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Carbonatite intrusions host the world's most important light rare earth element (LREE) deposits, and their formation generally requires extraordinary fertile sources, magmatic evolution, and hydrothermal events. However, carbonatitic magma evolution, particularly the role of fractional crystallization and contamination from silicate rocks in REE enrichment, remains enigmatic. The Maoniuping world-class REE deposit in southwestern China, is an ideal target to decipher magmatic evolution and related REE enrichment as it shows continuous textual evolution from medium- to coarse-grained calcite carbonatite (carbonatite I) at depth, to progressively pegmatoidal calcite carbonatite (carbonatite II) at shallow levels. In both types of calcite carbonatites, four generations of calcite can be classified according to petrographic and geochemical characteristics. Early-crystalizing calcite (Cal-I and Cal-II) are found in carbonatite I and exhibit equigranular and a polygonal mosaic textures, while late calcites (Cal-III and Cal-IV) in carbonatite II are large-size oikocrysts (>0.5 mm in length) with strain-induced undulatory extinction and bent twinning lamellae. All these generations of calcite yield similar, near-chondritic, Y/Ho ratios (26.6–28.1) and are inferred to be of magmatic origin. Remarkably, gradual enrichment of MgO, FeO and MnO from Cal-I to Cal-IV is coupled with a significant increase in REE contents (~800 to 2000 ppm), with LREE-rich and gentle-to-steep chondrite-normalized REE patterns ((La/Yb)N = 3.1–26.8 and (La/Sm)N = 0.9–3.9, respectively). Such significant REE enrichment is ascribed to protracted magma fractional crystallization with initial low degree of fractional crystallization (fraction of melt remining (F) = ~0.95) evolving to late stage (F = 0.5–0.6) by formation of abundant calcite cumulates. Differential LREE and HREE behavior during magma evolution largely depend on separation of phlogopite, amphibole, and clinopyroxene from the carbonatitic melt, which is indicated by progressively elevated (La/Yb)N ratios ranging from 3.1 to 26.8. The four generations of calcite have significantly different C and Sr isotopic compositions with δ13CV-PDB decreasing from −3.28 to −9.97‰ and 87Sr/86Sr increasing from 0.70613 to 0.70670. According to spatial relations and petrographic observations, the relative enrichment of δ13C and depletion in 87Sr/86Sr ratios of Cal-I and Cal-II show primary isotopic characteristics inherited from initial carbonatitic magma. By contrast, the variable Sr and C isotopic compositions of Cal-III and Cal-IV are interpreted as the results of contamination by components derived from silicate wall rocks and loss of CO2 by decarbonation reactions. To model such contamination processes, Raleigh volatilization and Monte Carlo simulation have been invoked and the model results reveal that carbonatitic melt-wall rock interaction requires 40% radiogenic Sr contamination from silicate rocks and 35% CO2 degassing from carbonatitic melt. Moreover, positive correlations between decreasing δ13C values and increasing REE contents, together with bastnäsite-(Ce) precipitation, indicate further REE accumulation during the contamination processes. In summary, alongside REE-rich magma sources, the extent of fractional crystallization and contamination during carbonatitic magma evolution are inferred to be important mechanisms in terms of REE enrichment and mineralization in carbonatite-related REE deposits worldwide. [ABSTRACT FROM AUTHOR]

The Tethyan metallogenic domain (TMD), as one of the three major domains in the world, extends over 10000 km from east to west, and has developed several world-class metallogenic belts, such as the Gangdese porphyry Cu belt, the Sanjiang metallogenic belt, the Iran porphyry Cu belt, the Pakistan porphyry Cu belt, the southeastern European epithermal gold deposit belt, and the Southeast Asian Sn belt. The formation and evolution of the TMD is mainly controlled by the multi-stage subduction of Tethys oceanic slabs, the opening and closing of several small ocean basins, and continent-continent collision. The Tethys oceans include the Proto-Tethys (Cambrian-Silurian), Paleo-Tethys (Carbonaceous-Triassic) and Neo-Tethys (Jurassic to Cretaceous), which in turn are formed by rifting from the Gondwana land at different times in different micro-continents. With a series of geological processes such as oceanic opening and closing, continental collision and post-collisional reworking with intraplate deformation, various types of ore deposits are developed in the TMD, including porphyry deposits, epithermal deposits, VMS deposits, chromite deposits, Sn deposits and orogenic gold deposits. The metallogenic processes of the TMD can be categorized into three stages. (1) Oceanic subduction: With the subduction of the oceanic slab and dehydration of basalt and sediments, the asthenospheric mantle was metasomatized with preliminary enrichment in metals under oxidized condition. (2) Continental subduction: Continental collision induced partial melting of the mantle wedge enriched the metals and water in mafic melts, which ascended from subarc depths to the lower crust, locally to the shallow crust for hydrothermal mineralization. (3) Post-collisional reworking: Partial melting of the mafic intrusives in the lower crust produced felsic melts under oxidized and water-rich conditions, which underwent crystal fractionation and transferred water and metals into hydrothermal fluids for mineralization. The large-scale porphyry mineralization in the TMD mainly occurs in the Miocene, which is an important scientific issue worthy of further study in the future. How is the metal enriched in the processes of gradual maturity of the crust, and how does large-scale mineralization occur in a collisional orogen where there is no subduction and dehydration of oceanic slabs anymore to supply S and Cl? These are still important questions in the study of porphyry mineralization in the Tethyan orogen. The application of hyperspectral and mineralogical studies of alteration assemblages is beneficial for prospecting and exploration in the TMD. [ABSTRACT FROM AUTHOR]

