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The Late Cretaceous Marilia Formation located in the central-southern portion of Brazil is characterized by a succession of sandstones, conglomerates, and paleosols. The paleosols constitute more than 60% of this formation, providing significant information about pedogenetic processes as well as paleoenvironmental and paleoclimate implications. The paleosols of the Marilia Formation have been studied principally from a stratigraphical, sedimentological and paleopedological point of view; however, there are no studies addressing in detail the geochemical behavior of the paleosols. Therefore, we used a robust geochemical dataset combined with stratigraphical and macromorphological interpretations as well as clay mineralogy to conduct a paleoenvironmental and paleoclimate analysis of the Marilia Formation in the western portion of the state of Minas Gerais in Brazil. The results indicate that the paleosols of the Marilia Formation can be divided into three pedotypes and pedochemical units based on their geochemical variations and are limited at the base and top by pedochemical markers. Moreover, X-ray diffraction identified quartz and calcite as primary minerals associated with montmorillonite, smectite, illite and palygorskite, indicating wet periods combined with dry stages associated principally with dry and arid environments. The paleosol distribution and weathering index allow us to interpret the paleoenvironmental evolution of the Late Cretaceous Marilia Formation, suggesting an increase in humidity from east to west in the study area.

Rhizoliths are organosedimentary structures produced by plants and are an important proxy for paleoenvironmental reconstructions because the differences in the morphology of rhizoliths and their rooting depths can be used to interpret soil humidity regimes, overall biomass at the soil surface, and the behavior of the water table. With the objective of advancing knowledge on rhizoliths, a study was performed on the macromorphological and micromorphological characterizations of the rhizoliths preserved in the thirty-one paleosols of the Marilia Formation in Minas Gerais, southeastern Brazil. Based on the topological and architectural attributes of rhizoliths, and on their possible functional adaptations, such as mycorrhizal associations, three different types of rhizoliths are described in this study and represent at least three different plants: rhizohaloes, root casts and rhizocretions. Well-developed paleosols with nodular horizons contain the higher density of long root casts, indicating a seasonally dry environment, because the root casts present two meters in length. These adaptations are associated with an exploitation of a lowered water table during most times of the year. The higher density of rhizoliths indicates an area with agglomerated arboreous arbustive vegetation cover. Paleosols with chalky horizons also show a high density of root casts, indicating a landscape with high plant density that is adapted to drained soils, but with a seasonally elevated water table or the influence of ephemeral flows, given the proximity to the flow channels. The poorly drained paleosols with redoximorphic features show the lowest density of rhizoliths, thus indicating an incipient vegetation in response to near-surface water table and waterlogged soils in a distal floodplain. The rhizogenic laminar horizons have developed near fluvial channels with frequent sedimentary input, resulting in a sequence of laminar horizons composed of rhizocretions that are separated by sandy deposits or poorly developed pedogenic horizons. The micromorphological analysis on the rhizogenic laminar calcretes showed biogenic features, such as alveolar septal structures, calcified filaments, microcodium, calcified cells and pisoliths. Despite the scarce paleobotanical findings in the Marilia Formation, the results obtained indicate an ecosystem that was composed of plants varying from herbaceous to arboreous, with an environment similar to modern semiarid shrublands.

This is the first report of trace fossils potentially associated with insect social behavior in sandy and well-drained paleosols of the Upper Cretaceous continental sequence of Brazil. The trace fossils consist of dozens of lobed and vertical structures cemented by CaCO 3 and preserved mainly in full relief in paleosols of the Marilia Formation (Bauru Basin) in the state of Minas Gerais. The described ichnofossils are predominantly vertical, up to 2 m long, and are composed of horizontal lobed structures connected by vertical tunnel-like structures that intersect in the center and at the edges. The lobed structures range from 3 to 15 cm long and 2–6 cm thick. Two different hypotheses are analyzed to explain the origin of the trace fossils; the less probable one is that the structures are laminar calcretes associated with rhizoliths and rhizoconcretions. The hypothesis involving social insects was considered because the trace fossils described herein partially resemble a modern ant nest and the ichnofossil Daimoniobarax. The micromorphological analysis of the lobed and tunnel-like structures indicates modifications of the walls, such as the presence of inorganic fluidized linings, dark linings and oriented grains, supporting the hypothesis that they are chambers and shafts. The architecture and size of the reported nests suggest the possibility that social insect colonies existed during the Maastrichtian and are direct evidence of the social behavior and reproductive strategies of the Cretaceous pedofauna.

