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This paper presents a detailed review of shell materials that have the potential to be used for high temperature thermal energy storage (TES) applications, particularly in conjunction with concentrated solar power (CSP) plants. This paper considers shell materials that are thermally stable at more than 300 °C and have successfully been used to encapsulate a phase change material (PCM). The current review does not consider the thermal performance of the shell material and PCM combinations that have been studied. Using these constraints several feasible materials were identified including: steel (carbon and stainless), nickel (and nickel alloy), sodium silicate, silicon dioxide, calcium carbonate and titanium dioxide. These materials have the potential to encapsulate high temperature PCMs and thus provide a suitable method of high temperature TES. [ABSTRACT FROM AUTHOR]

Abstract: This paper presents the results of a thermal performance analysis of a phase change thermal storage unit. The unit consists of several parallel flat slabs of phase change material (PCM) with a liquid heat transfer fluid (HTF) flowing along the passages between the slabs. A validated numerical model developed previously to solve the phase change problem in flat slabs was used. An insight is gained into the melting process by examining the temperatures of the HTF nodes, wall nodes and PCM nodes and the heat transfer rates at four phases during melting. The duration of the melting process is defined based on the level of melting completion. The effects of several parameters on the HTF outlet temperature, heat transfer rate and melting time are evaluated through a parametric study to evaluate the effects of the HTF mass flow rate, HTF inlet temperature, gap between slabs, slab dimensions, PCM initial temperature and thermal conductivity of the container on the thermal performance. The results are used to design a phase change thermal storage unit for a refrigerated truck. [Copyright &y& Elsevier]

The eutectic Na 2 CO 3 -Li 2 CO 3 salt is widely used as an electrolyte in the Molten Carbonate Fuel Cell because of its high both ionic conductivity and operating temperature. The major objective of this study was to investigate the thermal stability of the binary salt as a phase change material for thermal energy storage through thermal decomposition analysis in different environments and thermal cycling. The composition of the binary salt was determined using FactSage software 6.4 and its thermophysical properties were experimentally investigated using a Simultaneous Thermal Analyzer and X-Ray Diffraction. The results show that the eutectic Na 2 CO 3 -Li 2 CO 3 salt has a melting/solidification point of 498.3 ± 0.1 °C/483.9 ± 0.1 °C, with a heat of fusion of 330.8 ± 0.6 J/g and heat of solidification of 329.2 ± 0.3 J/g. The thermal decomposition analysis indicates that the eutectic molten salt has good thermal stability in a CO 2 environment without weight loss at temperatures up to 600 °C. However, 0.8% weight loss is observed at 500 °C in a N 2 atmosphere, which is associated with the thermal decomposition of the eutectic salt to produce corresponding metal oxides and CO 2 . The CO 2 environment could inhibit the thermal decomposition, thus resulting in higher thermal stability of the binary salt in CO 2 than when in N 2 . Hence, an operating environment has a large effect on the thermal stability of the eutectic Na 2 CO 3 -Li 2 CO 3 salt. The eutectic salt exhibits high thermal stability in CO 2 after 500 thermal cycles with little change in its thermal properties compared with the initial sample. [ABSTRACT FROM AUTHOR]

A numerical study has been conducted on a shell and tube latent heat storage system whereby the inlet heat transfer fluid direction is periodically reversed during charging and discharging. The impact of varying the boundary condition at the interface of the tubes carrying the heat transfer fluid and phase change material (PCM) on the evolution of the phase change front, heat transfer area and heat transfer rate have been evaluated during the charging and discharging processes. Results for the charging processes show a higher heat transfer area develops during the early stages and amplification of natural convection after 40% melt fraction, leading to a higher heat transfer rate. In comparison to the fixed flow condition, periodic flow reversal for the discharge cases results in an increased heat transfer area for a longer period of time, leading to a higher heat transfer rate particularly after 75% solidification. This effect is more important for discharging cases in the absence of convection heat transfer. Periodically reversing the direction of heat transfer fluid, which produced a periodic boundary condition at the tube-PCM interface, also resulted in a lower temperature gradient in space and time and consequently higher exergy recovery, and about a 6% increase in the time-average heat transfer rate in the charging and discharging cases. The novel reversal flow method provides a means to implement a periodic boundary condition without changing the heat source/sink, enhancing the thermal performance and cost effectiveness of latent heat storage systems. Phase change storage systems incorporating periodic flow reversal provide higher energy delivery rates, greater power density and more exergy recovery. This method can support fast heat release to respond to a peak load in a CSP plant or fast heat storage to protect a tubular receiver from high thermal stresses. [ABSTRACT FROM AUTHOR]

