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In this work, we fabricated an Ag/Bi7O9I3 composite and tested the composite for the photodegradation of Rhodamine B (RhB) dye under UV–vis light irradiation. XRD, FESEM, TEM, UV–visible absorbance, XPS studies, ESR, and electrochemical analysis were used to characterize the synthesized photocatalysts. The synthesized catalyst displayed a maximum degradation efficiency of 98.45% in the 150-min experiment, which is nearly 1.56 times higher than Bi7O9I3. The enhanced photocatalytic activity of Ag/Bi7O9I3 is attributed to the acceleration of charge separation and transfer of charge carriers with the inclusion of Ag. The improvement in photocatalytic efficiency of Ag/Bi7O9I3 can be attributed to Ag deposition, which acts as an electron sink to avoid recombination of photogenerated electrons and holes. Additionally, Ag nanoparticles may show plasmonic resonance producing more electron–hole pairs in Bi7O9I3. Furthermore, a variety of tests were carried out on Ag/Bi7O9I3 in order to clarify how different factors affect the photodegradation efficiency. The medium with pH = 3, catalyst loading = 35 mg, and Rhodamine B concentration = 10 ppm resulted in highest activity. Using a radical scavenging experiment and ESR studies, the effective radicals in promoting dye degradation have been identified, and ·O2− radicals turned out to be the main radicals in promoting photocatalysis. Additionally, the reusability and degradation mechanisms of the enhanced photodegradation on the specified photocatalyst were examined. [ABSTRACT FROM AUTHOR]

In the current study, g-C3N4/Fe-MOF was synthesised and utilised for the elimination of antibiotic contaminants from wastewater. There are two steps followed for the fabrication of g-C3N4/Fe-MOF i.e. pyrolysis and solvothermal method. The proximity of g-C3N4 and Fe-MOF was confirmed by X-ray diffraction, scanning electron microscopy, ultraviolet spectroscopy, electrochemical impedance spectroscopy, photoluminescence spectroscopy, and X-ray photoelectron spectroscopy analysis of as-prepared samples. The developed photocatalyst was tested for tetracycline degradation. Remarkable photocatalytic activity for tetracycline under visible light irradiation is demonstrated by the g-C3N4/Fe-MOF photocatalyst. In comparison to bare g-C3N4 and Fe-MOF, the g-C3N4/Fe-MOF (G4) demonstrates significantly stronger photocatalytic activity. The best degradation efficiency of 87.12% was achieved at optimized reaction conditions with TC concenteration-25 ppm, catalyst dosage-40 mg and pH-5.5. The enhanced photocatalytic activity is because of the direct Z-scheme heterojunction formed between g-C3N4 & Fe-MOF, which allows for easier separation of photoinduced charge. The investigation also represented an analysis of the prevailing active species and potential photocatalytic mechanism. Finally, the study concludes that the optimized nanocomposite, consisting of g-C3N4/Fe-MOF, exhibited significant biocompatibility as seen by the development of barley seeds in the resultant solution after the degradation process. [ABSTRACT FROM AUTHOR]

Tetracycline hydrochloride (TC-HCl) is widely implemented as a wide-ranging antibacterial drug in medical care and animal husbandry, in spite of having negative effects on the environment and human health. Photocatalytic treatment is one of the popular techniques used to treat TC-HCl in wastewater. In this study, we have used CuFe2O4 and CuFe2O4/polyaniline (PANI) nanohybrids as photocatalysts for the degradation of TC-HCl. The metal ferrite and its nanohybrids were synthesized by co-precipitation method. FTIR, UV-Vis, XRD, and SEM-EDX were used to characterize the synthesized nanohybrids. The optical band gaps were estimated to be 2.74 eV for CuFe2O4, 1.72 eV for 1-PANI/CuFe2O4, 1.66 eV for 3-PANI/CuFe2O4, and 1.31 eV for 5-PANI/CuFe2O4. The photocatalytic performance of the nanohybrids appeared superior than pristine CuFe2O4, and maximum photocatalytic degradation was observed to be 86% within 120 min using 5-PANI/CuFe2O4 as the photocatalyst. The degraded fragments were analyzed by LCMS technique, and a tentative mechanism for the degradation of TC-HCl was proposed. [ABSTRACT FROM AUTHOR]

