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Since the beginning of the Trace Gas Orbiter (TGO) science operations in April 2018, its instrument "Nadir and Occultation for MArs Discovery" (NOMAD) supplies detailed observations of the IR spectrums of the Martian atmosphere. We developed a procedure that allows us to evaluate the composition and distribution's parameters of the atmospheric Martian aerosols. We use a retrieval program (RCP) in conjunction with a radiative forward model (KOPRA) to evaluate the vertical profile of aerosol extinction from NOMAD measurements. We then apply a model/data fitting strategy of the aerosol extinction. In this first article, we describe the method used to evaluate the parameters representing the Martian aerosol composition and size distribution. MY 34 GDS showed a peak intensity from LS 190° to 210°. During this period, the aerosol content rises multiple scale height, reaching altitudes up to 100 km. The lowermost altitude of aerosol's detection during NOMAD observation rises up to 30 km. Dust aerosols reff were observed to be close to 1 μm and its νeff lower than 0.2. Water ice aerosols reff were observed to be submicron with a νeff lower than 0.2. The vertical aerosol structure can be divided in two parts. The lower layers are represented by higher reff than the upper layers. The change between the lower and upper layers is very steep, taking only few kilometers. The decaying phase of the GDS, LS 210°–260°, shows a decrease in altitude of the aerosol content but no meaningful difference in the observed aerosol's size distribution parameters. Plain Language Summary: Mars' atmosphere is filled with dust and water ice particles carried by the winds. These aerosols affect the way sunlight is distributed in the atmosphere and on the surface, and this directly affects temperature. In addition, approximately every three Martian years, Mars experiences what is known as a "global dust storm." This type of dust storm covers the entire red planet in dust. It affects the temperature and water vapor content of the Martian atmosphere. Determining and assessing aerosol properties, number, size and mass during and after a global dust storm is of crucial importance to understanding its underlying mechanisms. Here, we develop an analysis scheme to study the size, nature, number and distribution of Martian aerosols. Our study confirms that, overall, dust and water ice particles are quite small, close to 1 μm or even smaller, and that a global dust storm affects the intensity of other storms that follow. Key Points: Retrieval of Martian aerosols key properties from NOMAD‐SO data during the MY 34 GDSMesospheric dust and water ice reff are mainly ∼1 μm and ≤0.5 μm respectively during the MY 34 GDS and its decay phaseDuring the MY 34 GDS, the effective variance shows a slight N/S asymmetry and values mainly ≤0.2 [ABSTRACT FROM AUTHOR]

We present CO density profiles up to about 100 km in the Martian atmosphere obtained for the first time from retrievals of solar occultation measurements by the Nadir and Occultation for Mars Discovery (NOMAD) onboard ExoMars Trace Gas Orbiter (TGO). CO is an important trace gas on Mars, as it is controlled by CO2 photolysis, chemical reaction with the OH radicals, and the global dynamics. However, the measurements of CO vertical profiles have been elusive until the arrival of TGO. We show how the NOMAD CO variations describe very well the Mars general circulation. We observe a depletion of CO in the upper troposphere and mesosphere during the peak period, LS = 190°–200°, more pronounced over the northern latitudes, confirming a similar result recently reported by Atmospheric Chemistry Suite onboard TGO. However, in the lower troposphere around 20 km, and at least at high latitudes of the S. hemisphere, NOMAD CO mixing ratios increase over 1,500 ppmv during the GDS (Global Dust Storm) onset. This might be related to the downwelling branch of the Hadley circulation. A subsequent increase in tropospheric CO is observed during the decay phase of the GDS around LS = 210°–250° when the dust loading is still high. This could be associated with a reduction in the amount of OH radicals in the lower atmosphere due to lack of solar insolation. Once the GDS is over, CO steadily decreases globally during the southern summer season. A couple of distinct CO patterns associated with the Summer solstice and equinox circulation are reported and discussed. Plain Language Summary: CO is an extremely interesting trace species in the Martian atmosphere. It has been used for both dynamical and photochemical studies of the atmosphere. But its vertical distribution has not been systematically measured until the arrival of the Exomars