Rare-earth deposits associated with intrusive carbonatite complexes are the world's most important source of these elements (REE). One of the largest deposits of this type is Maoniuping in the Mianning-Dechang metallogenic belt of eastern Tibet (Sichuan, China). In the currently mined central part of the deposit (Dagudao section), REE mineralization is hosted by a structurally and mineralogically complex Late Oligocene (26.4 ± 1.2 Ma, 40Ar/39Ar age of fluorphlogopite associated with bastnäsite) hydrothermal vein system developed in a coeval syenite intrusion. Low-grade stockworks of multiple veinlets and breccias in the lower part of the orebody grade upwards into progressively thicker veins (up to 12 m in width) that are typically zoned and comprise ferromagnesian micas (biotite to fluorphlogopite), sodium clinopyroxenes (aegirine to aegirine-augite), sodium amphiboles (magnesio-arfvedsonite to fluororichterite), K-feldspar, fluorite, barite, calcite, and bastnäsite. The latter four minerals are most common in the uppermost 80 m of the Dagudao section and represent the climax of hydrothermal activity. Systematic variations in the fluid inclusion data indicate a continuous hydrothermal evolution from about 230–400 °C (fluid inclusions in feldspar, clinopyroxene, and amphibole) to 140–240 °C (fluid inclusions in bastnäsite, fluorite, calcite). Hydrothermal REE transport was probably controlled by F−, (SO4)2−, Cl−, and (CO3)2− as complexing ligands. We propose that at Dagudao, silicate magmas produced orthomagmatic fluids that explored and expanded a fissure system generated by strike-slip faulting. Initially, the fluids had appreciable capacity to transport REE and, consequently, no major mineralization developed. The earliest minerals to precipitate were alkali- and Fe-rich silicates containing low levels of F, which caused progressive enrichment of the fluid in Ca, Mg, F, Cl, REE, (SO4)2−, and (CO3)2−, leading to the crystallization of aegirine-augite, fluororichterite, fluorphlogopite, fluorite, barite, calcite, and bastnäsite gradually. Barite, fluorite, calcite, and bastnäsite are the most common minerals in typical ores, and bastnäsite generally postdates these gangue minerals. Thus, it is very probable that fluid cooling and formation of large amount of fluorite, barite, and calcite triggered bastnäsite precipitation in the waning stage of hydrothermal activity. [ABSTRACT FROM AUTHOR]

Located in the eastern section of the Indus‐Yarlung Tsangbo Suture Zone, the Triassic Langjiexue Group is also very important for the distribution of the orogenic gold deposits, such as Bangbu and Zhemulang. Two regional profiles (Jiacha profile and Lang County profile) in the Langjiexue Group have been chosen for systematic mapping. Combing with the method of Ar–Ar dating for mica, this paper provides a detailed analysis of the structural movements and stress periods of the Langjiexue Group, and the relationship between them with the orogenic gold deposits distributed within it, and finally, establish the structural control model for orogenic gold deposits in the Langjiexue Group. The structural deformation of the Langjiexue Group can be divided into 4 stages. In the D1 stage, shallow ductile shear played a dominant role with the principal stress of the reaction in a nearly E–W direction. The main stress of D2 stage was in an obviously S–N direction whose foliation of the axial surface was a ubiquitous phyllitic foliation and foliation. The structures of the D3 stage were superimposed on those of the D2 stage with the main stress of S–N direction. In the D4 stage, the principal stress of the structural movements was in a nearly E–W direction. According to the morphology and spatial positions of the profile folds, the main body of the Songre Formation in the southern parts of the tectonic profiles can be restored into a large reverse antiform, whereas the main body of the Tectonic mélange zone in the northern parts can be restored into a continuous large antiform and synform. Judging by the Ar–Ar plateau ages (56.04 ± 0.72 Ma, 47.98 ± 0.46 Ma) of the sericite in the two quartz veins that were arranged along the axial plane cleavage of the folders in D3 stage, the widely distributed quartz veins in the Langjiexue Group were mainly the outcome of fluid action accompanied by the structural deformation that occurred in the main Indo‐Asian collision orogenesis period, which were in consistent with the mineralogenetic epoch of the orogenic gold deposits in this region. [ABSTRACT FROM AUTHOR]

Abstract: The Zhaxikang Pb‐Zn‐Ag‐Sb deposit, the largest polymetallic deposit known in the Himalayan Orogen of southern Tibet, is characterized by vein‐type mineralization that hosts multiple mineral assemblages and complicated metal associations. The deposit consists of at least six steeply dipping vein‐type orebodies that are hosted by Early Jurassic black carbonaceous slates and are controlled by a Cenozoic N–S‐striking normal fault system. This deposit records multiple stages of mineralization that include an early period (A) of massive coarse‐grained galena–sphalerite deposition and a later period (B) of Sb‐bearing vein‐type mineralization. Period A is only associated with galena–sphalerite mineralization, whereas period B can be subdivided into ferrous rhodochrosite–sphalerite–pyrite, quartz–sulfosalt–sphalerite, calcite–pyrite, quartz–stibnite, and quartz‐only stages of mineralization. The formation of brecciated galena and sphalerite ores during period A implies reworking of pre‐existing Pb–Zn sulfides by Cenozoic tectonic deformation, whereas period B mineralization records extensive open‐space filling during ore formation. Fluid inclusion microthermometric data indicate that both periods A and B were associated with low–medium temperature (187–267°C) and low salinity (4.00–10.18% wt. NaCl equivalent) ore‐forming fluids, although variations in the physical–chemical nature of the period B fluids suggest that this phase of mineralization was characterized by variable water/rock ratios. Microprobe analyses indicate that Fe concentrations in sphalerite decrease from period A to period B, and can be divided into three groups with FeS concentrations of 8.999–9.577, 7.125–9.109, 5.438–1.460 mol.%. The concentrations of Zn, Sb, Pb, and Ag within orebodies in the study area are normally distributed in both lateral and vertical directions, and Pb, Sb, and/or Ag concentrations are positive correlation within the central part of these orebodies, but negatively correlate in the margins. Sulfide S isotope compositions are highly variable (4‰–13‰), varying from 4‰ to 11‰ in period A and 10‰ to 13‰ in period B. The Pb isotope within these samples is highly radiogenic and defines linear trends in 206Pb/204Pb vs. 207Pb/204Pb and 206Pb/204Pb vs. 208Pb/204Pb diagrams, respectively. The S and Pb isotopic characteristics indicate that the period B orebodies formed by mixing of Pb–Zn sulfides and regional Sb‐bearing fluids. These features are indicative of overprinting and remobilization of pre‐existing Pb–Zn sulfides by Sb‐bearing ore‐forming fluids during a post‐collisional period of the Himalayan Orogeny. The presence of similar ore types in the north Rhenish Massif that formed after the Variscan Orogeny suggests that Zhaxikang‐style mineralization may be present in other orogenic belts, suggesting that this deposit may guide Pb–Zn exploration in these areas. [ABSTRACT FROM AUTHOR]