Photocatalysis utilizing titanium dioxide (TiO2) photocatalysts doped with metal/non-metal has shown great potential in degradation of recalcitrant pollutant like Diclofenac sodium (DCLF). DCLF is one of the most detected pharmaceuticals in water matrices. In this study, a straight-forward sol–gel method for synthesis of cerium (Ce)-doped and boron (B)–Ce co-doped TiO2 photocatalysts has been used. By adjusting the ratio of Ce and B in TiO2 in the prepared photocatalysts, the optimum dopants' concentration was selected and the photocatalytic characteristics of the prepared materials were investigated. The prepared photocatalysts were thoroughly characterized using common physiochemical methods, such X-ray diffraction (XRD), scanning electron microscope (SEM), energy-dispersive X-ray (EDX), X-ray photoelectron spectroscopy (XPS), physisorption (BET), and UV–visible diffuse reflectance spectroscopy (DRS), in order to know more about the structure. Structure and elemental mapping analyses proved the presence of Ce and B in the TiO2 containing anatase phase with a tetragonal structure. The optical properties using a UV–Vis DRS showed a reduction in the bandgap upon Ce/B co-doping. The photocatalytic results obtained showed that Ce–B-doped TiO2 outperforms undoped TiO2 and Ce-doped TiO2. [ABSTRACT FROM AUTHOR]

In recent years, nanotechnology has garnered significant attention and recognition due to its multifaceted contributions across diverse disciplines. Nano zinc oxide (ZnO) is a highly promising nano metal oxide that has found application in a wide range of areas, including fire retardancy, wrinkle reduction, and antimicrobial properties, among others. The wet chemical process was employed to synthesise nano zinc oxide, with Zinc nitrate hexahydrate as the precursor. The synthesised nano ZnO powder underwent characterization in order to determine its shape and physical properties. Four analytical techniques were utilised in this study. FTIR analysis was used to identify the functional group, X-Ray Diffraction was employed to determine the crystalline structure, SEMEDX Analysis was utilised to investigate the morphological structure and size of the synthesised nanoparticles as well as to confirm the presence of specific elements, and Transmission Electron Microscopy was employed to determine the size and shape of the synthesised nanoparticles. The synthesised nanoparticles of zinc oxide (ZnO) were employed for the purpose of photodegradation of a solution containing the Carbaryl insecticide. The experiment involved the utilisation of a set concentration of 5 ppm of Carbaryl pesticide. Additionally, a catalyst consisting of 5mg/L of nano ZnO was introduced. The resulting mixture was then subjected to photodegradation through exposure to UV irradiation. The degradation of the pesticide was shown to occur at a rate of 95% within a 60-minute timeframe. The results demonstrate the significant photocatalytic degradation activity exhibited by the nano ZnO particles that were synthesised. [ABSTRACT FROM AUTHOR]

Phenolic chemicals are poisonous and have long-term impacts on humans and animals. Even in low quantities, as carcinogens, they destroy red blood cells and the liver. These biological waste products pollute groundwater. Thus, removing these organic chemicals to meet discharge limits is difficult. Electrochemical oxidation, redox reactions, membrane separation, and photocatalytic degradation help remove phenolic chemicals from water. Recently, phenolic chemicals have been shown to be removed via adsorption and photocatalysis employing carbon materials and clays. Due to their unique chemical and physical properties, nanometric materials are crucial to these processes. These substances' structures, classification, entry points, and reactivity or interaction with other aquatic components have been extensively studied. Phenolic substances can be removed from the water before usage. This has led to the development of water treatment technologies and methods like activated carbon adsorption, solvent extraction, the electro-Fenton method, membrane-based separation method, photocatalysis, and others that have been shown to successfully remove phenolic compounds from water. Activated carbon is the most promising adsorbent for numerous contaminants (dyes, metals, etc.). However, low-cost agricultural materials are typically used to switch to more environmentally friendly ones. This study uses low-cost, eco-friendly adsorbents to remediate biomedical effluents. Pyrolysis of potato peels (waste) from a restaurant produced carbon samples. Absorption–desorption experiments examined pH, temperature, starting drug concentration, contact time, and regeneration ability. [ABSTRACT FROM AUTHOR]