This paper presents a new TRNSYS model of a refrigeration system incorporating phase change material (PCM) for mobile transport. The PCTSU is charged by an off-vehicle refrigeration unit and the PCM provides cooling when discharging and the cooling released is utilized to cool down the refrigerated space. The advantage of this refrigeration system compared to a conventional system is that it consumes less energy and produces significantly lower greenhouse gas emissions. A refrigeration system for a typical refrigerated van is modelled and simulations are performed with climatic data from four different locations. The main components of the TRNSYS model are Type 88 (cooling load estimation) and Type 300 (new PCTSU component), accompanied by other additional components. The results show that in order to maintain the temperature of the products at −18 °C for 10 h, a total of 250 kg and 390 kg of PCM are required for no door opening and 20 door openings during the transportation, respectively. In addition, a parametric study is carried out to evaluate the effects of location, size of the refrigerated space, number of door openings and melting temperature of the PCM on the thermal performance. [ABSTRACT FROM AUTHOR]

This paper investigates the dynamic thermal behavior of phase change material (PCM) melting in a rectangular enclosure at various inclination angles. Lauric acid as a PCM with high Prandtl number (Pr ≈100) is used. The enclosure is heated isothermally from one side while the other walls are thermally insulated. Experiments were performed with hot wall temperatures of 55, 60 and 70°C for different inclination angles of 0°, 45° and 90°. Image processing of melt photographs along with recorded temperatures were used to calculate the melt fractions, Nusselt numbers and the local interfacial heat transfer rates at the solid–liquid interface. Qualitative time-dependent natural convection flow structures were deduced indirectly from the instantaneous shape of the solid–liquid interface which were confirmed by quantitative data from temperature measurements. The results reveal that the enclosure inclination has a significant effect on the formation of natural convection currents and consequently on the heat transfer rate and melting time of the PCM. As the inclination angle is decreased from 90° to 0°, the convection currents in the enclosure increases and chaotic flow structures appear. When melting commences in the horizontally inclined enclosure, the solid–liquid interface line becomes wavy which implies the formation of Benard convection cells in the liquid PCM. For the same hot wall temperatures, a decrease in inclination angle leads to a considerable enhancement in energy transport from the hot wall of the enclosure to the PCM. It is found that the heat transfer enhancement ratio for the horizontal enclosure is more than two times higher than that of the vertical enclosure. [ABSTRACT FROM AUTHOR]

One feasible solution to reduce the cost of concentrated solar power is to employ a higher temperature and efficiency supercritical carbon dioxide Brayton power cycle. An alternative heat transfer medium and thermal energy storage (TES) system therefore needs to be explored. This work considered a variety of phase change materials (PCMs) and graphite as the storage media in four indirect shell-and-tube storage configurations, including a 3-PCM and 5-PCM cascade storage, a PCM-graphite-PCM hybrid storage and a single graphite storage. The sizing and design of the TES systems were performed by using a dynamic cycling methodology based on a transient 2D numerical model. The cost of those designs were then determined by using an economic model developed inhouse. This work also investigates the impact of some geometric parameters and cost assumptions on the techno-economic performance of the TES system. The analysis suggests a scenario exists whereby a low thermal efficiency storage system which therefore utilises less tube or storage material could be more cost-effective. Overall, the cost of hybrid TES is the lowest among all studied systems, at $26.96/kWh t and $21.49/kWh t for charging temperature of 720 °C and 750 °C, respectively, followed by the 5-PCM storage at $28.06/kWh t and $21.82/kWh t , respectively. [Display omitted] [ABSTRACT FROM AUTHOR]

Abstract: Designing a cost-effective phase change thermal storage system involves two challenging aspects: one is to select a suitable storage material and the other is to increase the heat transfer between the storage material and the heat transfer fluid as the performance of the system is limited by the poor thermal conductivity of the latent heat storage material. When used for storing energy in concentrated solar thermal power plants, the solar field operation temperature will determine the PCM melting temperature selection. This paper reviews concentrated solar thermal power plants that are currently operating and under construction. It also reviews phase change materials with melting temperatures above 300°C, which potentially can be used as energy storage media in these plants. In addition, various techniques employed to enhance the thermal performance of high temperature phase change thermal storage systems have been reviewed and discussed. This review aims to provide the necessary information for further research in the development of cost-effective high temperature phase change thermal storage systems. [Copyright &y& Elsevier]

