1. Wide-Range Tuning of the Mo Oxidation State in La1-xSrxFe2/3Mo1/3O3 Perovskites.
- Author
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Istomin, Sergey Ya., Chernova, Varvara V., Antipov, Evgeny V., Lobanov, Maxim V., Bobrikov, Ivan A., Yushankhai, Viktor Yu., Balagurov, Anatoly M., Hsu, K. Y., Lin, J. ‐Y., Chen, J. M., Lee, J. F., Volkova, Olga S., and Vasiliev, Alexander N.
- Subjects
OXIDATION states ,OXIDATION ,PEROVSKITE ,ANTIFERROMAGNETISM ,ANTIFERROMAGNETIC materials - Abstract
La
1- x Srx Fe2/3 Mo1/3 O3 (0 ≤ x ≤ 1) perovskites allow exceptionally wide tuning of the Mo oxidation state from +3 ( x = 0) to +6 ( x = 1) with the FeIII oxidation state virtually unchanged. The end members of this series show antiferromagnetic ordering in LaFe2/3 Mo1/3 O3 at TN = 520 K and ferrimagnetic ordering in SrFe2/3 Mo1/3 O3 at TC = 420 K. The crucial role of electron correlations in the Mo 4d shell suggests that LaFe2/3 Mo1/3 O3 with a half-filled band is a Mott insulator, whereas SrFe2/3 Mo1/3 O3 is a band insulator. In both cases, the magnetic structure is dictated by antiferromagnetic superexchange between localized magnetic moments. At intermediate compositions, an interplay of antiferromagnetic-superexchange and double-exchange interactions results in nonmonotonous variations of both the magnetic-ordering temperature and saturation magnetization. [ABSTRACT FROM AUTHOR]- Published
- 2016
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