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Collective assessment of marine and terrigenous organic biomarkers was performed on a sediment core spanning the last 34,800 years on the upper slope southeast of Brazil to verify the signatures of climatic variations in sea surface temperature (SST), marine productivity, and the flux of terrigenous material in this region. This evaluation is based on marine and terrigenous proxies including alkenones, chlorins, aliphatic hydrocarbons, n-alcohols, and fatty acids. This first report of organic biomarker data for this region confirms a correlation between SST, changes in terrigenous organic matter flow into the ocean, and marine productivity over the last 34.8 ka as a response to the displacement of the Brazil Current. Conditions prevailing during marine isotopic stage (MIS) 3 may be considered intermediate between the last glacial maximum (LGM) and the Late Holocene. For MIS 2, a period of low relative sea level, it was verified that the lowest SSTs were associated with the LGM and higher marine productivity. SST increased by up to 4.4 °C between the LGM and the Holocene. This reveals synchronicity between SST on the southeastern Brazilian upper slope and the North Atlantic Ocean SST records reported in earlier studies. [ABSTRACT FROM AUTHOR]

Abstract: A feature of Pliocene climate is the occurrence of “permanent El Niño-like” or “El Padre” conditions in the Pacific Ocean. From the analysis of sediment cores in the modern northern Benguela upwelling, we show that the mean oceanographic state off Southwest Africa during the warm Pliocene epoch was also analogous to that of a persistent Benguela “El Niño”. At present these events occur when massive southward flows of warm and nutrient-poor waters extend along the coasts of Angola and Namibia, with dramatic effects on regional marine ecosystems and rainfall. We propose that the persistent warmth across the Pliocene in the Benguela upwelling ended synchronously with the narrowing of the Indonesian seaway, and the early intensification of the Northern Hemisphere Glaciations around 3.0–3.5 Ma. The emergence of obliquity-related cycles in the Benguela sea surface temperatures (SST) after 3 Ma highlights the development of strengthened links to high latitude orbital forcing. The subsequent evolution of the Benguela upwelling system was characterized by the progressive intensification of the meridional SST gradients, and the emergence of the 100 ky cycle, until the modern mean conditions were set at the end of the Mid Pleistocene transition, around 0.6 Ma. These findings support the notion that the interplay of changes in the depth of the global thermocline, atmospheric circulation and tectonics preconditioned the climate system for the end of the warm Pliocene epoch and the subsequent intensification of the ice ages. [Copyright &y& Elsevier]

Abstract: The seasonality of sea surface temperatures (SST) estimated from the alkenone- index has been a debated issue since the development of the proxy. Using a compilation of sediment trap time series data from 34 sampling locations, we show that the seasonality of maximum alkenone flux in sediment traps varies markedly across the oceans, depending not only on latitude and light availability but also on local oceanographic conditions. The seasonality of the alkenone flux to sediments may also be shaped by the complexity of sedimentation processes and a consistent, globally applicable, seasonal pattern is not apparent. Nevertheless, values display a world ocean scale correlation with mean annual SSTs (0 m) that closely resembles the standard calibration equation now established for modern surface sediment records. Thus, with a few notable exceptions at oceanographic locations proximate to major hydrographic fronts, it can be concluded that the integrated sedimentation patterns for measured in sediment trap time series provide a measure of annual mean SST. [Copyright &y& Elsevier]

The Arctic has undergone significant changes in the last 20–30 years. The understanding of these changes is limited by the time span or resolution of existing climate records. The main gateway of heat to the Arctic Ocean is the Fram Strait, between Greenland and Svalbard. We have reconstructed past air and sea surface temperatures and relative variations in freshwater extent in a marine core from eastern Fram Strait which spans the last 2000 years. The results show a progressive increase in air temperature and a decrease in the upper mixed water layer temperature, together with an increase in freshwater content during the last 1000 years. Considering the oceanographic features of the eastern Fram Strait, these results suggest that there might have been a progressive increase in the inflow of Atlantic water during the last 1000 years, accompanied by an increase in atmospheric heat transport, causing progressive sea-ice melting and subsequent cooling and freshening of the upper mixed water layer in this area. We suggest that our data show long-scale average changes in the modes of positive and negative Arctic multidecadal variability over the last 2000 years. [ABSTRACT FROM PUBLISHER]

Abstract: The mid-Pleistocene climate transition (MPT) is defined by the emergence of high amplitude, quasi-100ka glacial–interglacial cycles from a prior regime of more subtle 41kacycles. This change in periodicity and amplitude cannot be explained by a change in ‘external’ astronomical forcing. Here, we review and integrate published records of sea-surface temperatures (SSTs) to assess whether a common global expression of the MPT in the surface ocean can be recognized, and examine our findings in light of mechanisms proposed to explain climate system reorganization across the MPT. We show that glacial–interglacial variability in SSTs is superimposed upon a longer-term cooling trend in oceanographic systems spanning the low- to high-latitudes. Regional variability exists in the timing of the onset and magnitude of cooling but, in most cases, a long-term cooling trend begins or intensifies from ~1.2Ma (Marine Isotope Stage, MIS, 35-34). The SST cooling accompanies a long-term trend towards higher global ice volume as recorded in benthic foraminifera δ18O, but predates a step-like increase in δ18O at ~0.9Ma (MIS 24-22) that is argued to reflect expansion of continental ice-sheets. The strongest expression of Pleistocene cooling is found during glacial stages, whereas minor or negligible trends in interglacial temperatures are identified. However, pronounced cooling during both glacial and interglacial maxima is evident at 0.9Ma. Alongside the long-term SST cooling trends, quasi-100kacycles begin to emerge in both the SST and δ18O records at 1.2Ma, and become dominant with the expansion of the ice-sheets at 0.9Ma. We show that the intensified glacial-stage cooling is accompanied by evolving pCO2, abyssal ocean ventilation, atmospheric circulation and/or dust inputs to the Southern Ocean. These changes in diverse environmental parameters suggest that glacial climate boundary conditions evolved across the MPT. In turn, these modified boundary conditions may have altered climate sensitivity to orbital forcing by placing pre-existing ice-sheets closer to some threshold of climate–ice sheet response. [Copyright &y& Elsevier]