The Sanfranciscana basin is a wide intracratonic basin sub-divided in Abaeté sub-basin and Urucuia sub-basin which includes four Groups of Neo Paleozoic to Neo Cretaceous ages, among them there is the target of this study, the Urucuia Group (Upper Cretaceous). The Urucuia Group has the largest rock volume and areal distribution of the basin. Its rocks constitute two Formations, the basal named Posse overlaid by Serra das Araras Formation. In a continental environment where there is a few fossil contents, the paleosol study can bring important information about climatic and geomorphologic conditions, and biological activity being possible to do an environmental reconstruction. Therefore, this project aims to elaborate a paleoenvironmental model to the Upper Cretaceous of the Sanfraciscana basin through facies analysis and paleosol characterization. The fieldwork was accomplished in the outcrops of the Urucuia Group situated near to São Domingo (GO) town. Outcrop descriptions, photographic registration, and sample collection to laboratory analysis were the methodology applied. The outcrop description was made by the identification of lithologies, textures, sedimentary structures, paleocurrents, fossil content, bed geometry, as well as paleosol macromorphologic description.

Paleosols are soils that were formed on an ancient landscape. They may be buried soils and/or soils incorporated into the sedimentary sequences, exhumed soils, or soils developed on ancient relief surfaces (relict soils). Exposed on the surface and influenced by later environmental changes, paleosols reveal ancient environments and contain records regarding the climate, vegetation, landforms, organisms, parent material, time, intensity of pedogenesis, and sedimentation rates in effect during their training. In the Marilia Formation, the paleosols, exhumed and buried, developed on sandstones have argic (Btk, Bt and Bss), hydromorphic (Cg) and calcic (Bk) horizons with different degrees of cementation, forming mainly calcretes. The objective of this study was to characterize the genesis of the paleosols of the Marilia Formation, addressing the dynamics of their formation factors and processes at local and regional levels in order to reconstitute the conditions of environmental evolution of the Maastrichtian of the Bauru Basin. Eleven sections (S1, S2, S3, S4, S5, S6, S7, S8, S9, S10 and S11) of the Marilia Formation were described and collected on nine sample profiles. Micromorphological, mineralogical and geochemical analyses were performed according to the specialized literature. In the Marilia Formation, sedimentation, erosion and pedogenesis are processes that occurred together, concomitantly or subsequently, in view of the fluvial paleoenvironmental dynamics. The paleosols indicate the end of depositional cycles, with differentiated rates, intensities and duration. The paleosols of the Marilia Formation comprise well-drained (Bt-horizon) and poorly drained or hydromorphic (Cg-horizon) pedotypes, of drier conditions (Bkm-horizon) and pedotypes indicative of drier periods alternated with periods of higher humidity (Bss-horizon). The profiles were classified as Luvisols (Bt and Btk horizons), Calcisols (Bk and Ck horizons), Arenosols (C-horizons) and Vertisols (Bss-horizons). Paleosols developed on the flatter and lower portions of the slopes and floodplains and were commonly influenced by the oscillation of the groundwater and the seasonality of the climate. Sandstone with allochthonous and autochthonous carbonate cementation constituted the main parent material of the paleosols. The predominant climate during the Maastrichtian was semi-arid, with seasonality and variations in precipitation patterns and a precipitation-evapotranspiration relationship that provided conditions for the formation of paleosols with Bk, Btk, Bss, Bg and Bt horizons. The time of formation of these diagnostic horizons was dependent on climatic and edaphic factors. However, the time factor lasted until approximately 200,000 years, allowing paleosols to develop with Bt-horizons and prismatic and block structures. Calcification and argilluviation were the formation processes responsible for the genesis and evolution of paleosols during the Maastrichtian of the Bauru Basin. Weathering indexes have shown that paleosols with Bt-horizons are more weathered than are those with Btk and Bk horizons. The paleosols with Bk-horizons reflect periods with more arid conditions in the general context of the semi-arid paleoclimate of the Maastrichtian of the Bauru Basin.

