Search

Your search keyword '"D'Angeli, Ferrucio"' showing total 1 results
Start Over Author "D'Angeli, Ferrucio" Topic organic compounds -- synthesis
1 results on '"D'Angeli, Ferrucio"'

1. Stereoselective synthesis of N,N'-diaryl-2,5-dioxopiperazines from homochiral or racemic 2-bromopropananilides

Author

D'Angeli, Ferrucio, Marchetti, Paolo, Rondanin, Riccardo, and Bertolasi, Valerio

Subjects
Organic compounds -- Synthesis, Nitrogen compounds -- Research, Biological sciences, Chemistry
Abstract

The preparation and characterization of N,N'-diaryl-2,5-dioxopiperazines are described. The stereoselective synthesis involves the self-coupling of 2-bromopropananilides. The reaction can be controlled to favor cis-(R,R) or cis-(S,S)/trans-(R,S) isomers by starting either from a single enantiomer or racemate and by the promoter, aryl substituent and solvent. The six diastereomeric couples have been characterized by 1H NMR spectroscopy and X-ray crystallography.

Published
1996

Catalog

Books, media, physical & digital resources
See catalog results