In this work, we report fabrication of a new Zn3V2O8/g-C3N4 Z-scheme nano-heterojunction for superior photodegradation of organo-phosphorous pesticide diazinon under visible light irradiation. The crystal structure, morphology, elemental composition, photo-electrochemical response and band structure of nano-photo-catalysts were investigated using various analytical techniques. The as-synthesized photocatalyst with best optimized ratio Zn3V2O8/40 wt% g-C3N4 (ZC-40) composites led to 95.2% diazinon (DZN) degradation in 60 min exposure and maintaining high structural stability after multiple reuse cycles (10 mg L−1 initial DZN concentration, pH = 6, catalyst dosage 0.35 g L−1 and visible light intensity 180 mW cm−2). Moreover, the experiments were performed under various reaction conditions as pH conditions, co-existing electrolytes, humic acid, tap water, river water and natural solar light. The improved photocatalytic activity of the heterojunction was ascribed to the synergistic effect of Z-scheme mechanism, high visible light absorption, oxygen vacancies, charge separation and metallic redox mediator. The reduced recombination and high charge transfer capacity was confirmed by electrochemical impedance spectroscopy and photoluminescence. The Z-scheme transfer between Zn3V2O8 and g-C3N4 boosted by V5+/V3+ metallic redox mediator retains the strong redox capacity, and diminishes the recombination. LC–MS results confirm the degradation intermediates and a detailed degradation mechanism were also predicted. Superoxide radicals (●O2–) and hydroxyl radicals (HO●) were found as major oxidative species involved in the photocatalytic degradation. The ZC-40 photocatalyst exhibited high degradation of other pesticides as malathion (90.1%), glyphosate (85.4%) and chlorpyrifos (97.4%) in water system under visible light. This work provides new approaches in designing new photocatalytic heterojunctions with high efficiency and structural robustness for utilizing visible light and efficient water treatment based on advanced oxidation technology. [ABSTRACT FROM AUTHOR]

Antibiotic water contamination is a growing environmental problem in the present day. As a result, water treatment is required for its reduction and elimination. Due to their important role in resolving this issue, photocatalysts have drawn a great deal of interest over the past few decades. When non-biodegradable organic matter is present in polluted water, the photo catalytic process, which is both environmentally friendly and an improved oxidation method, can be an effective means of remediation. In this regard, we report the successful synthesis of pure phased rare earth doped ZnO nanoparticles for tetracycline degradation. The prepared catalysts were systematically characterized for structural, optical, and magnetic properties. The optical band gap was tailored by rare earth doping, with redshift for Sm and Dy doped nanoparticles and blueshift for Nd doped ZnO nanoparticles. The analysis of photoluminescence spectra revealed information about the defect chemistry of all synthesised nanoparticles. Magnetic studies revealed that all synthesized diluted magnetic semiconductors exhibit room temperature ferromagnetism and can be employed for spintronic applications. Moreover, Dy doped ZnO nanoparticles were found to exhibit a maximum degradation efficiency of 74.19% for tetracycline (TCN) removal. The synthesized catalysts were also employed for the degradation of Malachite green (MG), and Crystal violet (CV) dyes. The maximum degradation efficiency achieved was 97.18% for MG and 98% for CV for Dy doped ZnO nanoparticles. The degradation mechanism involved has been discussed in view of the reactive species determined from scavenging experiments. [ABSTRACT FROM AUTHOR]