Soils and paleosols reflect the complex interplay between sedimentation, erosion and non-deposition. An analysis of the mineralogical components of paleosols is critical for the reconstitution of the factors, processes and environments in which they were formed. The recognition of mineralogical assemblages can reveal the environmental conditions during pedogenesis and through quantitative analysis it is possible to identify a vertical variation in mineral concentration or leaching over the paleosol profiles, indirectly pointing to environmental processes that dominated during the pedogenetic evolution. The objective of this study is to discuss the significance of mineral phases and to quantify the environmental evolution and degree of development of paleosols of the Marília Formation, Maastrichtian of Bauru Basin. Three sections have been described (A1, A2, A3) in the Marília Formation. The mineralogy was determined by x-ray diffraction, and mineral quantification was obtained through the Rietveld refinement method. The calcretes of the Marília Formation are pedogenic, mostly authigenic minerals. The variation of quartz, calcite, palygorskite and smectite, the micromorphology, and the diversity of subsurface horizons (Bkm, Btkm, Bt) indicate that the studied paleosols did develop in semi-arid conditions, with episodes of higher rainfall rates, humidity, leaching and desilication. RESUMO: Solos e paleossolos refletem complexa inter-relação entre sedimentação, erosão e não-deposição. A análise dos constituintes mineralógicos de paleossolos é fundamental para a reconstituição dos fatores, processos e ambientes no qual esses se formaram. O reconhecimento de determinadas assembléias mineralógicas podem revelar as condições ambientais durante a pedogênese e através da análise quantitativa se torna possível constatar variação vertical ao longo dos perfis de paleossolos, identificando horizontes com maior concentração mineral ou lixiviação, apontando indiretamente processos ambientais que dominavam no decorrer da evolução pedogenética. O objetivo desse trabalho foi discutir o significado das fases minerais e sua quantificação na evolução ambiental e no grau de desenvolvimento dos paleossolos da Formação Marília, Maastrichtiano da Bacia Bauru. Foram descritas três seções (A1, A2, A3) da Formação Marília. A mineralogia foi determinada através da difratometria de raios-x e para a quantificação mineral foi utilizado o método de refinamento Rietveld. Os calcretes da Formação Marília são predominantemente pedogênico, com minerais autigênicos em sua maioria. A variação do teor de quartzo, calcita, paligorskita e esmectita, a micromorfologia e a diversidade de horizontes subsuperficiais (Bkm, Btkm, Bt) demonstraram que os paleossolos se desenvolveram em condições gerais semiáridas, com episódios de maiores taxas de precipitação, umidade, lixiviação e dessilicação.