The recently discovered Zhuxi W–Cu ore deposit is located within the Taqian–Fuchun Ore Belt in the southeastern edge of the Yangtze Block, South China. Its inferred tungsten resources, based on new exploration data, are more than 280 Mt by 2016. At least three paragenetic stages of skarn formation and ore deposition have been recognized: prograde skarn stage; retrograde stage; and hydrothermal sulfide stage. Secondly, greisenization, marmorization and hornfels formation are also observed. Scheelite and chalcopyrite are the dominant metal minerals in the Zhuxi deposit and their formation was associated with the emplacement of granite stocks and porphyry dykes intruded into the surrounding Carboniferous carbonate sediments (Huanglong and Chuanshan formations) and the Neoproterozoic slate and phyllites. The scheelite was mostly precipitated during the retrograde stage, whereas the chalcopyrite was widely precipitated during the hydrothermal sulfide stage. A muscovite 40 Ar/ 39 Ar plateau age of about 150 Ma is interpreted as the time of tungsten mineralization and molybdenite Re–Os model ages ranging from 145.9 ± 2.0 Ma to 148.7 ± 2.2 Ma (for the subsequent hydrothermal sulfide stage of activity) as the time of the copper mineralization. Our new molybdenite Re–Os and muscovite 40 Ar/ 39 Ar dating results, along with previous zircon U–Pb age data, indicate that the hydrothermal activity from the retrograde stage to the last hydrothermal sulfide stage lasted up to 5 Myr, from 150.6 ± 1.5 to 145.9 ± 1 Ma, and is approximately coeval or slightly later than the emplacement of the associated granite porphyry and biotite granite. The new ages reported here confirm that the Zhuxi tungsten deposit represents one of the Mesozoic magmatic–hydrothermal mineralization events that took place in South China in a setting of lithospheric extension during the Late Jurassic (160–150 Ma). It is suggested that mantle material played a role in producing the Zhuxi W–Cu mineralization and associated magmatism. [ABSTRACT FROM AUTHOR]

The Cenozoic Mianning–Dechang (MD) rare earth element (REE) belt in eastern Tibet is an important source of light REE in southwest China. The belt is 270 km long and 15 km wide. The total REE resources are >3 Mt of light rare earth oxides (REO), including 3.17 Mt of REO at Maoniuping (average grade = 2.95 wt.%), 81,556 t at Dalucao (average grade = 5.21 wt.%), 0.1 Mt at Muluozhai (average grade = 3.97 wt.%), and 5764 t of REO at Lizhuang (average grade = 2.38 wt.%). Recent results from detailed geological surveys, and studies of petrographic features, ore-forming ages, ore forming conditions, and wallrock alteration are synthesized in this paper. REE mineralization within this belt is associated with carbonatite–syenite complexes, with syenites occurring as stocks intruded by carbonatitic sills or dikes. The mineralization is present as complex vein systems that contain veinlet, stringer, stockwork, and brecciated pipe type mineralization. Carbonatites in these carbonatite-related REE deposits (CARDs) are extremely rich in light REEs, Sr (>5000 ppm), and Ba (>1000 ppm), and have low Sr/Ba and high Ba/Th ratios, and radiogenic Sr–Nd isotopic compositions. These fertile magmas, which may lead to the formation of REE deposits, were generated by the partial melting of sub-continental lithospheric mantle (SCLM) that was metasomatized by REE- and CO 2 -rich fluids derived from subducted marine sediments. We suggest that this refertilization occurred along cratonic margins and, in particular, at a convergent margin where small-volume carbonatitic melts ascended along trans-lithospheric faults and transported REEs into the overlying crust, leading to the formation of the CARDs. The formation of fertile carbonatites requires a thick lithosphere and/or high pressures (>25 kbar), a metasomatized and enriched mantle source, and favorable pathways for magma to ascend into the overlying crust where REE-rich fluids exsolve from cooling magma. The optimal combination of these three factors only occurs along the margins of a craton with a continental root, rather than in modern subduction zones where the lithosphere is relatively thin. U–Pb zircon dating indicates that the Maoniuping, Lizhuang, and Muluozhai alkali igneous complexes in the northern part of the belt formed at 27–22 Ma, whereas the Dalucao complex in the southern part of the belt formed at 12–11 Ma. Biotite and arfvedsonite in Lizhuang and Maoniuping REE deposit have 40 Ar/ 39 Ar ages of 30.8 ± 0.4 Ma (MSWD = 0.98) and 27.6 ± 2.0 Ma (MSWD = 0.06), respectively. Biotitaion alteration in syenite and fenitization caused by the relatively amount of carbonatite on syenite and host rocks is the main alteration along the whole belt. Initial Sr (0.7059–0.7079), 143 Nd/ 144 Nd (0.5123–0.5127), and 207 Pb/ 204 Pb (15.601–15.628) and 208 Pb/ 204 Pb (38.422–38.604) isotopic compositions of fluorite, barite, celestite, and calcite in the MD belt are similar to those of the associated syenite and carbonatite. Given the relatively high contents of Cl, F, SO 4 2− , and CO 2 in the rocks of the complexes, it is likely that the REEs were transported by these ligands within hydrothermal fluids, and the presence of bastnäsite indicates that the REEs were precipitated as fluorocarbonates. Petrographic, fluid inclusion, and field studies of the ores indicate that bastnäsite and other REE minerals formed during the final stages (<300 °C) of the evolution of magmatic–hydrothermal systems in the belt. The mineralization formed from magmatic and meteoric fluids containing CO 2 derived from the decarbonation of carbonatite, as indicated by C–O isotopic values of hydrothermal calcite and bastnäsite (δ 13 C = −4.8 to −8.7 and δ 18 O = 5.8 to 12.5‰) and O–H isotopic values of quartz (330 °C) and arfvedsonite (260 °C), which correspond to fluid isotope compositions of δ 18 O = 0.3–9.8‰ and δD = −70.0 to −152.8‰ in the belt. This study indicates that formation the largest REE deposits are related to voluminous carbonatite–syenite complexes, compositionally similar ore-forming fluids, extensive alteration, multiple stages of REE mineralization, and tectonic setting. [ABSTRACT FROM AUTHOR]

