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This study investigated the impact of ocean acidification on the photodegradation of three microplastics (MPs): polypropylene (PP), expanded polystyrene (EPS), and ethylene-vinyl acetate (EVA), under accelerated UV radiation at three pH levels (i.e., 8.1, 7.8, and 7.5), simulating marine conditions. The acidification system simulated current and projected future environmental conditions. As expected, an increase in partial pressure of CO2, total inorganic carbon, bicarbonate ion, and CO2 resulted in more acidic pH levels, with the reverse being true for the carbonate ion. Structural changes of MPs were evaluated, revealing that all weathered samples underwent higher degradation rate compared to the virgin samples. The oxidation state and crystallinity of PP and EVA MPs were higher in samples exposed to the lowest pH, whereas no significant increase in the degradation rate of EPS samples was observed. Saltwater acidification in this study contributed to enhance the photo-oxidation of MPs depending on their polymeric composition., Competing Interests: Declaration of competing interest The authors have no relevant financial or non-financial interests to disclose. Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier Ltd. All rights reserved.)

This study investigated the influence of environmental factors (UV radiation and salinity) in the degradative process of microplastics (MPs). MPs derived from polypropylene (PP), polystyrene (PS), and ethylene-vinyl acetate (EVA) were subjected to accelerated photodegradation while being submerged in distilled water or artificial seawater. Depending on the polymer, changes in surface properties, new functional chemical group formation and oxidative index, and thermal characteristics of samples were observed. After photodegradation experiments, EVA-MPs samples showed an increase in their thermal resistance, besides the changes in their surface. PP-MPs crystallinity index increased upon exposure to UV radiation. PS samples showed a higher carbonyl and hydroxyl index after 30 h of UV exposure. The methodology exploited applies to any location in the world and can be comparable once considering the total ultraviolet index (UVI). The saline medium increases the crystallinity index of PP and EVA-MPs samples and intensifies the formation of new carbonyl and hydroxyl bonds in EVA-MPs samples. The results showed that several environmental factors should be considered in interpreting MPs photodegradation., (© 2023. The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature.)

Research on microplastics in Latin America is limited compared to a global perspective. Brazil plays a significant role in this context, as it possesses 12% of the world's freshwater reserves, constituting 53% of South America's water resources. There has been growing concern regarding the plastic pollution of the country's freshwater systems in recent years. Therefore, this study investigated the impact of plastic pollution on the Guaíba River, a significant watercourse in the southern region of Brazil that is subjected to high anthropogenic pressure. Additionally, we examined correlations between the presence of microplastics and key factors influencing their distribution in the river. Thus, freshwater was collected in seven sampling campaigns from 2019 to 2020, totaling 66 samples. The microplastics were quantified and characterized according to their color, shape, and polymeric composition. The concentration of microplastics varied between 2.9 and 53.8 items m -3 , and the distribution and transport were positively influenced by the population density, precipitations, and depth of each sampling point. White-transparent color category (51%) and fragment shape (89%) were predominant among the found particles. Polyethylene (PE) and polypropylene (PP) represented 37% and 57% of the analyzed particles. The non-metric multidimensional scaling (nMDS) analysis indicated that similar contamination sources, such as domestic sewage, could influence three out of ten sampled points. Several microplastics presented the formation of cracks, with sizes smaller than 10 μm on their surface, which might indicate an erosion process, resulting in the formation of nanoplastics. The color fading observed in microplastics suggests that the particles were subjected to environmental stressors, leading to the leaching or degradation of the dye on the plastic. The results confirmed the ubiquity of microplastics in Guaíba River, highlighting the importance of improving the regulations on plastic waste disposal in the country to prevent the contamination of freshwater bodies., (© 2023. The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature.)

Microplastics of polyamide are commonly found in aquatic environments and might act as vectors of different contaminants such as endocrine disrupting compounds (EDC). Therefore, sorption of 17α-ethynylestradiol (EE2), 17β-estradiol (E2), and estriol (E3) on polyamide microplastics was studied under different simulated environments. The results suggest that the sorption process was affected by the presence of dissolved organic matter (DOM) and salinity, where both positive and negative effects were observed. Kinetics revealed that the process occurs through multiple steps wherever the sorption rate depicting the transportation of EDC molecules from the liquid phase to the solid boundary of the sorbent, is higher than the intraparticle and pore diffusion process. In addition, the sorption rate of E2 decreased with the increase of water matrix complexity from ultrapure water (UPW) > artificial seawater (ASW) > fulvic acid water (FAW) > artificial seawater with fulvic acid (AS/FAW), while the sorption rate of EE2 decreased from UPW > ASW > FAW and increased in the matrix combining salinity and organic matter (AS/FAW). On the contrary, the E3 sorption rate increased with matrix complexity, from UPW < ASW < FAW and decreased with the influence of salinity and organic matter combination (AS/FAW). The sorption capacity of the EDC reached maximum values of 82% for E2, 90% for EE2 and 56% for E3. Isotherms demonstrated the occurrence of multilayer sorption. A positive relationship has been found between the hydrophobicity of polyamide microplastics and the Log K ow of EDC, showing an important role of hydrophobic interactions in the sorption process under all the studied conditions. Moreover, hydrogen bonding and binding of contaminants and DOM to microplastics through bridges were also suggested. The results show that salinity and DOM can greatly influence the sorption and transportation of EDC in the aquatic environment and pose a risk to aquatic ecosystems., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2021 Elsevier B.V. All rights reserved.)