Trace Gas Orbiter (TGO). We use observations of the NOMAD (Nadir and Occultation for Mars Discovery) spectrometer onboard TGO to retrieve full profiles of mixing ratios of CO up to 100 km with a good vertical resolution. The retrievals cover two Martian seasons during which a global dust storm event occurred. We have found the behavior of CO during this event to be governed by local chemistry as well as by the long range transport. During the dust storm, CO mixing ratios are depleted all over the globe while over the southern high latitudes, we discover an increase in CO due to transport from low latitudes during the end of the southern winter. The dynamical effect of global transport is found in the vertical distribution of CO during the southern summer. Another important result, where the local chemistry might be at play is the increase of CO in the low altitudes over low and midlatitudes during the decay phase of the GDS. Key Points: Global map of CO profiles from Nadir and Occultation for Mars Discovery solar occultation observations during the first year of Trace Gas Orbiter operations is presented for the first timeDuring the onset of the 2018 global dust storm (GDS), the CO volume mixing ratios (VMRs) are found to be depleted by 28% at 50 km compared to the average CO VMR valuesHigh CO abundance at tropospheric altitudes is observed over NH during decay of the GDS when the atmospheric dust loading is high [ABSTRACT FROM AUTHOR]

We present vertical profiles of temperature and density from solar occultation (SO) observations by the "Nadir and Occultation for Mars Discovery" (NOMAD) spectrometer on board the Trace Gas Orbiter during its first operational year, which covered the second half of Mars Year 34. We used calibrated transmittance spectra in 380 scans, and apply an in‐house pre‐processing to clean data systematics. Temperature and CO2 profiles up to about 90 km, with consistent hydrostatic adjustment, are obtained, after adapting an Earth‐tested retrieval scheme to Mars conditions. Both pre‐processing and retrieval are discussed to illustrate their performance and robustness. Our results reveal the large impact of the MY34 Global Dust Storm (GDS), which warmed the atmosphere at all altitudes. The large GDS aerosols opacity limited the sounding of tropospheric layers. The retrieved temperatures agree well with global climate models (GCM) at tropospheric altitudes, but NOMAD mesospheric temperatures are wavier and globally colder by 10 K in the perihelion season, particularly during the GDS and its decay phase. We observe a warm layer around 80 km during the Southern Spring, especially in the Northern Hemisphere morning terminator, associated to large thermal tides, significantly stronger than in the GCM. Cold mesospheric pockets, close to CO2 condensation temperatures, are more frequently observed than in the GCM. NOMAD CO2 densities show oscillations upon a seasonal trend that track well the latitudinal variations expected. Results uncertainties and suggestions to improve future data re‐analysis are briefly discussed. Plain Language Summary: The detailed variation of temperature and density with altitude is of paramount importance to characterize the atmospheric state and to constrain the chemistry and dynamics as a whole. The Nadir and Occultation for Mars Discovery (NOMAD) instrument on board the Trace Gas Orbiter (TGO) has among its key targets the characterization of the thermal state with unprecedented vertical resolution. This is the target of this work, where we analyzed transmittance spectra obtained from the NOMAD solar occultation channel, with a state‐of‐the‐art retrieval scheme, adapted from Earth to Mars conditions and geometry. We applied it to the first year of TGO observations, which covered the last two Mars seasons of Mars Year 34. The results permit to study the temperature structure up to 90 km and its seasonal and latitudinal variations, revealing the impact of the MY34 Global Dust Storm, a warm layer at mesospheric altitudes not present in climate models, more frequent cold pockets than in current global climate models, and generally, colder temperature at those altitudes, all of which can be of importance for the validation of these climate models. Key Points: Temperature and density profiles up to 90 km are retrieved from Nadir and Occultation for Mars Discovery (NOMAD) first year of solar occultations, covering two seasons of Mars Year 34NOMAD temperatures agree well with climate model predictions below 50 km but are wavier and globally colder by about 10 K at high altitudesWe report large thermal tides producing warm layers at 80 km in the morning terminator. Also strong warming by the 2018 global dust storm [ABSTRACT FROM AUTHOR]