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Here, we study slate microfabrics from the exhumed accretionary wedge of the central European Alps and focus on the development of foliation. High-resolution micrographs from novel BIB-SEM imaging and Synchrotron X-ray Fluorescence Microscopy are analysed with 2D auto-correlation functions to quantify the geometry and spacing of slate microfabrics along a metamorphic gradient covering the outer and inner wedge (200–330 °C). The sedimentary layering primarily controls the morphology of the slate microfabrics. However, from outer to inner wedge, a fabric evolution is observed where diagenetic foliations gradually transform to secondary continuous and spaced foliations. With increasing metamorphic grade, the amount of recrystallized phyllosilicate grains and their interconnectivity increase, as does clast/microlithon elongation (aspect ratios up to 11), while foliation spacing decreases to <20 μm. This foliation evolution under non-coaxial deformation involves a combination of mechanical rotation of phyllosilicates, fracturing, and fluid-assisted pressure-dissolution-precipitation creep. The latter is the dominant deformation mechanism at T > 230 °C and accommodates background strain in the inner wedge. The evolving microstructural anisotropy is interpreted to lead to strain weakening by structural softening and may provide preferential fluid pathways parallel to the foliation, enabling the dehydration of large rock volumes in accretionary sediment wedges undergoing prograde metamorphism. • From outer to inner wedge slate fabrics change from isotropic to densely spaced. • Fabric intensity is a function of increasing metamorphic grade. • Pressure-dissolution-precipitation creep is dominant at T > 230 °C. • Increase in foliation density indicates increasing finite strain in the inner wedge. • Background strain in the inner wedge is accommodated by pressure solution. [ABSTRACT FROM AUTHOR]

White mica has been widely used to date microstructures and tectonic events in faults, shear-zones and folds because of its suitability for radiogenic dating. However, complex (i) microstructural evolution, (ii) individual chemical evolution of the K-bearing phases, (iii) mixing of 'detrital grains' with newly formed and/or recrystallized or chemically reset grains as well as (iv) volume diffusion may result in apparent K-Ar ages. Here, specimens from a prograde sediment sequence of the exhumed fossil European Alpine accretionary wedge were used to investigate resetting processes of white mica by the type and intensity of deformation as well as peak metamorphic conditions. We combine the K-Ar system with mass and mineral quantities from grain size fractions to calculate the amount of recrystallized white mica in each grain size fraction along the metamorphic gradient. Increasing recrystallization with increasing metamorphic grade is related to thermally activated pressure solution and dissolution-precipitation creep, as seen by the formation of a spaced cleavage of recrystallized phyllosilicates documented through Synchrotron X-ray Fluorescence Microscopy and Scanning Electron Microscope imaging techniques. Increasing recrystallization by dissolution-precipitation processes induces chemical resetting of the isotopic system, resulting in a prograde decrease of apparent K-Ar ages. We demonstrate that Ar volume diffusion does not play a significant role for the low-temperature samples, promoting recrystallization as the important physico-chemical process for age resetting. However, white mica chemistry reveals that no simple relation between isotopic resetting and grain size exists along the prograde path. Reliable age information can therefore only be obtained in the case of (nearly) complete resetting, which accounts only for the smallest grain size fraction at the highest metamorphic temperature. These findings could shed new light on accurate dating of mica-rich fault rocks, where the time constraints depend not only on the temperature, but also on the amount and type of deformation. • We investigate resetting mechanisms in white mica from a prograde sediment sequence. • Isotopic resetting is related to ductile dissolution-precipitation processes. • No simple relation between isotopic resetting and grain size exists. • Reliable age information is only obtained in case of complete resetting. • Complete resetting is reported for smallest grains at highest metamorphic grade. [ABSTRACT FROM AUTHOR]