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Abstract: Using the carbon nanotube (CNT) arrays embedded in anodic aluminum oxide (AAO) template as an electrode, large amounts of Ni nanoparticles have been encapsulated into the CNTs by an alternating current (AC) electrodepostion technique. As deposited Ni nanoparticles with a typical size of 50–60 nm randomly nucleated on the CNT walls, thus inhomogeneously distributed in the CNTs. After annealing at 600 ∘C, the nanoparticles transformed into quasi-spherical structures with the diameter increasing to 60–80 nm. The quasi-spherical nanoparticles were aligned in orderly rows along the axis of the CNT channels. Magnetic hysteresis measured at 5 K showed that the coercivity was 450 Oe for the as-deposited sample and 385 Oe for annealed sample, with the applied magnetic field parallel with the CNT’s axis. The structures and magnetic properties were discussed for both as-deposited and annealed samples. [Copyright &y& Elsevier]

Supercapacitors (SCs), also called electrochemical capacitors, often show high power density, excellent charge/discharge rates, and long cycle life. The recent development of flexible and wearable electronic devices requires that their power sources be sufficiently compact and flexible to match these electronic components. Therefore, flexible SCs have attracted much attention to power current advanced electronics that can be flexible and wearable. In the past several years, many different strategies have been developed to programmably construct different nanocarbon materials into bendable electrode architectures. Furthermore, flexible SC devices with simplified configurations have also been designed based on these nanocarbon-based architectures. Here, recent developments in the programmable assembly of bendable architectures based on nanocarbon materials are presented. Additionally, the design of flexible nanocarbon-based SC devices with various configurations is highlighted. The progress made recently paves the way for further development of nanocarbon architectures and corresponding flexible SC devices. Future development and prospects in this area are also analyzed. [ABSTRACT FROM AUTHOR]

Asymmetric supercapacitors with high energy density are fabricated using a self-assembled reduced graphene oxide (RGO)/MnO2 (GrMnO2) composite as a positive electrode and a RGO/MoO3 (GrMoO3) composite as a negative electrode in safe aqueous Na2SO4 electrolyte. The operation voltage is maximized by choosing two metal oxides with the largest work function difference. Because of the synergistic effects of highly conductive graphene and highly pseudocapacitive metal oxides, the hybrid nanostructure electrodes exhibit better charge transport and cycling stability. The operation voltage is expanded to 2.0 V in spite of the use of aqueous electrolyte, revealing a high energy density of 42.6 Wh kg−1 at a power density of 276 W kg−1 and a maximum specific capacitance of 307 F g−1, consequently giving rise to an excellent Ragone plot. In addition, the GrMnO2//GrMoO3 supercapacitor exhibits improved capacitance with cycling up to 1000 cycles, which is explained by the development of micropore structures during the repetition of ion transfer. This strategy for the choice of metal oxides provides a promising route for next-generation supercapacitors with high energy and high power densities. [ABSTRACT FROM AUTHOR]

Abstract: We applied X-ray absorption near edge structure (XANES) spectroscopy to investigate the adsorption of amino acids (phenylalanine and glycine) onto single-walled carbon nanotubes (SWCNTs). The adsorption of amino acids has been confirmed by XANES analysis. Moreover, a clear energy shift of the C 1s to πC=O⁎ peak for glycine adsorbed on SWCNTs has been identified and assigned to the interaction between the amino acid and SWCNTs. The experimental data confirm the capability of the XANES spectroscopy as a powerful tool to characterize fine structural details at the interface of complex bio-systems. [Copyright &y& Elsevier]

We report angular dependent microphotoluminescence measurements on individual suspended ZnO nanorods attached to sharp metal tips. The luminescence measured along and perpendicular to the axis of the same single nanorod indicates quantitatively that >99% of the near band edge emission can be confined effectively in the nanorods and emitted from the end facets. The radially confined luminescence is dominated by P bands and LO phonon replicas of the free exciton emission and P bands. The measurements along the length of the nanorods show that the confinement is evidently influenced by the surface structure. [ABSTRACT FROM AUTHOR]

Small zinc oxide tripodlike arms were assembled at the end of nanowires through thermal evaporation of zinc powder in a horizontal tube furnace. These arms are hundreds of nanometers in length, and they are tens of nanometers in diameter, similar to that of the based nanowires. High-resolution transmission electron microscopy investigation exhibits that they are wurtzite structure and have clear twin planes at the junction of the arms and the based nanowires. The growth mechanism, Raman, and photoluminescence properties were discussed. [ABSTRACT FROM AUTHOR]