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2. A water reduction process performed by zinc metal under very mild conditionsElectronic supplementary information (ESI) available: Synthesis and experimental data for H2L and complexes 1, 1·3CH3CN·H2O and 2. ORTEP diagram, selected bond distances and angles for 1·3CH3CN·H2O. 1and 2characterization figures. CCDC 766560. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c0cc00256a

3. The coordination preferences of metal centres modulate superexchange coupling interactions in a metallo-supramolecular helical assemblyElectronic supplementary information (ESI) available: Synthesis and experimental data for H2Land complexes [Cu2(L)2], [Ni2(L)2]. CIF files, ORTEP diagrams, selected bond distances and angles for 1and 2. Ancillary figures relative to the magnetic studies. CCDC 767303and 767304. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c0cc00338g

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