The Himalayan Mianning–Dechang (MD) rare earth element (REE) belt in western Sichuan Province, southwestern China, is approximately 270 km long and 15 km wide, and contains total reserves of more than 3 Mt of light REEs (LREEs), comprising one giant (Maoniuping), one large (Dalucao), two small–medium-sized (Muluozhai and Lizhuang), and numerous smaller REE deposits. The belt occurs within the eastern Indo-Asian collision zone (EIACZ), where its location is controlled by large-scale strike-slip faults and tensional fissure zones. Himalayan carbonatite–syenite complexes consist predominantly of alkaline syenite stocks and carbonatite sills or dikes that host REE mineralization. Previous studies have reported inconsistent ages for alkaline magmatism syenite formation and REE mineralization. Here, we present new results of sensitive high-resolution ion micro-probe U–Pb dating of zircons from syenites from the Dalucao, Maoniuping, Lizhuang and Diaoloushan areas, the first systematic and precise age determinations for these rocks in the MD belt. The new data give concordant ages of 12.13 ± 0.19 and 11.32 ± 0.23 Ma for the Dalucao deposit, 22.81 ± 0.31 and 21.3 ± 0.4 Ma for Maoniuping, 26.77 ± 0.32 Ma for Muluozhai, and 27.41 ± 0.35 Ma for Lizhuang. These ages, which should be regarded as maximum ages for the REE mineralization in the study area, can be split into two groups, i.e. 11–12 Ma in the southern part of the MD belt and 12–27 Ma in the northern part, suggesting a progression of magmatism from north to south. These data suggest that the majority of carbonatite–syenite magmatism within the EIACZ occurred during the main stage of Himalayan metallogenesis. The ages presented in this study suggest that strike-slip shear along the MD belt was initiated at ca. 27 Ma and ended ca. 12 Ma. This timing is consistent with movements along the adjacent Ailaoshan–Red River strike-slip fault in southeastern Tibet (to the south of the MD belt) and one of the three Cenozoic strike-slip faults in eastern Tibet. Ascent of an asthenospheric mantle diapir beneath the EIACZ in the Cenozoic may have provided a thermal mechanism for the generation of magmas that formed the carbonatite–syenite complexes in the study area. Alternatitvely, the magmas may have been generated by decompression melting associated with the transition from a transpressional to a transtensional regime at 38–40 Ma. The precise age results for syenite magmatism in the study area indicate that this transition occurred prior to carbonatite–syenite magmatism and the formation of the MD REE belt, which is consistent with the regional tectonic model. [ABSTRACT FROM AUTHOR]

Located on the northeast margin of the Qiangtang terrane between the Jinshajiang suture zone and Bangonghu-Nujiang suture zone, the Dongmozhazhua and Mohailaheng Pb-Zn deposits in the Yushu area of Qinghai Province are representative Pb-Zn deposits of the Pb-Zn-Cu polymetallic mineralization belt in the northern part of the Nujiang-Lancangjiang-Jinshajiang area, which are in the front belt of the Yushu thrust nappe system. The formed environments of these two deposits are different from those of sediment-hosted base metal deposits elsewhere in the world. The authors hold that they were formed during the Indian-Asian continental collision and developed within the fold-thrust belt combined with thrust and strike-slip-related Cenozoic basins in the interior of the collisional zone. Studying on the metallogenic epochs of these two deposits is helpful to the understanding of ore-forming regularity of the regional Pb-Zn-Cu mineralization belt and also to the search for new deposits in this region. The age of the Dongmozhazhua deposit has been determined by the Rb-Sr isochron method for sphalerite residues, whereas the age of the Mohailaheng deposit has been determined by the Rb-Sr isochron method for sphalerite residues and the Sm-Nd isochron method for fluorite. The age of the Dongmozhazhua deposit is 35.0±0.0 Ma ((87Sr/86Sr)0=0.708807) for sphalerite residues. The age of the Mohailaheng deposit is 32.2±0.4 Ma ((87Sr/86Sr)0=0.708514) for sphalerite residues and 31.8±0.3 Ma ((143Nd/144Nd)0=0.512362) for fluorite with an average of 32.0 Ma. Together with the regional geological setting during mineralization, a possible tectonic model for metallogeny of the Dongmozhazhua and Mohailaheng Pb-Zn deposits has been established. These two ages are close to the ages of the Pb-Zn deposits in the Lanping and Tuotuohe basins, indicating that it is possible that the narrow 1000-kilometer-long belt controlled by a thrust nappe system on the eastern and northern margins of the Tibetan plateau could be a giant Pb-Zn mineralized belt. [ABSTRACT FROM AUTHOR]