Abstract: An innovative refrigeration system incorporating phase change material (PCM) is proposed to maintain refrigerated trucks at the desired thermal conditions. The advantage of using PCM to maintain low temperatures is that a conventional refrigeration system does not have to be located on-board the vehicle. In addition, the system consumes less energy and produces much lower local greenhouse gas (GHG) emissions. The phase change thermal storage unit (PCTSU) is charged by a refrigeration unit located off the vehicle when stationary. The PCM is discharged and provides cooling when in service. A new PCM with a lower cost than currently available PCMs was developed, suitable for maintaining the refrigerated truck at a temperature of −18°C. The PCM has a melting temperature of −26.7°C and a latent heat of 154.4kJkg−1. A prototype system was constructed and test results proved that the proposed refrigeration system is feasible for mobile transport. An analysis shows that delivery of refrigerated products can be made with a PCM system having a weight comparable to that of an on board conventional refrigeration system with less than half of the energy cost. [Copyright &y& Elsevier]

A shell-and-tube design with different thermal energy storage (TES) media was investigated as a promising TES system for a next generation concentrated solar power (CSP) plant. Sensible TES using graphite, latent TES using phase change materials (PCMs) and a hybrid of both were investigated. A two-dimensional transient heat transfer model was applied to simulate the thermal performance of multiple shell-and-tube TES modules connected in series. Considering the realistic operation of the CSP plant, an intensive numerical investigation was conducted to design and size the storage system. The TES systems studied were categorized as 3-PCM cascade, 5-PCM cascade, PCM-graphite-PCM hybrid and single graphite. All the PCMs considered in this paper have been experimentally proven as potential candidate storage media. It was found that all the TES systems studied, if well designed, can meet the CSP operational requirements. In comparison, single graphite storage is less problematic, but it has the lowest storage density (47.3 kWhr/tonne). By forming a PCM-graphite-PCM sandwich configuration, the energy density was increased to 60.9 kWhr/tonne and the storage effectiveness of this hybrid system is 70.7%, the highest among all the TES systems studied. • A 2D model was validated and verified using experimental and CFD results. • Six designs of sensible, latent and sensible-latent hybrid storage were investigated. • The overall storage effectiveness of the hybrid design is the highest. • The effectiveness of the graphite system is improved by 21.2% in hybrid design. [ABSTRACT FROM AUTHOR]

Abstract In the current study the feasibility of using solar-based renewables coupled with thermal energy storage (TES) to displace gas for heating was explored. To assess the feasibility, a numerical model of an air-based encapsulated phase change (EPCM) storage system was developed, validated, optimised, and economically costed. The optimised air-based EPCM system utilised a high and low melting temperature phase change material (PCM) with a sensible storage filler. It was found that a capsule radius of 10 mm and PCM volume of 13% resulted in the lowest cost of discharged thermal energy of $25.55/kWh when storage effectiveness and pumping power was considered. This system was then coupled to solar data for Adelaide, South Australia, to simulate the performance of a 1 MWt heat load over a year. By solving an hourly system generation and demand profile, it was found that a concentrated solar thermal (CST) and photovoltaic (PV) system coupled with TES was able to economically reduce gas consumption by 45–65% when the price of gas was $30/GJ. By employing near-term cost estimates for CST and PV systems coupled with TES, it was found that gas consumption could be reduced by similar amounts with a gas price of $20/GJ. Highlights • Solar-based renewables coupled with TES is explored to reduce commercial/industrial reliance on gas as a heat source. • A numerical model of an air-based EPCM system is developed, validated, optimised, and economically costed. • A 2-PCM hybrid system was found to produce the desired performance at the lowest cost ($25.55/kWh t). • Both PV and CST systems are able to currently compete with gas as a heat source when the gas price is more than $25/GJ. • Predicted cost reductions coupled with low cost grid electricity show these systems capable of being economic at $15/GJ. [ABSTRACT FROM AUTHOR]

