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Constrained geometry complexes (CGCs) are homogeneous olefin polymerization catalysts that have been improved because of their considerably high activity and their copolymerization abilities for ethylene with α‐olefins. The ancillary ligands in CGCs comprise bridged 6π‐electron moieties (e.g., cyclopentadienyl (Cp) and fluorenyl) and amide donors. In this study, we investigated the effect of changing the 6π‐electron moieties to a diphenylmethyl moiety (Ph2C) on the polymerization activity of [Me2Si(Ph2C)(tBuN)]ZrCl2(thf) (thf = tetrahydrofuran). We synthesized [Me2Si(Ph2C)(tBuN)]ZrCl2(thf) and characterized it via 1H nuclear magnetic resonance analysis and single‐crystal X‐ray crystallography. Ethylene polymerization at 2 MPa using a catalyst of the [Me2Si(Ph2C)(tBuN)]ZrCl2(thf) and modified methylaluminoxane (MMAO) as a cocatalyst yielded a linear polyethylene (PE) with a high melting point (124°C–134°C); moreover, the polymerization activity of the catalyst was found to be up to 445 g (PE) mmol (Zr)−1 h−1. The polymerization of styrene using the zirconium complex and MAOs did not proceed, but the polymerization of 1,3‐butadiene produced a small amount of polybutadiene with ~60% cis‐1,4‐structure. These results indicate that non‐Cp‐type CGCs, which can be defined as metal complexes bearing an ancillary ligand in which non‐Cp moieties (benzyl moiety in this study) and an amido group are bridged by an organic linker, can become a new family of homogeneous olefin polymerization catalysts. [ABSTRACT FROM AUTHOR]

Abstract: The titanium and zirconium complexes based on thioether substituted β-carbonylenamine were prepared and characterized. In the presence of MMAO, the titanium complexes showed good activity in syndiospecific styrene polymerization with high syndioselectivity, and performed good thermal stability. Electron withdrawing group on ligands is beneficial to the styrene polymerization. [1,3-diphenyl-3-(2-(isopropylthio)ethylimino)prop-1-en-1-olate]2ZrCl2(IV) could also polymerize styrene to give syndiotactic polymer, however in low activity and with low syndioselectivity. [Copyright &y& Elsevier]

Abstract: Groundwater is a very important component of water resources in coastal aquifers in Thoothukudi. It has been established that the groundwaters in the coastal zone of the Zirconium Complex, Pazhayakayal, Thoothukudi district, Tamilnadu, India, are subjected to wave and tidal impact. The groundwater quality was studied by hydrogeological methods, 2D electrical resistivity imaging (ERI) techniques (six profiles), 11 Wenner vertical electrical sounding (VES), and well log analysis. Also, nine geochemical water samples were taken from the study area. The 2D ERI and VES surveys were carried out using WGMD-4 Ltd., Chennai, resistivity meter, multicore cable, and multielectrodes with Wenner array. The collected resistivity data were interpreted using the Res2DINV software. The research shows that the groundwaters are the result of the paleoriver flow along the Tamirabarani Channel in the western area and of the seawater intrusion in the eastern area. The fresh water is characterized by resistivity of about 10–100 Ohm⋅m in the study area. The resistivity of 10–50 Ohm⋅m indicates that the subsurface section is made up of sand, clay, and caliche. Resistivity values of more than 200 Ohm⋅m are specific to sand dunes. The very low resistivity (<5 Ohm⋅m) layer might be due to the seawater intrusion in the study area. Six water samples from the well drilled in the coastal area were analyzed, which made it possible to determine the concentrations of major and trace elements in the groundwaters. These data were used to establish the seawater intrusion and coastal environment characteristics in the study area. [Copyright &y& Elsevier]

Abstract: A new zirconium complex containing amidinate, guanidinate and amide ligand sets with formula Zr[(CyN)2CMe][(CyN)2CNMe2](NMe2)2 (1) (Cy=cyclohexyl) was synthesized by the insertion of the 1,3-dicyclohexylcarbodiimide moiety into the bond of zirconium and dimethylamido group. Characterization of the complex 1 was achieved using elemental analysis, 1H and 13C NMR spectra and single crystal X-ray diffraction. The molecular structure of the complex 1 revealed that the coordination geometry around the zirconium is a distorted pseudo-octahedron. The metal center is surrounded by the four nitrogen atoms of two bidentate amidinate and guanidinate ligands positioned cis to each other and two cis-NMe2 groups. [Copyright &y& Elsevier]