The Dexing porphyry Cu–Mo–Au deposit in east China (1,168 Mt at 0.45 % Cu) is located in the interior of the South China Craton (SCC), made up of two lithospheric blocks, the Yangtze and Cathaysia blocks. The Cu–Mo–Au mineralization is associated with mid-Jurassic granodioritic porphyries with three high-level intrusive centers, controlled by a series of lineaments at the southeastern edge of the Yangtze block. Available age data define a short duration (172–170 Ma) of the felsic magmatism and the mineralization (171 ± 1 Ma). The deposit shows broad similarities with deposits in volcanoplutonic arcs, although it was formed in an intracontinental setting. Porphyries associated with mineralization are mainly granodiorites, which contain abundant phenocrysts (40–60 %) and carry contemporaneous microgranular mafic enclaves (MMEs). They are mainly high-K calc-alkaline and show geochemical affinities with adakite, characterized by relatively high MgO, Cr, Ni, Th, and Th/Ce ratios. The least-altered porphyries yielded relatively uniform εNd( t) values from −0.9 to +0.6, and wide ( 87Sr/ 86Sr) i range between 0.7046 and 0.7058 partially overlapping with the Sr–Nd isotopic compositions of the MMEs and mid-Jurassic mafic rocks in the SCC. Zircons from the porphyries have positive εHf( t) values (3.4 to 6.9), and low δ 18O values (4.7 to 6.3 ‰), generally close to those of depleted mantle. All data suggest an origin by partial melting of a thickened juvenile lower crust involving mantle components (e.g., Neoproterozoic mafic arc magmas), triggered by invasion of contemporaneous mafic melts at Dexing. The MMEs show textural, mineralogical, and chemical evidence for an origin as xenoliths formed by injection of mafic melts into the felsic magmas. These MMEs usually contain magmatic chalcopyrite, and have original, variable contents of Cu (up to 500 ppm). Their geochemical characteristics suggest that they were derived from an enriched mantle source, metasomatized by Proterozoic slab-derived fluids, and supplied a part of Cu, Au, and S for the Dexing porphyry system during their injection into the felsic magmas. The 171 ± 1 Ma magmatic-hydrothermal event at Dexing is contemporaneous with the mid-Jurassic extension in the SCC, followed by 160–90 Ma arc-like magmatism in southeastern China. With respect to the tectono-magmatic evolution of the SCC, the emplacement of Cu-bearing porphyries and the associated Cu mineralization occurred in response to the transformation from a tensional regime, related to mid-Jurassic extension, to a transpressional regime, related to the subduction of the Paleo-Pacific oceanic lithosphere. [ABSTRACT FROM AUTHOR]

The article reports on geological study of Pb-Zn deposits located in Narusonghuo, China. Topics discussed include several Pb-Zn mineralization formed by various physical processes chloritization, silicification and carbonation, found in the region, associated with quartz syenite porphyry, geochemical analysis on the same and role of Neo Tethys oceanic crust and wedge mantle in formation of Narusongduo porphyry magma, with characteristic chemical geology.

Fault zones control the locations of many ore deposits, but the ore-forming processes in such fault zones are poorly understood. We have studied the deformation and ore textures associated with fault zones that controlled the lead–zinc mineralization of the Dongmozhazhua deposit, central Tibet, ∼100 km southwest of Yushu City. Geological mapping shows that the structural framework of the Dongmozhazhua area is defined by NW–SE-trending reverse faults and superposed folds that indicate at least two stages of deformation. The first stage is characterized by tight nearly E–W-striking folds that formed during the closure of the Jinshajiang Paleo-Tethyan Ocean in the Triassic. The second stage of deformation produced NW–SE-trending reverse faults and related structures of the Fenghuoshan–Nangqian fold-and-thrust belt associated with India–Asia collision in the late Eocene to Oligocene. Scanline surveys along the ore-controlling fault zones show an internal structure that comprises a damage zone, a breccia zone with clasts that have become rounded, and a breccia zone with lenticular clasts, and this complex architecture was formed during at least two compressional substages of deformation. The Pb–Zn mineralization in the Dongmozhazhua area occurs exclusively close to NW–SE-trending reverse fault zones. Microtextural observations reveal that mineralization occurred as veinlets and disseminated blebs in limestone clasts, and as continuous bands and cements in fractured rocks. Cataclastic sulfide grains also can be seen in the matrix of some fault zones. The types of mineralization differ with structural position. The fillings of the ore-bearing veinlets typify the products of hydraulic fracture and both types of mineralization took place concurrently with regional contraction. We consider, therefore, that the ore-bearing fluids in the Dongmozhazhua deposit were concentrated in fault zones during regional compression and that the ore minerals were precipitated during hydraulic fracturing of host rocks. Subsequent fault activity pulverized some pre-existing sulfide material into cataclastic grains in the matrix of a tectonic breccia that developed in the same faults. [ABSTRACT FROM AUTHOR]