Highlights • Na and Li sulfates solid-solid PCM mixtures are proposed for cascade systems. • The thermal stability, specific heat capacity and latent heat are obtained. • NaLiSO 4 is the most stable material with lower cost. • NaSO 4 shows irreversible phase transition. • A selected mixture of LiSO 4 and NaLiSO 4 shows $50.2 kWh th −1. Abstract In this work, we investigate novel solid–solid phase-change cascade systems based on mixtures of lithium and sodium sulfates. Solid–solid phase-change materials (PCMs) can be coupled with concentrated solar power technologies. They present several advantages over solid–liquid PCMs including lower thermal expansion, lower or no corrosiveness, and no need for encapsulation. In solid–solid PCMs, the energy is stored during crystal structure transitions. Specifically, lithium sulfate undergoes a crystal structure transition (monoclinic to cubic) at 576 °C, which is a suitable temperature for concentrated solar thermal technologies. Due to the high cost of lithium sulfate, we evaluated the potential of mixing lithium with sodium sulfate to create solid–solid cascaded PCM systems to provide higher thermal storage densities. We used differential scanning calorimetry, high-temperature in situ X-ray diffraction and thermogravimetric analysis to evaluate the phase-transition temperature, phase-change enthalpy, specific heat capacity, crystalline phase composition and thermal expansion. The obtained values for heat capacity and enthalpies of phase transitions showed good agreement with available thermodynamic databases. Therefore, further calculations of thermodynamic properties of each mixture in the system were performed for designing cascaded latent thermal energy storage system. From the PCM mixtures studied, NaLiSO 4 shows the greatest stability under ambient conditions. A mixture of 59.17% NaLiSO 4 and 40.83% Li 2 SO 4 allows an optimum charge of both PCMs for power cycles such as supercritical CO 2. Economic assessment revealed that this cascade system has an estimated cost of $50.2 kWh th −1. [ABSTRACT FROM AUTHOR]

Considerable effort has been devoted to the characterization of thermal properties of the different types of materials that can be used as thermal energy storage (TES) media, but scarce literature exists concerning the materials to manufacture the tanks that can be used to contain these storage media. One of the main concerns when selecting the most suitable material for these tanks is its resistance to corrosion due to molten salts that constitute the TES system. Dynamic gravimetric analysis is a newly proposed method for the study of corrosion on metals, which optimizes the standard procedure described by ASTM G1–03. The new technique avoids the direct handling of samples, so more accurate values can be obtained. In this work, the resistance to corrosion of AISI 316 stainless steel samples in contact with commercial grade molten salts of the Li 2 CO 3 -Na 2 CO 3 -K 2 CO 3 system, at 600 °C for different exposure times, has been determined by using this new methodology. The results show that the initial corrosion rate is lower at higher amounts of lithium carbonate present in the molten salts mixture. [ABSTRACT FROM AUTHOR]

The eutectic Na 2 SO 4 -NaCl salt was investigated as a novel high temperature phase change material for solar thermal energy storage due to its low cost and melting point (626.0 °C) interested. The measured melting point and heat of fusion of the eutectic salt are 625.3 °C and 263.3 J/g, which are in agreement with their theoretical values. The eutectic salt shows good thermal stability after 100 melting-freezing thermal cycles in the range of 550–680 °C in air. Three types of the eutectic Na 2 SO 4 -NaCl-ceramic composites have been designed and evaluated to address the salt’ corrosion issues with containment materials. Results show that eutectic Na 2 SO 4 -NaCl/both α-alumina and mullite composites with a mass ratio of salt to ceramics of 1:1 (wt%) have good thermal stability without cracking as well as with weight losses of 0.50% and 0.74% and the decrease of latent heat by 1% and 2% respectively after 20 thermal cycles, where no phase separation and chemical reaction occur. Their measured melting temperature and latent heat are consistent with their theoretical values. Addition of α-alumina and mullite to the eutectic Na 2 SO 4 -NaCl salt can reduce the eutectic Na 2 SO 4 -NaCl salt’ supercooling. In contrast, the sample of the Na 2 SO 4 -NaCl/diatomite composite cracked after the cycles. [ABSTRACT FROM AUTHOR]

The use of paraffin, salts and salt hydrates as phase change materials (PCMs) have been researched extensively and used in a number of commercial applications. However, metals and metal alloys, which possess a high storage density on a volume basis as well as a substantially higher thermal conductivity, has received much less attention. This paper discusses the considerations for the use of metal and metal alloys as phase change materials for high temperature thermal storage applications, as well as summarises the literature on the limited research in this area. Although some pure metals and metal alloys present interesting thermal properties to be used as PCMs in thermal storage systems, there is a lack of understanding on the implications of the metallurgical aspects related to the melting and solidification of these materials under thermal cycling at high temperatures. The main issues to be considered include vapour pressure, undercooling, corrosion, segregation, changes in composition and microstructure, changes in thermal properties and undesired reactions. Further research is needed before these materials can be used as PCMs in thermal energy storage systems in industry. [ABSTRACT FROM AUTHOR]

