1. Influence of Cr3+ substitution for Mg2+ on the crystal structure and microwave dielectric properties of CaMg1-xCr2x/3Si2O6 ceramics.
- Author
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Tang, Bin, Xiang, Qiuyuan, Fang, Zixuan, Zhang, Xing, Xiong, Zhe, Li, Hao, Yuan, Changlai, and Zhang, Shuren
- Subjects
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MICROWAVES , *DIELECTRIC properties , *CRYSTAL structure , *SPECIFIC gravity , *CERAMICS , *DIFFRACTION patterns , *MICROWAVE sintering - Abstract
The CaMg 1 -x Cr 2 x /3 Si 2 O 6 (0 ≤ x ≤ 0.1) microwave dielectric ceramics were synthesized via conventional solid state reaction. In this study, the effects of Cr3+ substituting for Mg2+ on morphology, crystal structure and microwave dielectric properties of CaMg 1 -x Cr 2 x /3 Si 2 O 6 ceramics were explored. XRD diffraction patterns exhibited that the CaMg 1 -x Cr 2 x /3 Si 2 O 6 ceramics possessed the pure phase of CaMgSi 2 O 6 when x ≤ 0.06 and a small amount of secondary phase Ca 3 Cr 2 (SiO 4) 3 for 0.08 ≤ x ≤ 0.1. SEM micrographs revealed that the substitution of Mg2+ with Cr3+ could decrease the grain size. The apparent density was affected by the concentration of Mg vacancies. The correlation between crystal structure and microwave dielectric properties was investigated through the Rietveld refinement and Raman analysis. The microwave dielectric properties were mainly dependent on relative density, ionic polarizabilities, internal strain Ƞ, disordered structure and MgO 6 octahedron distortions. Finally, CaMg 1 -x Cr 2 x /3 Si 2 O 6 (x = 0.02) ceramics sintered at 1270 °C for 3 h exhibited excellent microwave dielectric properties of ε r = 8.06, Q × f = 89054 GHz, τ f = −44.92182 ppm/ºC. [ABSTRACT FROM AUTHOR]
- Published
- 2019
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