This study determined the chemical and stable isotopic (B, H, and O) compositions of three stages of ore-related hydrothermal tourmaline in the newly discovered Maocaoping vein-type Cu deposit, western Yunnan, China, as well as the chemical and B isotopic compositions of magmatic tourmaline (tourmaline-G) from a neighboring peraluminous granitic intrusion that is contemporaneous with the Cu mineralization. The objective was to constrain the source and evolution of the CO 2 -rich ore-forming fluid. The Maocaoping cupriferous veins (types V1 and V2) are hosted in mylonitized and metamorphosed Jurassic sedimentary rocks. Early- to late-stage hydrothermal tourmaline occurs as vein-related alteration halos (tourmaline-A) in altered marble or schist, as tourmaline-V1 in type V1 veins, and as tourmaline-V2 in type V2 veins. Tourmaline-A, -V1, and -V2 belong to the alkalic group and consist mostly of dravite, with δ 11 B values of − 3.9‰ to − 1.1‰, − 2.8‰ to + 0.5‰, and − 6.3‰ to − 3.9‰, respectively. Tourmaline-G belongs to the alkalic group and consists of schorl, with δ 11 B values of − 14.7‰ to − 12.2‰. The similarities in chemical composition between marble- and schist-hosted tourmalines and between tourmalines in veins and alteration halos (indicating their formation at different water/rock ratios) suggest that the compositions of the hydrothermal tourmaline at Maocaoping were controlled mainly by the chemistry of ore fluid rather than that of the host rocks. The similarities together with the lack of systematic variations in δ 11 B values in individual tourmaline grains imply that mixing of multiple fluids cannot be important during the mineralization. The positive shift in δ 11 B values from tourmaline-A to tourmaline-V1 is interpreted to result from continuous precipitation of tourmaline in a closed fluid system. Relative to tourmaline-A and -V1, tourmaline-V2 is Fe-rich, Al-poor, and 11 B-depleted. These differences may be explained by fluid phase separation and subsequent escape of the CO 2 -rich vapor phase during the formation of type V2 veins, consistent with the observations that these veins are extensional, contain large amounts of carbonate minerals, and include fluid inclusions trapped in the vapor–liquid two-phase field. The earliest tourmaline-A records the initial ore fluid chemistry. The calculated δ 11 B, δ 18 O, and δD values of the initial ore fluid in equilibrium with tourmaline-A at mineralization temperatures of 280 to 320 °C are − 0.3‰ to + 3.0‰, + 10.7‰ to + 11.8‰ and − 110‰ to − 84‰, respectively. The δ 11 B values as well as the chemical compositions of tourmaline-A are much different from those of tourmaline-G, suggesting that the ore fluid at Maocaoping was not derived directly from the peraluminous granitic magma. The B–H–O isotopic features as well as enrichment of CO 2 in fluid inclusions also suggest the ore fluid cannot solely be derived from basinal fluid or meteoric water. The simplest explanation is that the fluid was derived from a metamorphic fluid that had obtained isotopically lighter hydrogen via reaction with “organic” compounds (e.g., CH 4 , H 2 S). Alternatively, the ore fluid sourced from the mixed metamorphic fluid and basinal brine, meteoric water, or degassed magmatic fluid. It implies that the vein Cu ore formation in the Lanping Basin is unlikely as a result of a sole magmatic or basinal fluid activity and it needs the involvement of metamorphic fluid/process. [ABSTRACT FROM AUTHOR]

[Display omitted] • Late Mesozoic granites in the Pingmiao deposit intruded at ca. 146–143 Ma. • The Pingmiao granites mainly derived from the Proterozoic metamorphic basement. • The Pingmiao granites have reduced redox state. • The Pingmiao granites are favorable for W, Sn, Nb, and Ta mineralization. The Pingmiao W (Cu) deposit is located in the central part of the newly-discovered giant Dahutang ore-concentrated district, South China. Field relationships and mineral assemblages confirm that the W (Cu) mineralization in the Pingmiao deposit is genetically related to multiphase late Mesozoic granites, which include the porphyritic two-mica granite, biotite granite porphyry, fine-grained muscovite granite, and Li-mica albite granite. Zircon U–Pb dating shows that these granites emplaced at ca. 146–143 Ma, which are coeval with the W–Cu–Mo-bearing granitoids from other ore deposits in the Dahutang district. The strongly peraluminous (A/CNK > 1.1) feature, negative correlations between Rb and Th and between Rb and P 2 O 5 , low Zr + Nb + Ce + Y values (mostly lower than 200), and relatively low Zr saturation temperatures (lower than 800 °C) suggest that these granites are typical S-type granite. These granites show similar Nd isotopes (−8.91 to −4.61), CaO/Na 2 O (0.2–0.57), and Al 2 O 3 /TiO 2 (mostly ranging of 50–90) ratios with those W–Cu–Mo-bearing granitoids from other ore deposits in the Dahutang district, suggesting that they derived from partial melting of metapelites in the Shuangqiaoshan Group (or the Proterozoic metamorphic basement geochemically similar to the Shuangqiaoshan Group), with involving of minor mafic–ultramafic volcanic rocks. Geochemical fractionation trends recorded by whole-rocks and micas permit to distinguish the evolutionary trend from the porphyritic two-mica granite and biotite granite porphyry to the fine-grained muscovite granite and Li-mica albite granite. The apparent rare earth element tetrad effect, high Li and F contents, low K/Rb, Zr/Hf, and Nb/Ta ratios, as well as the zoned features of micas suggest that the melt–fluid interaction occurring during the formation of Li-mica albite granite. The Pingmiao granites have reduced redox state, revealed by their low whole-rock Fe 2 O 3 /FeO ratios (mostly <0.5), biotite Fe3+/Fe2+ ratios (ranging of 0.02–0.07), zircon Ce4+/Ce3+ ratios (median value of 18.70), and oxygen fugacity (near or below the FMQ buffer). The data in this study indicate that the late Mesozoic granitoids in the Dahutang district are favorable for W, Cu (<1 Mt), and Mo (<0.3 Mt) mineralization. Notably, the more evolved Li-mica albite granite has potential for W, Sn, Nb and Ta mineralization. [ABSTRACT FROM AUTHOR]