Thermal energy storage (TES) is a critical component in a concentrated solar power (CSP) plant since it is able to provide dispatchability and increase the capacity factor of the plant. Recently the Brayton power cycle using supercritical carbon dioxide (s-CO 2 ) has attracted considerable attention as it allows a higher thermal to electric power conversion efficiency compared to the conventional Rankine cycle using subcritical steam. However, no commercial TES has yet been developed for integration with a s-CO 2 based plant. One reason is the lack of a suitable storage material. This work explores the use of a eutectic NaCl-Na 2 CO 3 salt as a reliable high temperature phase change material (PCM). The PCM has been thermally cycled up to 1000 times. Its thermo-physical properties have been measured before and after it has been subjected to the thermal cycling and its corrosion behavior has been investigated. This eutectic salt shows good thermal stability without degradation after cycling 1000 times between 600 and 650 °C. The corrosion rate on stainless steel 316 (SS316) increases linearly up to 350 cycles, and thereafter it stabilizes at 70 mg/cm 2 . [ABSTRACT FROM AUTHOR]

The search for optimal phase change materials (PCMs) for latent heat thermal energy storage systems (LHTESS) focuses almost exclusively on the properties of the PCM. This neglects the significant contribution of the cost of the containment vessel on the total cost of the LHTESS. Thus, to accurately assess the thermoeconomic performance of various PCMs, the relationship between the cost of the containment vessel and the properties of the PCM must be understood. This paper presents an analytical method for optimizing the design of tube and shell or tube and fin containment vessels for the least cost, subject to geometric and performance constraints. One of the key performance constraints is the time to charge, whose evaluation typically requires computationally-expensive simulations which are unsuitable for optimization algorithms. To enable efficient optimization, a novel closed-form approximation of the charge time is developed and validated through numerical simulations. Subsequently, the optimization methodology is used to investigate the relationship between the optimal vessel geometry and configuration, fin properties, PCM properties, and cost of two PCMs. For these PCMs, the use of high thermal conductivity fins is shown to dramatically reduce the total cost of the system. The new methodology is an efficient way to compare the thermoeconomic performance of PCMs as latent heat storage solutions, allowing for the accurate assessment of PCMs. [ABSTRACT FROM AUTHOR]

The mechanisms leading to corrosion in stainless steel containments for thermal energy storage through phase change materials, such as carbonates and chlorides, are crucial for understanding the degradation of these steel alloys. A comprehensive study of this area will allow for down-selection of materials suitable for solar thermal energy storage (TES) operation at an elevated temperature range. Samples of stainless steel (SS) 316L were subjected to a cyclic heat environment of 550–750 °C in air and argon headspace environments, in the presence of a carbonate salt phase change material (PCM). A series of complementary microscopy, spectroscopy and diffractometry analytical techniques were applied to the corroded SS316L. Corrosion rate, interface formation and chemical products with respect to thermal cycling are presented with associated degradation mechanism explained and comparisons are made among different gas environments and varied immersion conditions. In the PCM under ambient air conditions, steel surfaces were mainly corroded by the penetration of oxidants from air, such as H 2 O or O 2 , along grain boundaries. SS316L samples demonstrated more severe degradation when exposed to air with a small fraction of PCM vapour present compared to when they were exposed to liquid or solid PCM. Cycling in Ar resulted in less corrosion in samples as opposed to when they were exposed to an air environment. In an Ar environment corrosion is driven via the formation of chromite, while the SS316L showed a less degradation when exposed to Ar with a small fraction of PCM vapour compared to when it was immersed in PCM. The mechanisms for degradation in air and in Ar are common in that the corrosion products of Cr and Ni dissolve in the PCM thus removing any layer that could protect against corrosion. The present study provides insight into corrosion of stainless-steel when exposed to carbonate salts, in air and inert gas environments, and contributes to down-selection of materials for solar thermal energy storage. • SS316L compatibility test for PCM based solar thermal storage at high temperatures. • Determine the migration of elements including Na form the PCM into SS316L. • Identifying the depletion of steel components dissolving into the liquid PCM. • Corrosion mechanism of steels under inert gas in the presence of carbonates. [ABSTRACT FROM AUTHOR]

In the present paper, an experimental study is carried out to evaluate the effect of the dynamic melting concept in a cylindrical shell-and-tube heat exchanger using water as the phase change material (PCM) and a potassium formate/water solution as the heat transfer fluid (HTF). The dynamic melting concept is a new heat transfer enhancement technique which consists of recirculating the liquid PCM during the melting process with a pump and thus increasing the overall heat transfer coefficient as a result of the dominance of the forced convection. The HTF flow rate was kept constant at 1 l/min and four different PCM flow rates of 0, 0.5, 1 and 2 l/min were tested. Results from the experimental analysis showed enhancements up to 65.3% on the melting period, up to 56.4% on the effectiveness, and 66% on the heat transfer rates when the PCM flow rate was twice the HTF flow rate. From these experiments, it can be concluded that dynamic melting is an effective technique for enhancing heat transfer during melting of PCM. [ABSTRACT FROM AUTHOR]

