1. Magnetic moments of short-lived nuclei with part-per-million accuracy: Towards novel applications of $\beta$-detected NMR in physics, chemistry and biology
- Author
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Harding, R. D., Pallada, S., Croese, J., Antušek, A. A., Baranowski, M., Bissell, M. L., Cerato, L., Dziubinska-Kühn, Gins, W., Gustafsson, F. P., Javaji, A., Jolivet, R. B., Kanellakopoulos, A., Karg, B., Kocman, M. Kempka V., Kozak, M., Kulesz, K., Flores, M. Madurga, Neyens, G., Plavec, R. Pietrzyk J., Pomorski, M., Skrzypczak, A., Wagenknecht, P., Wienholtz, F., Xu, J. Wolak Z., Zakoucky, D., and Kowalska, M.
- Subjects
Physics - Chemical Physics ,Nuclear Experiment - Abstract
We determine for the first time the magnetic dipole moment of a short-lived nucleus with part-per-million (ppm) accuracy. To achieve this two orders of magnitude improvement over previous studies, we implement a number of innovations into our $\beta$-detected Nuclear Magnetic Resonance ($\beta$-NMR) setup at ISOLDE/CERN. Using liquid samples as hosts we obtain narrow, sub-kHz linewidth, resonances, while a simultaneous in-situ $^1$H NMR measurement allows us to calibrate and stabilize the magnetic field to ppm precision, thus eliminating the need for additional $\beta$-NMR reference measurements. Furthermore, we use ab initio calculations of NMR shielding constants to improve the accuracy of the reference magnetic moment, thus removing a large systematic error. We demonstrate the potential of this combined approach with the 1.1 s half-life radioactive nucleus $^{26}$Na, which is relevant for biochemical studies. Our technique can be readily extended to other isotopic chains, providing accurate magnetic moments for many short-lived nuclei. Furthermore, we discuss how our approach can open the path towards a wide range of applications of the ultra-sensitive $\beta$-NMR in physics, chemistry, and biology., Comment: re-submitted
- Published
- 2020
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