The increasing influence of Atlantic Water (AW) in the Barents Sea, a process known as "Atlantification", is gradually decreasing sea ice cover in the region. Ongoing global climate warming is likely to be one of its drivers, but to further understand the role of natural variability and the biogeochemical impacts of the inflow of AW into the western Barents Sea, we reconstructed sea surface temperatures (SSTs) and primary productivity in Storfjordrenna, a climatically sensitive area south of Spitsbergen, between approximately 13,950 cal yr BP and 1300 cal yr BP. The alkenone U 37 K * proxy has been applied to reconstruct SSTs, and the alkenone accumulation rate in marine sediments has been used to infer changes in primary productivity. Our data show that the SST increase was concomitant with the progressive loss of sea ice cover and an increase in primary productivity in the western Barents Sea. We interpret these changes as reflecting the increasing influence of AW in the area as the ice sheets retreated in Svalbard. The transition from the Arctic to the Atlantic domain first occurred after 11,500 cal yr BP, as the Arctic Front moved eastward of the study site but with considerable variability in surface ocean conditions. High SSTs at approximately 6400 cal yr BP may have led to limited winter surface cooling, likely inhibiting convective mixing and the return of nutrients to the euphotic zone and/or enhanced organic matter consumption by zooplankton due to an earlier light signal in the ice-free Storfjordrenna. During the late Holocene (3600-1300 cal yr BP), low insolation facilitated sea ice formation and thus brine production. The former may have launched convective water mixing and increased nutrient resupply to the sea surface, consequently enhancing primary productivity in Storfjordrenna. We propose that, on the basis of the paleoceanographic evidence, the modern increasing inflow of warm AW and the disappearance of pack ice on the Eurasian continental shelf are likely to weaken convective water mixing and decrease primary production in the region. • Postglacial SST and primary productivity in Storfjordrenna were reconstructed. • Meltwater supply limited primary productivity during deglaciation. • Mid-Holocene primary productivity was linked to both inhibited convective mixing and grazing. • Late Holocene decrease in insolation facilitated brine production and nutrient resupply. [ABSTRACT FROM AUTHOR]

The southeast Atlantic Ocean is dominated by two major oceanic systems: the Benguela Upwelling System, one of the world's most productive coastal upwelling cells and the Agulhas Leakage, which is important for transferring warm salty water from the Indian Ocean to the Atlantic Ocean. Here, we present a multi-proxy record of marine sediments from ODP Site 1087. We reconstruct sea surface temperatures ( U 37 K ′ and TEX 86 indices), marine primary productivity (total chlorin and alkenone mass accumulation rates), and terrestrial inputs derived from southern Africa (Ti/Al and Ca/Ti via XRF scanning) to understand the evolution of the Southeast Atlantic Ocean since the late Pliocene. In the late Pliocene and early Pleistocene, ODP Site 1087 was situated within the Benguela Upwelling System, which was displaced southwards relative to present. We recognize a series of events in the proxy records at 3.3, 3.0, 2.2, 1.5, 0.9 and 0.6 Ma, which are interpreted to reflect a combination of changes in the location of major global wind and oceanic systems and local variations in the strength and/or position of the winds, which influence nutrient availability. Although there is a temporary SST cooling observed around the initiation of Northern Hemisphere glaciation (iNHG), proxy records from ODP Site 1087 show no clear climatic transition around 2.7 Ma but instead most of the changes occur before this time. This observation is significant because it has been previously suggested that there should be a change in the location and/or strength of upwelling associated with this climate transition. Rather, the main shifts at ODP Site 1087 occur at ca. 0.9 Ma and 0.6 Ma, associated with the early mid-Pleistocene transition (EMPT), with a clear loss of the previous upwelling-dominated regime. This observation raises the possibility that reorganisation of southeast Atlantic Ocean circulation towards modern conditions was tightly linked to the EMPT, but not to earlier climate transitions. [ABSTRACT FROM AUTHOR]

Assessing the impact of future anthropogenic carbon emissions is currently impeded by uncertainties in our knowledge of equilibrium climate sensitivity to atmospheric carbon dioxide doubling. Previous studies suggest 3 kelvin (K) as the best estimate, 2 to 4.5 K as the 66% probability range, and nonzero probabilities for much higher values, the latter implying a small chance of high-impact climate changes that would be difficult to avoid. Here, combining extensive sea and [and surface temperature reconstructions from the Last Glacial Maximum with climate model simulations, we estimate a lower median (2.3 K) and reduced uncertainty (1.7 to 2.6 K as the 66% probability range, which can be widened using alternate assumptions or data subsets). Assuming that paleoclimatic constraints apply to the future, as predicted by our model, these results imply a lower probability of imminent extreme climatic change than previously thought. [ABSTRACT FROM AUTHOR]