1. Enhanced dielectric, ferroelectric and magnetic properties of Ba4Sm2Fe2Nb8O30 RT multiferroics prepared by microwave sintering.
- Author
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Huang, X., Liu, Y.T., Luo, G.S., Lin, C., Wu, X., Zheng, X.H., and Tang, D.P.
- Subjects
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MICROWAVE sintering , *TUNGSTEN bronze , *MAGNETIC properties , *MULTIFERROIC materials , *FERROELECTRIC ceramics , *DIELECTRICS , *POINT defects - Abstract
High density Ba 4 Sm 2 Fe 2 Nb 8 O 30 (BSFN) multiferroics ceramics with tetragonal tungsten bronze structure had been prepared by microwave sintering (MS) for 30min and conventional sintering (CS) methods for 4 h at 1275 °C. Single tungsten bronze phase and equiaxial grains are obtained for the MS BSFN ceramics, while a small amount secondary phase of SmNbO 4 is observed in the CS BSFN ceramics with columnar grains. Compared to Ba 4 Sm 2 Fe 2 Nb 8 O 30 ceramics prepared by CS method, enhanced dielectric, ferroelectric and magnetic properties are achieved for the MS BSFN ceramics. The values of electric polarization Pr and coercive electric field Ec are 2.11 μC/cm2 and 7.14 kV/cm for the MS BSFN ceramics, respectively. Meantime, the magnetic polarization Mr of 0.410emu/g and coercive magnetic field Hc of 2930Oe are also obtained for the MS BSFN ceramics. Based on the density, crystal structure, point defect and grain, the reasons of enhanced dielectric, ferroelectric and magnetic properties are discussed for the MS BSFN ceramics It is indicated that Ba 4 Sm 2 Fe 2 Nb 8 O 30 is an intrinsic room temperature multiferroic materials. [ABSTRACT FROM AUTHOR]
- Published
- 2021
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