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Start Over Author "Goff, George S." Topic metallocenes
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1. New Twists and Turns for Actinide Chemistry: Organometallic Infinite Coordination Polymers of Thorium Diazide.

Author

Monreal, Marisa J., Seaman, Lani A., Goff, George S., Michalczyk, Ryszard, Morris, David E., Scott, Brian L., and Kiplinger, Jaqueline L.

Subjects
COORDINATION polymers, ACTINIUM compounds, ORGANOMETALLIC polymers, THORIUM compounds, METALLOCENES
Abstract

Two organometallic 1D infinite coordination polymers and two organometallic monometallic complexes of thorium diazide have been synthesized and characterized. Steric control of these self-assembled arrays, which are dense in thorium and nitrogen, has also been demonstrated: infinite chains can be circumvented by using steric bulk either at the metallocene or with a donor ligand in the wedge. [ABSTRACT FROM AUTHOR]

Published
2016
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