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The BL28XU beamline, dedicated to rechargeable battery analysis, is described., The newly installed BL28XU beamline at SPring-8 is dedicated to in situ structural and electronic analysis of rechargeable batteries. It supports the time range (1 ms to 100 s) and spatial range (1 µm to 1 mm) needed for battery analysis. Electrochemical apparatus for battery charging and discharging are available in experimental hutches and in a preparation room. Battery analysis can be carried out efficiently and effectively using X-ray diffraction, X-ray absorption fine-structure analysis and hard X-ray photoelectron spectroscopy. Here, the design and performance of the beamline are described, and preliminary results are presented.

著者人数: 13名, 資料番号: SA1002759000

We have been developing an X-ray photoelectron tracking imager based on a glass capillary plate (CP) gas detector for cosmic X-ray polarimetry applications. The optical imaging system consists of a CP gas detector filled with a noble-gas mixture and a cooled CCD camera coupled to an optical lens system. The performance of the optical imaging CP gas detector as an X-ray polarimeter was investigated with highly polarized, well-monochromized, and well-collimated X-ray beams at the synchrotron radiation facilities in SPring-8 and KEK-PF. Owing to the fine imaging capability of the optical imaging CP gas detector, images of X-ray photoelectron tracks were clearly observed for the polarized X-rays. A modulation factor of 26% was obtained for a 15 keV polarized X-ray beam, for which the energy resolution was 13%. We report on the properties of the optical imaging CP gas detector as an X-ray polarimeter and describe the outlook on future developments on the basis of the measured characteristics and the results of Monte Carlo simulations.

At the Paul Scherrer Institute PSI an X-ray single photon counting pixel detector (PILATUS) based on the hybrid-pixel detector technology was developed in collaboration with SPring-8. The detection element is a 320 or 450 μm thick silicon sensor forming pixelated pn-diodes with a pitch of 172 μm×172 μm. An array of 2×8 custom CMOS readout chips are indium bump-bonded to the sensor, which leads to 33.5 mm×83.8 mm detective area. Each pixel contains a charge-sensitive amplifier, a single level discriminator and a 20 bit counter. This design realizes a high dynamic range, short readout time of less than 3 ms, a high framing rate of over 200 images per second and an excellent point-spread function. The maximum counting rate achieves more than 2×106 X-rays/s/pixel.

High-quality excitation-energy spectra of Λ 7 Li, Λ 9 Be, Λ 13 C and Λ 16 O as well as Λ 12 C have been obtained with 2 MeV (FWHM) resolution and good statistics through the (π + ,K+) reaction. The spectra of Λ 12 C, Λ 16 0 and Λ 13 C are discussed in relation to the ΛN spindependent interaction, and those of Λ 9 Be and Λ 7 Li within the framework of the cluster structure of Λ hypernuclei. It is emphasized that Λ hypernuclear spectroscopy provides us with valuable information on Λ hypernuclear structure and the ΛN interaction.

An X-ray Raman spectrometer for studies of local structures in minerals is discussed. Contrary to widely adopted back-scattering spectrometers using ≤10 keV X-rays, a spectrometer utilizing ~20 keV X-rays and a bent Laue analyzer is proposed. The 20 keV photons penetrate mineral samples much more deeply than 10 keV photons, so that high intensity is obtained owing to an enhancement of the scattering volume. Furthermore, a bent Laue analyzer provides a wide band-pass and a high reflectivity, leading to a much enhanced integrated intensity. A prototype spectrometer has been constructed and performance tests carried out. The oxygen K-edge in SiO(2) glass and crystal (α-quartz) has been measured with energy resolutions of 4 eV (EXAFS mode) and 1.3 eV (XANES mode). Unlike methods previously adopted, it is proposed to determine the pre-edge curve based on a theoretical Compton profile and a Monte Carlo multiple-scattering simulation before extracting EXAFS features. It is shown that the obtained EXAFS features are reproduced fairly well by a cluster model with a minimal set of fitting parameters. The spectrometer and the data processing proposed here are readily applicable to high-pressure studies.

More than 20 X-ray mirror systems have been constructed in the SPring-8 beamlines since 1997. To simplify the design and reduce the construction, alignment, and maintenance time, the X-ray mirror systems have been standardized as far as possible. An overview of the design, alignment method, and performance of the standard X-ray mirror systems in SPring-8 is given here.

aJASRI, SPring-& Mikazuki, Sayo-gun, Hyougo 679-5198, Japan, bRIKEN, SPring-& Kamigori, Ako-gun, Hyougo 6795198, Japan, CjAERI Kansai, SPring-& Mikazuki, Sayogun, Hyougo 679-5143, Japan, dlnstitute of Scientific and Industrial Reseach, Osaka University, Ibaraki, Osaka 5670047, Japan, eFaculty of Science, Okayama University, Okayama 700, Japan, tDepartment of Molecular Engineering, Kyoto University, Kyoto 606-5801, Japan, gFaculty of Science, Osaka University, Toyonaka, Osaka 560, Japan, "Fundamental Research Laboratry, NEC, Tsukuba, Ibaragi 305, Japan. Emaihurugat@springS.or.jp