The release of microfibres from fabrics during laundering represents an important source of plastic and natural microfibres to aquatic environments. Garment age - how long the garment has been used - could be a key factor influencing the rate of release, yet most studies of microfibre shedding have only assessed newly manufactured products. To this end, we quantified microfibre release during laundering in domestic washing machines from polyester (PES) and cotton garments (n = 38) used in real-life conditions for periods between 1 and 31 years with different use intensities. In addition, to better understand the factors involved in microfibre releases, fibre composition (different PES percentages) and type of garments (T-shirts, polo shirts, uniforms, sports shirts, and sweatshirts) were examined. All garments released microfibres during washing, while the older garments presented higher releases for clothing with a PES/cotton blend. In general, older garments (15–31 years) released nearly twice as many fibres when washed than newer garments (1–10 years). The mass of microfibres released was consistently greater in garments with a higher proportion of cotton than PES (up to 1.774 mg g−1 in 2% PES and 0.366 mg g−1 in 100% PES fabrics), suggesting that cotton might be released more readily such that the relative proportion of PES in the garments could increase over time. Additionally, SEM images showed fibre damage, with fibres from the older garments exhibiting more peeling and splitting. While it is important to note that the overall environmental footprint is undoubtedly reduced by keeping garments in use for longer periods of time, older garments were shown to release more microfibres. [Display omitted] • Garment age is an important factor in the release of microfibres during laundry. • Older garments release nearly twice as many microfibres as newer clothes. • Studies underestimate microfibre release due to the absence of use of the garments between washes. • SEM images revealed fibre damage from years of garment use. • Smaller microfibres (1–63 μm) were dominant in newer and older garments. [ABSTRACT FROM AUTHOR]

Brazil maintains its position at the top of the global ranking of plastic producers, yet recycling efforts have been incipient. Recent data reveals an annual production of approximately 14 million tons of plastic waste, not accounting for the surge in the usage of plastic masks and related materials due to the COVID-19 pandemic. However, what remains largely unreported is that over half of post-consumer plastic packaging in Brazil is managed without any monitoring, and it remains unclear how this will contribute to the occurrence of plastic waste and microplastics in Brazilian freshwaters. This scenario requires the consideration of several other crucial factors. Studies have been carried out mainly in marine and estuarine waters, while data on freshwaters are lacking. Brazil has continental dimensions and the highest water availability on the planet, yet the demand for water is greatest in regions with medium to low supply. Many densely populated Brazilian urban areas face chronic flood problems, possess inadequate levels of wastewater treatment, and display inadequate solid waste management practices. Consequently, urban freshwater with tropical characteristics in Brazil presents an intriguing scenario and is complementary to the most commonly studied marine environments. In this study, we explore the nuances of pollution in Brazilian urban freshwater and discuss how various parameters, such as organic matter, suspended solids, temperature, and pH, among others, influence the behavior of microplastics and their interactions with organic and inorganic contaminants. Furthermore, we address how microplastic conditions, such as biofouling, the type of plastic, or degradation level, may impact their behavior. By analyzing how these conditions change, we propose priority themes for investigating the occurrence of microplastics in Brazilian urban freshwater systems under different degrees of human impact. Ultimately, this study aims to establish a network dedicated to standardized monitoring of microplastic pollution in Brazilian urban freshwaters. [Display omitted] • Poor plastic waste management causes microplastic (MP) pollution in Brazilian waters. • Most urban freshwaters in Brazil are impacted by waste and wastewater discharges. • Climate and organic pollution may affect MP degradation and behavior in freshwaters. • Standard protocols for monitoring MPs in freshwater should rely on research networks. • MPs in Brazilian urban freshwaters present a complementary scenario worth exploring. [ABSTRACT FROM AUTHOR]

• A computer-vision-based method for microplastic (MP) quantitation. • Partial least squares coupled with interval selection was used. • MP quantitation with respect to colour. • A fast and inexpensive approach was achieved. Microplastic (MP) contamination is a topic of growing global concern; these particles are ubiquitous in environmental ecosystems and have been found in aquatic, terrestrial, and atmospheric mediums. However, the protocols to quantify MPs in environmental samples have limitations and may lead to overestimation and/or underestimation of the plastic debris. Therefore, the aim of this research was to develop a simple procedure to determine the abundance of MPs using digital image processing and chemometric treatment. The proposed method combined computer-vision-based and multivariate calibration by partial least squares coupled with interval selection (i PLS and successive algorithm projection - i SPA). The abundance ranges of the yellow, blue, black, colourless, green, and red MPs were 1–212, 7–134, 0–50, 6–290, 0–113, and 20–392, respectively. When the models were applied to an independent set of samples, the following RMSEP values were found: 9.8 (yellow), 6.4 (blue), 3.5 (black), 8.1 (colourless), 7.5 (green), and 19.3 (red). The results showed that image processing has the potential to quantify MPs with respect their colour. This method could help to reduce time-consuming and to avoid subjectivity in future analyses. [ABSTRACT FROM AUTHOR]