In this work, the eutectic Na 2 CO 3 –NaCl molten salt was investigated as a new high temperature phase change material for solar thermal energy storage. The composition of the eutectic binary salt was determined with the aid of FactSage software and its thermophysical properties were investigated using a Simultaneous Thermal Analyzer (STA) and X-Ray Diffraction (XRD). Inductively coupled plasma analysis has shown that the composition of the as-prepared sample is consistent with the nominal one. The STA results exhibit that the melting point of the eutectic salt is 637.0 °C and its heat of fusion is 283.3 J/g whereas its specific heat is a function of temperature, which all are in agreement with the theoretical values determined by the FactSage software. The thermal stability analysis indicates that the eutectic molten salt has good thermal stability without weight loss in a CO 2 environment at temperatures below 700 °C, compared with 0.51% weight loss in a N 2 atmosphere. The weight loss observed in the latter, is most likely to be due to the salt׳s decomposition at high temperature. The thermophysical properties of the salt such as melting temperature, latent heat of fusion and solidification, varied marginally after 50 and 100 thermal cycle tests. This demonstrates that the eutectic Na 2 CO 3 –NaCl salt is a promising high temperature phase change material when used in a CO 2 environment or encapsulation. [ABSTRACT FROM AUTHOR]

• Critical cell size of a multi-scaled periodic structure has been ascertained. • Lowering porosity or lifting thermal diffusivity lead to a larger critical PPI. • The critical PPI is 5 when SS at 0.75 porosity or Ni at 0.95 porosity. • The occurrence of localised melting has been identified and correlated. The use of metallic periodic structures was considered for melting rate enhancement of a phase change material (PCM) contained in a rectangular enclosure isothermally heated from the side. The critical (optimized) cell size, or pore size, of a periodic structure with fixed porosity, realising the shortest melting time by maximizing the convection and conduction heat transfer rate into the PCM, was studied. Furthermore, the effects of material properties (copper, aluminium, nickel, and stainless steel), enclosure length, wall-melting temperature difference and porosity were numerically investigated. It was observed that increasing porosity and/or reducing thermal conductivity enlarged the critical cell size (i.e. the optimal cell size that minimizes the melting time). The critical PPIs (pores per inch) of copper and aluminium periodic structures for all studied porosities were 10; for nickel, the critical values were 10 PPIs for porosity values of 0.75, 0.8 and 0.85 while it reduces to 5 PPI for the highest porosity considered here being 0.95. Interestingly, showing a different trend, the critical PPI of stainless-steel structures was 5 for the lowest porosity (0.75) and reduced to 3 for higher porosities. The results clearly demonstrated localised melting which was observed in all periodic structures except for the 10 PPI stainless-steel case. Scattered melting islands are observed as opposed to a moving interface when ϕ = (d p / L) α ligament / α PCM > 1. For such cases, localized melting occurs and the PCM is melted at the ligaments away from the heated wall before the melt front reaches those ligaments. [ABSTRACT FROM AUTHOR]

Demand for high temperature storage is on a high rise, particularly with the advancement of circular economy as a solution to reduce global warming effects. Thermal energy storage can be used in concentrated solar power plants, waste heat recovery and conventional power plants to improve the thermal efficiency. Latent thermal energy storage systems using phase change materials are highly thought for such applications due to their high energy density as compared to their sensible heat counterparts. This review, therefore, gives a summary of major factors that need to be assessed before an integration of the latent thermal energy system is undertaken. In addition, challenges faced when constructing and experimenting with the storage systems are mentioned. Finally, an insight on the cost analysis and the general performance metrics of the latent thermal energy storage systems is provided before conclusions are drawn. • High temperature phase change materials for CSP thermal energy storage. • Phase change materials in CSP plants. • Challenges in building LTES systems. • TES sizing and effectiveness. [ABSTRACT FROM AUTHOR]

Highlights: [•] Liquid sodium has a quite high convection heat transfer coefficient. [•] Liquid sodium delivered the highest electrical energy to grid −99.4% relative to the ideal case. [•] Gaseous HTFs achieved 87.9–91.3% of the ideal delivered electricity. [ABSTRACT FROM AUTHOR]