[Display omitted] • Late Mesozoic granites in eastern Jiangnan Orogen include 154–136 and 136–126 Ma. • Zircon and biotite parameters reveal redox state of Late Mesozoic granitoids. • Early stage granitoids originate from metasedimentary & volcanic–sedimentary rocks. • Late stage granitoids originate from anatexis with various mantle-derived melts. • Magmatic redox states and protoliths controlled the diverse mineralization. Late Mesozoic magmatism is extensively developed in the eastern Jiangnan Orogen and is closely related to W, Mo, Cu, Au, and Sn mineralization. Late Mesozoic granitoids show various petrological and mineralizing features that vary spatially (northern Jiangxi Province and southern Anhui Province) and temporally (early stage: 154 to 136 Ma, late stage: 136 to 126 Ma). In this study, we analyzed zircon trace element data from four Late Mesozoic granitoids. Together with published zircon trace element data and biotite compositions from granitoids in the eastern Jiangnan Orogen and W–Sn, Mo and Cu deposits, we use these data to determine the magmatic redox state of the Late Mesozoic granitoids, which is useful in determining mineralization competency and is instructive during exploration. The results show that early stage granitoids of southern Anhui Province are oxidized, characterized by high zircon Ce4+/Ce3+ (median = 278), Ce/Nd (median = 17.1), and Eu N /Eu N * (median = 0.42) ratios, and high biotite Fe3+/Fe2+ ratios (median = 0.23) and X Mg values (median = 0.48). The late stage granitoids of southern Anhui Province are relatively reduced, showing lower zircon Ce4+/Ce3+ (median = 49.7), Ce/Nd (median = 12.7), and Eu N /Eu N * (median = 0.16) ratios, and lower biotite Fe3+/Fe2+ ratios (median = 0.11) and X Mg values (median = 0.38). The early stage granitoids of northern Jiangxi Province show a somewhat reduced redox state. They have comparatively low zircon Ce4+/Ce3+ (median = 17.28), Ce/Nd (median = 4.50), and Eu N /Eu N * (median = 0.17) ratios, and comparatively low biotite Fe3+/Fe2+ ratios (median = 0.07, N = 160) and X Mg values (median = 0.35). The late stage granitoids of northern Jiangxi Province are strongly reduced, characterized by low zircon Ce4+/Ce3+ (median = 17.03), Ce/Nd (median = 0.72), and Eu N /Eu N * (median = 0.02) ratios, and low biotite Fe3+/Fe2+ ratios (median = 0.06) and X Mg values (median = 0.25). Geochemical and isotopic data reveal that early stage granitoids in northern Jiangxi Province were sourced from Neoproterozoic metasedimentary rocks, whereas those in southern Anhui Province originated from Neoproterozoic volcanic–sedimentary sequences. The late stage granitoids in the eastern Jiangnan Orogen formed under an extensional regime and were generated by anatexis with various mantle inputs. The results suggest that early stage granitoids of southern Anhui Province have the potential for Cu (>1 Mt) and Mo (>0.3 Mt) mineralization, whereas late stage granitoids are related to W, Cu (<1 Mt), and Mo (<0.3 Mt). In northern Jiangxi Province, the highly evolved and relatively reduced early stage granitoids have more potential to form large- to super-large-scale W mineralization, with subordinate Cu (<1 Mt) and Mo (<0.3 Mt) mineralization, whereas the similarly reduced and evolved late stage granitoids are closely associated with large- to super-large-scale Sn and W mineralization, with subordinate Cu (<1 Mt) and Mo (<0.3 Mt) mineralization. Different magmatic redox states and protoliths have controlled diverse mineralization in the eastern Jiangnan Orogen. [ABSTRACT FROM AUTHOR]

Graphical abstract Highlights • The first precise age for carbonate-hosted Pb-Zn ore in Central Tethys is 66.5 Ma. • The age of Irankuh Zn-Pb deposit demonstrates an epigenetic origin. • The Irankuh Zn-Pb deposit occurred during the compressional phase of Zagros Orogen. Abstract The investigation of epigenetic carbonate-hosted Pb-Zn deposits from China and Europe in the Eastern and Western orogens of the Tethyan Domain, have provided a new perspective on the range of processes operating in this deposit class globally. However, improved metallogenic models require new constraints on the timing of mineralization throughout the Domain. To address this need, we applied Re-Os pyrite dating to the world class Irankuh Zn-Pb deposit, Iran. The Irankah deposit is located in the thrust belt of the Malayer-Esfahan Pb-Zn Metallogenic Belt (MEMB) in the Zagros Orogen, Iran. Mineralization is hosted by the Goushfil Main Fault and adjacent dolomitized limestones. The hydrothermal mineral assemblage comprises sphalerite, galena, pyrite, minor chalcopyrite and sulfosalt minerals, together with dolomite, barite and abundant quartz. Pyrite associated with main-stage sphalerite mineralization has low concentrations of 3 to 37 ng/g Re and 6 to 49 pg/g Os that are typical of low-level highly radiogenic (LLHR) sulfides. Nonetheless, vein and replacement pyrites from the Goushfil orebody yielded a 5-point isochron age of 66.5 ± 1.6 Ma that is interpreted as the main Zn-Pb mineralization age. The new mineralization age confirms an epigenetic origin for the Irankuh Zn-Pb deposit and supports an early onset for compressional deformation in the Zagros Orogen. The geochronological data support textural evidence that mineralization in veins occurred during regional compression in an active tectonic environment. Therefore the possibility that magmatic fluids and/or heat contributed to the mineralizing system should be incorporated into regional exploration models. Further work is required to test the extent to which epigenetic carbonate-hosted Pb-Zn deposits in the thrust and fold belt settings of the Central and Eastern Tethys differ from those in the Western Tethys and classic Mississippi Valley Type ore deposits. [ABSTRACT FROM AUTHOR]