The application of sequence stratigraphy concepts to continental deposits lacking the referece provided sea level has been a challenge, mainly because the temporal relationships between stratigraphic surfaces and systems tracts depend on the tectonic and climatic evolution of the area. Using the concept of accommodation space (A) and sediment supply (S), we identify specific stacking patterns of aeolian, lacustrine, fluvial and alluvial systems that correspond to the particular tectonic and climatic evolution of the southeastern portion of South America. With the end of the Early Cretaceous volcanism (133 Ma), the southeastern portion of South America underwent tectonic restructuring, which generated basins that encompassed continental sedimentary sequences. The tectonic events responsible for the accumulation of these sequences occurred during two primary phases. The first phase is related to Early Cretaceous thermal subsidence, which was more pronounced in the regions where the thickest Serra Geral Formation basaltic successions are found, resulting in the formation of Bauru Basin. The second phase was related to the Late Cretaceous uplift in southeastern Brazil as a result of magmatic/volcanic activity associated with the Trindade Mantle Plume. Stratigraphic analysis based on well-logs and outcrops and aided by petrographic studies identified three sequences that are bounded by regional unconformities that record important changes in the Bauru Basin's tectonic and paleoenvironmental conditions. The unconformity K-0 is related to the origin of the Bauru Basin in the Early Cretaceous. The Early Cretaceous Sequence 1 (Caiua Group) is interpreted as a second- order sequence, formed by aeolian and fluvial deposits and constituting a Fluvial-Aeolian Systems Tract. Unconformity K-1 that was generated in the Late Cretaceous (Cenomanian – Campanian?) is related to the tectonic evolution of the basin and source area. Overlying Unconformity K-1, lacustrine, fluvial and alluvial deposits display progradational characteristics of the two-third- order sequences: Sequences 2A and 2B, constituted by the Fluvial-Lacustrine and Alluvial Systems Tracts, respectively, and separated by the Unconformity K-1A. Sedimentological characteristics, paleosols and stratigraphic architecture, suggest that A/S ratio was neutral in the late stage of the Sequence 1, whereas in the Sequence 2 there was an increase (Sequence 2A) followed by a decrease in the A/S ratio (Sequence 2B). Aeolian facies and paleosol P1 (Sequence 1), fluvial-lacustrine facies and hydromorphic soils (Sequence 2A), and alluvial facies and Paleosol P2 (Sequence 2B), indicate climatic changes in the South American during the Cretaceous. The stratigraphic framework, subaerial unconformities and paleosols provide key elements for subdividing of the Brazilian continental sequence into third-order sequences and systems tracts, for identification of allocyclic and autocyclic patterns in time and space.

Deduction of associated paleoenvironments and paleoclimate, definition of the chronosequence of paleosols, and paleogeographic reconstruction have become possible through the application of micromorphology in paleopedology. Micromorphology has also been useful in recognition of weathering processes and definition of minerals formed in succession. In this respect, the objective of this study was to identify the development of pedogenic processes and discuss their significance in the paleoclimate evolution of the Marília Formation (Maastrichtian) of Bauru Basin. Three sections of the Marília Formation (A1, A2, and A3) were described, comprising nine profiles. Micromorphologic al analysis was carried out according to the specialized literature. In the Marília Formation, the paleosols developed in sandstones have argillic (Btkm, Bt) and carbonate (Bk) horizons with different degrees of cementation, forming mainly calcretes. The evolution of pedogenic processes, in light of micromorphological analysis, evidenced three moments or stages for the genesis of paleosols with Bkm, Btk, and Bt horizons, respectively. In the Maastrichtian in the Bauru Basin, the paleosols with Bkm are older and more arid environments, and those with Bt were formed in wetter weather, but not enough to lead to the genesis of enaulic-related distributions, typical of current Oxisols.

The influence of post-burial geological processes on preserving pedogenic properties has great importance in identifying ancient paleosols both in the field and in a laboratory. However there are not many publications that focus on characterizing paleosol diagenesis. As temperature and pressure progressively increase, evidence of pedogenesis is modified and destroyed, hindering paleoenvironment characterization and interpretation. This paper discusses diagenetic evidence and its relation to strictly pedogenic features, like structure, cements, nodules, and neoformation of clay minerals using the carbonate paleosols of the Marilia Formation in the upper unit of the Bauru Basin as a case study. Despite the long geotectonic and thermal history of the Marilia Fomation, paleosols bring us pedogenic evidence that can undergo micromorphological analyses, such as cementation, clay illuviation, bioturbation, and ped structures. The results of analyses in 25 paleopedogenic horizons indicate that the paleotopographic features were responsible for distribution of the diagenetic processes and preservation of the paleosol properties. The maturity of those paleosols controls lithification. In mature paleosols that developed in more stable portions of the landscape, characteristics such as carbonate cementation and development of pedogenic structures are the main factors that inhibit diagenesis. However diagenetic processes that influence poorly-developed paleosols are controlled by depositional characteristics and by changes in the water table, enabling more advanced diagenetic processes, compared to mature paleosols.