Latent heat thermal energy storage, by using phase change materials (PCMs), is considered as a promising technology that can be integrated into concentrated solar power (CSP) applications to mitigate the load and electricity supply. Multiple PCMs connected in series has attracted considerable research attention as this configuration has the potential to improve the thermal performance compared to single PCM storage. However, this technology has not yet been deployed in commercial CSP plants. One of the major restrictions is the lack of reliable thermophysical property data for high temperature PCMs. This study gives a broad review of the experimentally verified PCMs with melting temperatures from approximately 500 °C–700 °C, applicable to CSP systems. A further twelve PCM candidates, containing low-cost sodium and/or potassium salts, were identified in this study and their thermophysical properties were experimentally evaluated. It was found that nine of the new candidates can be used as PCMs. • Experimentally verified PCMs with melting points of 500 °C–700 °C were reviewed. • 12 potentially low-cost PCM candidates were identified from the literature. • PCMs were experimentally characterised by using the DSC and TGA. • 9 out of 12 candidates are suitable as PCMs. • The measured weight loss by TGA is in proportion to the estimated vapor pressure. [ABSTRACT FROM AUTHOR]

Analysis of stainless steel 316 as a containment material in the presence of a phase change material (PCM) cycled at high temperature was carried out through a combination of X-ray photoelectron spectroscopy and X-ray diffraction methods. In this work, stainless steel tokens were half-immersed in a chloride carbonate-based PCM, which were then thermally cycled in an air or a nitrogen environment up to 500 times, allowing the PCM to repeatedly transform between solid and liquid phases. Spectroscopy and diffraction methods were applied on the tokens, as well as the cycled PCM, to investigate the extent and nature of corrosion in such steel alloys. With varying sputtering conditions, the oxidation state at different depths of token surfaces was quantified. From the outermost corroded layer through to the bulk, this study shows a gradual change in distribution in both Cr and oxidation of Fe, while Cr was specifically found to have depleted and migrated into the PCM. The oxidation and depletion have been found to increase with increasing exposure time to PCM while sigma-phase structure embrittled in the corrosion layer. [Display omitted] • Chemical degradation of thermal cycled SS 316 with PCM was analysed. • X-ray photoelectron spectroscopy methods were applied to analyse corrosion layers. • Chloride carbonate based PCM in air and nitrogen environment was studied. • With varying sputtering conditions, oxidation state of steel was quantified. [ABSTRACT FROM AUTHOR]

The formation and mechanism that drive corrosion in stainless steel as a containment material in the presence of phase change materials is of importance in solar thermal energy storage systems. In our work, half-immersed stainless steel 316 tokens in a carbonate-based phase change material (PCM 638) have been investigated. The samples were thermally cycled in air and Nitrogen environment up to 500 times within a high-temperature range, allowing the PCM to transform between solid and liquid states repeatedly. As a consequence of thermal cycling, severe thickness loss on steel token was observed, indicating a degree of oxidation occurring, which depleted the uncorroded steel. Cross-sectional microstructural analysis was carried out to determine the elemental distribution and structural morphology along the corrosion layers. This study shows that thermal cycling of SS 316 in PCM results in active Ni and Cr migration to the surface, leading to a significant depletion of Cr from steel moving into the PCM. Cr and Fe on the surface are found to oxidise with varying degrees, with respect to the exposure time. The depletion of Cr was found to be higher in SS 316 immersed in PCM, while also increasing with exposure time. [Display omitted] • Degradation of stainless steel as a containment material at high temperature is studied. • Corrosion of steel against PCM at accelerated thermal cycling is explained. • The degree of oxidation in corrosion layers due to reactions with PCM is explained. • Structural morphology along with active Ni and Cr migration of steel is found. • Relationship between elemental depletion and exposure time is explained. [ABSTRACT FROM AUTHOR]

The thermal performance of a latent heat energy storage system utilising tightly fitted, thermally bonded and non-bonded metal inserts as a heat transfer enhancement material has been investigated. Two methods were used for this purpose. Firstly, a numerical study using volume averaging method was performed and secondly, an analytical study using scale analysis to obtain the theoretical prediction of the performance of the phase change material. Both models agreed with the experimental data in the literature. A further numeric-parametric study was performed to determine the effect of increasing the thermal resistance gap on the total melting/solidification time. It was observed that the storage performance (complete charge/discharge) asymptotically decreased as the gap grows in size and that convection was negligible when periodic structures are used. Generally, it can be concluded that having tightly inserted metal inserts in the storage improves the performance by about three times compared to a case with a 1 mm thermal resistance gap. Numerical results show that when a thermally adhesive glue is used to make ligaments touch the inner wall (thus eliminating the gap), an improvement of about 10% of heat transfer enhancement in charge/discharge is realised as compared to the case of a 1 mm thermal resistance gap. • Numerical prediction of the effect of thermal contact resistance in the performance of phase change materials. • Analytical model accurately predicting the performance of enhanced phase change materials is developed. • The study can help in preliminary design before experimentation. [ABSTRACT FROM AUTHOR]