To synergistically enhance the adsorption and photocatalytic performance of Bi2WO6 and Bi2MoO6, using activated biochar (ACB) as substrate, ACB-Bi2WO6 and ACB-Bi2MoO6 composites were facilely prepared by hydrothermal synthesis. Their adsorption–photocatalytic degradation effects on rhodamine B (RhB), tetracycline (TC), and norfloxacin (NOR) were comparatively investigated. Additionally, the effects of environmental factors, wastewater treatment tests, and disinfection were systematically studied, and the enhancement mechanisms and reasons for the degradation differences were highlighted. The results showed that ACB-Bi2WO6 and ACB-Bi2MoO6 were confirmed to form intimately contacted heterojunctions by various advanced characterization techniques. The introduction of ACB narrowed the band-gap energy of Bi2WO6 and Bi2MoO6, and improved the visible light absorption range and specific surface area. The optimal loading ratios of ACB-Bi2WO6 and ACB-Bi2MoO6 were 1:1.06 and 1:0.58, respectively. The removal rate of ACB-Bi2WO6 for high concentrations of RhB (200 mg·L−1), TC and NOR (50 mg·L−1) were 89.15%, 87.27%, and 72.17%, respectively, which were higher than those of ACB-Bi2MoO6 and significantly stronger than those of Bi2WO6 and Bi2MoO6. This was attributed to the more effective inhibition of photogenerated carrier recombination, higher absorbance, and uniform morphology via ACB-Bi2WO6. ·OH and holes were dominant active species in photocatalysis, and the possible photogenerated carrier transfer path is type II heterojunction. Furthermore, ACB-Bi2WO6 possessed good reusability, and the removal of RhB and TC from the actual wastewater exceeded 80.63% and 58.54%, respectively. The sterilization rates of ACB-Bi2WO6 reached 99% and 95% for E. coli and S. aureus within 24 h, respectively. Therefore, ACB-Bi2WO6 was more recommended for environmental applications. [ABSTRACT FROM AUTHOR]

Constructing visible-light-active Z-scheme heterojunctions has proven fruitful in enhancing the photocatalytic activity of photocatalysts for superior water clean-up. Herein, we report the fabrication of a CoFe2O4@Bi2O3/NiO (CBN) Z-scheme nanoheterojunction. The obtained CBN heterojunction was used for visible-light-assisted degradation of ofloxacin (OFL) in water. The OFL degradation efficiency achieved by the CBN heterojunction was 95.2% in 90 min with a rate constant of kapp = 0.03316 min−1, which was about eight times that of NiO and thirty times that of CoFe2O4. The photocatalytic activity of a Bi2O3/NiO Z-scheme heterojunction was greatly enhanced by the visible activity and redox mediator effect of the cobalt ferrite co-catalyst. Higher charge-carrier separation, more visible-light capture, and the Z-scheme mechanism in the Z-scheme system were the important reasons for the high performance of CBN. The scavenging experiments suggested ●O2− as an active species for superior OFL degradation. The possible OFL degradation pathway was predicted based on LC-MS findings of degradation intermediate products. The magnetic nature of the CBN helped in the recovery of the catalyst after reuse for six cycles. This work provides new insights into designing oxide-based heterojunctions with high visible-light activity, magnetic character, and high redox capabilities for potential practical applications in environmental treatment. [ABSTRACT FROM AUTHOR]