Mengya’a is a typical Pb–Zn–(Ag) deposit in the Lhasa terrane, which is located in the eastern part of the central Lhasa subterrane, Tibet. Two different types of Pb–Zn–(Ag) mineralization (skarn and porphyry-like styles) have been identified in the Mengya’a mining district. The skarn-type mineralization occurs as layered or lenticular units in the Laigu Formation and contains nearly all the Pb–Zn ore resources, whereas the porphyry-like mineralization exists mainly as veins in granite porphyry. 40 Ar/ 39 Ar dating of muscovite suggests that the skarn orebodies formed at 54.8 ± 0.4 Ma, whereas zircon U–Pb dating of granite porphyry (13.2 ± 0.2 Ma) indicates that the porphyry-like mineralization formed in the Miocene. As such, the primary mineralization event (skarn type) took place during the main Indo-Asia collision. The ore-forming mineralization and alteration characteristics of the Mengya’a deposit are consistent with other examples of regional Pb–Zn–(Ag) mineralization in the Lhasa terrane. The present results, combined with previous studies, indicate that multiple Pb–Zn–(Ag) mineralization events occurred in the Lhasa terrane, including during the Cretaceous, Paleocene, and Miocene, all of which were associated with felsic intrusions. Sulfur and lead isotopes suggest that the Pb–Zn–(Ag) mineralization events were mainly magmatic in origin, and were closely associated with the ancient basement of the central Lhasa subterrane. Whole rock major and trace elements, and zircon Hf isotope data of the ore-forming intrusions indicate that these intrusions are S-type granites, produced mainly by partial melting of the ancient crust, which underwent extensive fractionation. Therefore, the presence of moderately to strongly fractionated S-types granites, along with the ancient crustal magma source, were the key factors in generating the Pb–Zn–(Ag) mineralization in the central Lhasa subterrane. Crustal melting in the central Lhasa subterrane peaked in the Paleocene, and resulted in the most intense Pb–Zn–(Ag) mineralization during the initial stages of Indo-Asia continental collision (65–50 Ma). During the Cretaceous, the scale of crust melting was considerable, creating large Pb–Zn–(Ag) deposits. Limited Miocene crustal melting and magmatism in the central Lhasa subterrane resulted in the Miocene Pb–Zn–(Ag) mineralization being smaller in scale than that in the Paleocene and Cretaceous. [ABSTRACT FROM AUTHOR]

• Indosinian magmatism is widespread in East Tianshan orogenic belt and Altai orogenic belt. • The monazite SIMS U-Th-Pb ages of Jinerquan Li-Be-Nb-Ta range from 246 Ma to 252.9 Ma. • The rare metal mineralization in the East Tianshan orogenic belt shows great potential in Indosinian period. • Intraplating of mantle derived magma induced the upper crustal melting and generation of granitic-pegmatitic magmas. The East Tianshan orogenic belt, a part of the Central Asian Orogenic Belt like Altai orogenic belt, has shown great potential for rare metal mineralization. Jingerquan Li-Be-Nb-Ta deposit is the largest pegmatite deposit in this region. Muscovite granite, quartz monzonite and gabbro have developed in the Jingerquan Li-Be-Nb-Ta pegmatite deposit in the eastern part of East Tianshan orogenic belt. Based on the content of elemental Li and the presence of Li-bearing minerals, we recognize two sets of intrusive assemblages, namely, class I, including muscovite granite and quartz monzonite, which are rich in Li with presence of spodumene and/or lepidolite, and class II mainly gabbro, which are poor in Li and absent of Li-bearing minerals. Class I rocks are rich in Si, Al, Na, K, calc-alkaline to high-K calc-alkaline series, and poor in Ca, P, Fe, and Mg, with A/CNK ≥ 1.1, which are similar to S-type peraluminous granites. Class I rocks are characterized by Rb, Ta, Nb, and Hf enrichments and significant Ti, Ba, and Sr depletions. The chondrite-normalized rare earth element (REE) patterns exhibit significant Eu anomalies (δEu = 0.01–0.20), "tetrad effect," and increased fractionation of rare earth elements with relatively low ΣREE. Class II rocks are calc-alkaline rocks that are rich in Ca, Al, and P and poor in Si, K, with A/CNK < 1; they are characterized by Ba and Sr enrichments and Th, Nb, and Ta depletions. The chondrite-normalized REE patterns exhibit no significant Eu anomalies (δEu = 0.97–1.40) and a smooth curve that slopes to the right. The monazite SIMS U-Th-Pb ages of class I (246–252.9 Ma) and the zircon LA-ICP-MS U-Pb ages of class II (247–250.7 Ma) indicate that both types of intrusions were formed in intraplate environment in Indosinian period. The εHf (t) values (12.0–15.2) and the depleted mantle model ages T DM (279–411 Ma) of class II rocks indicate that the magmas were mainly derived from partial melting of the depleted mantle. In the intraplate extensional setting, the mantle magmas represented by class II basaltic magmas intraplated into the crust and induced partial melting of the middle and upper crust to produce class I S-type granitic magmas. After that, the granitic magmas underwent continuous differential evolution and volatile enrichment, and finally form Li-Be-Nb-Ta mineralized granitic pegmatite. The geological setting, diagenetic and metallogenic chronology, and mineral assemblages of the East Tianshan orogenic belt and the Altai orogenic belt can be compared, and rare metal mineralization of both belts were controlled by the Indosinian tectonic-magmatic event. [ABSTRACT FROM AUTHOR]