• Critical cell size of a periodic structure with 0.9 porosity has been numerically ascertained for different materials. • Non-brazed scenarios could lead to three times longer melting time, compared to the perfectly brazed case. • The numerically-predicted effective thermal conductivity of the periodic structure agrees well with results available in the literature. To overcome the inherent poor thermal conductivity of most phase change materials (PCM), inserting highly thermally conductive wire nets with periodic structures into them have been proposed. Numerical simulations have been extensively conducted to determine critical cell size and the effect of cell height and interface gap thickness on the heat transfer within the PCM. In addition, predictive correlations of the effective thermal conductivity were put forward. The simulated results indicate that: for structures with the same porosity, the critical cell size gradually decreases as the thermal conductivity of the wire net (ligament material) increases. For the proposed periodic structure embedded in the considered computational domain with 0.90 porosity, the critical pores per inch (PPI) for copper ligaments is approximately 10 PPI, while for stainless steel, it is approximately 3-5 PPI; a shorter cell height with a lower porosity shortens the melting time, therefore, stacking inexpensive metal wire is considered as an interesting alternative to commercially produced metal foams. Moreover, non-brazed scenarios lead to longer melting times, more than three times, compared to a perfectly brazed case. Furthermore, the effective thermal conductivity of the proposed periodic structure has been numerically calculated, which agrees well with some models available in the literature. [ABSTRACT FROM AUTHOR]

• Inverse method used to improve original T-history method equations to determine PCMs latent heat. • The method shown to be suitable method to calculate latent heat of low thermal conductivity bulk PCMs. • New transient modelling is more suitable for calculating latent heat with cooling rates than using original equations. High temperature phase change materials (PCMs) are being proposed as thermal energy storage media in concentrated solar power plants. The thermophysical properties of PCMs, such as the latent heat of fusion/solidification need to be defined to enable system design and evaluate system performance and cost analysis. Several methods have been used to measure the latent heat of fusion/solidification of PCMs including the T-history method. The original assumption of the T-history method is the Biot number should be less than 0.1 where the lumped capacitance method is applicable. However, when the Biot number is more than 0.1 then the original equations are not applicable to estimate the latent heat of PCM. This paper demonstrates how a one-dimensional heat transfer mathematical model can be used by applying an inverse method to overcome the limitation of the lumped capacitance method in the original T-history method to determine the latent heat of PCMs. The mathematical model demonstrates that variation of the temperature distributions inside the samples for the discharge curves. Furthermore, this model shows the errors in the latent heat values if the T-history method is used. It is evident from the discharge curves of low thermal conductivity PCMs that the original simplified equations used for interpreting the T-history test results are not applicable for calculating the latent heat at different ambient temperature. [ABSTRACT FROM AUTHOR]

• The application of foams and fins, both straight and tree-shaped, is examined aiming at accelerate the melting of PCM. • There is an optimal fin number density for a given total fin volume in the storage tank. Moving to non-uniform fin size and un-even fin distribution cannot significantly shorten the melting time. • The fins, if designed properly, can be as efficient as foam while the former is much cheaper. Application of different heat transfer augmentation techniques, including the use of fins or foams, were investigated to enhance the melting rate of a solid phase change material within an annulus where the inner and outer pipes were subjected to constant wall temperature. The carbon fibre fins as well as three commonly-used foams (made of three different materials: nickel, aluminium and copper) were simulated. Firstly, keeping the total fin volume constant, the fin number density effect on the melting rate was investigated. After an optimal fin number density was obtained, three possible strategies (unequal length, uneven intervals and tree-shaped fins) were explored aimed at a more comprehensive understanding of the induced heat transfer enhancement. It was observed that with a fixed fin thickness and volume, the melting time is not a monotonic function of the fin number density and can be optimized. Comparing pure PCM melting, the use of optimized fin number reduced over 60% of melting time, while additional 8% and 4% further time reduction could be achieved by appropriately increasing lengths and decreasing intervals of bottom fins, respectively. The use of tree-like fins resulted in a longer melting time, comparing to that of longitudinal straight fins, which indicates it is not always a good option. Finally, the results, primarily the melting rates, were compared with those obtained through the use of metal foams with different metals. It was observed that the melting time of optimized strategy-1 is rather less than those of Cu and Al foams, and approximately 2200s shorter than that of Ni foams. These results indicate that the fins, if designed properly, can be as efficient as foams. [ABSTRACT FROM AUTHOR]