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Knowledge Organization Systems (KOS) as networks of knowledge have the potential to inform AI operations. This paper explores natural language processing and machine learning in the context of KOS and Helping Interdisciplinary Vocabulary Engineering (HIVE) technology. The paper presents three use cases: HIVE and Historical Knowledge Networks, HIVE for Materials Science (HIVE-4-MAT), and Using HIVE to Enhance and Explore Medical Ontologies. The background section reviews AI foundations, while the use cases provide a frame of reference for discussing current progress and implications of connecting KOS to AI in digital resource collections. [ABSTRACT FROM AUTHOR]