Paul R. McGonigal, Yulong Sun, Yixin Wang, Alyssa-Jennifer Avestro, and Hongyu Zhang
- Subjects
Materials science ,General Chemical Engineering ,Supramolecular chemistry ,engineering.material ,Biochemistry ,Dissociation (chemistry) ,Lubricity ,Coating ,Monolayer ,Materials Chemistry ,Environmental Chemistry ,chemistry.chemical_classification ,Biochemistry (medical) ,General Chemistry ,Polymer ,Chemical engineering ,chemistry ,Covalent bond ,Lubrication ,engineering ,human activities - Abstract
Summary Although advances in coating technologies have allowed us to match—or even exceed—the lubricity of Nature’s low-friction surfaces, the performance of synthetic materials inevitably diminishes over time as the surfaces are worn and damaged by irreversible breakage of covalent bonds. Synthetic systems lack the bespoke repair mechanisms that replenish hydration lubrication surfaces in Nature. Here, we demonstrate dynamic repair of low-friction surfaces prepared through a surface-selective self-assembly strategy. Monolayers of lubricating polymers associate with functionalized surfaces through strong and specific host–guest interactions, leading to hydration lubrication surfaces with low coefficients of friction (0.024–0.028). Following friction-induced dissociation of the polymers, the polymer-to-surface interaction is restored by the reformation of host–guest complexes, thus repairing the monolayer, renewing the lubricity, and reducing the effects of wear. Such dynamically restored low-friction materials will be an essential tool in decreasing global energy use—a fifth of which is expended overcoming friction.
- Published
- 2022