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Novel porous TiO2@Cu3(BTC)2 composites, which were synthesized using ionic liquids (ILs) as solvents, exhibited excellent activity for photooxidation of styrene to 4-aryl tetralones and promoting the Glaser coupling reaction with O2 under light irradiation. It was discovered that the transformation between Cu2+ and Cu+ was crucial for enhancing the photocatalytic performance. [ABSTRACT FROM AUTHOR]

MOF-derived In–Cu bimetallic oxides are highly efficient electrocatalysts for the transformation of CO2 into CO in an aqueous electrolyte. By controlling In/Cu ratios, the faradaic efficiency of CO could reach 92.1%. The excellent performance is mainly attributed to stronger CO2 adsorption, higher electrochemical surface area and lower charge transfer resistance. [ABSTRACT FROM AUTHOR]

Ultrathin metal–organic framework (MOF) nanosheets were fabricated by a surfactant-mediated coordination strategy through a pseudo-assembly process. The thickness of the nanosheets could be tuned from 3 nm to 60 nm by varying the hydrophobic chain length of the surfactant. Ru nanoparticles supported on the nanosheets exhibited superior catalytic activity for hydrogenation of levulinic acid to γ-valerolactone. [ABSTRACT FROM AUTHOR]

Electrocatalytic reduction of CO2 to a single product at high current densities and efficiencies remains a challenge. However, the conventional electrode preparation methods, such as drop‐casting, usually suffer from low intrinsic activity. Herein, we report a synthesis strategy for preparing heterogeneous electrocatalyst composed of 3D hierarchical Cu dendrites that derived from an in situ electrosynthesized hollow copper metal–organic framework (MOF), for which the preparation of the Cu‐MOF film took only 5 min. The synthesis strategy preferentially exposes active sites, which favor's the reduction of CO2 to formate. The current density could be as high as 102.1 mA cm−2 with a selectivity of 98.2 % in ionic‐liquid‐based electrolyte and a commonly used H‐type cell. [ABSTRACT FROM AUTHOR]

Electrocatalytic reduction of CO2 to a single product at high current densities and efficiencies remains a challenge. However, the conventional electrode preparation methods, such as drop‐casting, usually suffer from low intrinsic activity. Herein, we report a synthesis strategy for preparing heterogeneous electrocatalyst composed of 3D hierarchical Cu dendrites that derived from an in situ electrosynthesized hollow copper metal–organic framework (MOF), for which the preparation of the Cu‐MOF film took only 5 min. The synthesis strategy preferentially exposes active sites, which favor's the reduction of CO2 to formate. The current density could be as high as 102.1 mA cm−2 with a selectivity of 98.2 % in ionic‐liquid‐based electrolyte and a commonly used H‐type cell. [ABSTRACT FROM AUTHOR]

Abstract: Electrochemical reduction of CO2 into value‐added product is an interesting area. MoP nanoparticles supported on porous carbon were synthesized using metal–organic frameworks as the carbon precursor, and initial work on CO2 electroreduction using the MoP‐based catalyst were carried out. It was discovered that MoP nanoparticles supported on In‐doped porous carbon had outstanding performance for CO2 reduction to formic acid. The Faradaic efficiency and current density could reach 96.5 % and 43.8 mA cm−2, respectively, when using ionic liquid 1‐butyl‐3‐methylimidazolium hexafluorophosphate as the supporting electrolyte. The current density is higher than those reported up to date with very high Faradaic efficiency. The MoP nanoparticles and the doped In2O3 cooperated very well in catalyzing the CO2 electroreduction. [ABSTRACT FROM AUTHOR]