Water pollution has been a prevalent issue globally for some time. Some pollutants are released into the water system without treatment, making the water not suitable for consumption. This problem may lead to more grave problems in the future including the destruction of the ecosystem along with the organisms inhabiting it, and illness and diseases endangering human health. Conventional methods have been implemented to remove hazardous pollutants such as dyes, heavy metals, and oil but are incapable of doing so due to economic restraints and the inability to degrade the pollutants, leading to secondary pollution. Photocatalysis is a more recently applied concept and is proven to be able to completely remove and degrade pollutants into simpler organic compounds. Titanium dioxide (TiO2) is a fine example of a photocatalyst owing to its cost-effectiveness and superb efficiency. However, issues such as the high recombination rate of photogenerated electrons along with positive holes while being only limited to UV irradiation need to be addressed. Carbonaceous materials such as graphene oxide (GO) can overcome such issues by reducing the recombination rate and providing a platform for adsorption accompanied by photocatalytic degradation of TiO2. The history and development of the synthesis of GO will be discussed, followed by the methods used for GO/TiO2 synthesis. The hybrid of GO/TiO2 as a photocatalyst has received some attention in the application of wastewater treatment due to its efficiency and it being environmentally benign. This review paper thereby aims to identify the origins of different pollutants followed by the sickness they may potentially inflict. Recent findings, including that GO/TiO2-related nanocomposites can remove pollutants from the water system, and on the photodegradation mechanism for pollutants including aromatic dyes, heavy metal and crude oil, will be briefly discussed in this review. Moreover, several crucial factors that affect the performance of photocatalysis in pollutant removal will be discussed as well. Therefore, this paper presents a critical review of recent achievements in the use of GO/TiO2-related nanocomposites and photocatalysis for removing various pollutants in wastewater treatment. [ABSTRACT FROM AUTHOR]

Herein, we report the designing of a C3N4/BiOI heterostructure that is supported on gum acacia-crosslinked-poly(acrylamide) hydrogel to fabricate a novel nanocomposite hydrogel. The potential application of the obtained nanocomposite hydrogel to remediate crystal violet dye (CVD) in an aqueous solution was explored. The structural and functional analysis of the nanocomposite hydrogel was performed by FTIR (Fourier transform infrared spectroscopy), X-ray diffraction (XRD), transmission electron microscopy (TEM), and scanning electron microscopy (SEM). The different reaction parameters, such as CVD concentration, nanocomposite hydrogel dosage, and working pH, were optimized. The C3N4/BiOI heterostructure of the nanocomposite hydrogel depicts Z-scheme as the potential photocatalytic mechanism for the photodegradation of CVD. The degradation of CVD was also specified in terms of COD and HR-MS analysis was carried to demonstrate the major degradation pathways. [ABSTRACT FROM AUTHOR]

[Display omitted] • AgFeO 2 -Bi 5 O 7 I S-type heterojunctions developed by facile route. • AgFeO 2 -Bi 5 O 7 I exhibit superior 98.2 % norfloxacin degradation in120 min. • Rapid charge transfer and minimum recombination via S-scheme mechanism and oxygen-vacancies. • ●OH and ●O 2 – radicals as major reactive species- ESR findings. • Superior performance in solar light as well in different water matrices. Developing highly efficient heterojunction photocatalysts for high performance antibiotic removal is of immense importance but still remains a challenge. Herein, AgFeO 2 -Bi 5 O 7 I (AF-BI), a promising oxygen vacancies rich binary S-scheme heterojunction photocatalyst was synthseized via co-precipitation and hydrothermal treatment. The spherical AgFeO 2 spheres were uniformly affixed on the nanorods of Bi 5 O 7 I via an intimate contact, as verified through electron microscopy. The photodegradation efficiency of optimized 15 %AgFeO 2 -Bi 5 O 7 I (15AF-BI) for norfloxacin (NFX) was 98.2 % (120 min) with apparent rate constant 0.022 min−1 which was 4 times pure AgFeO 2. In municipal water, removal efficiency reached 90.4 % and a high 76.1 % and 65.2 % total organic carbon removal in 3 h in visible light and solar light respectively was achieved. The coupling of AgFeO 2 and Bi 5 O 7 I triggers electron transfer, forming an internal electric field (leading to a directional charge transfer efficient separation of the photo-induced carriers as confirmed by PL, EIS, TPCR results. The validation of existence of S-scheme mechanism and oxygen vacancies was achieved by in-situ X-ray photoelectron spectroscopy (XPS) and EPR analysis. The free radical scavenging experiments and electron spin resonance (ESR) spectroscopy revealed ●OH and ●O 2 – radicals were the major reactive species involved in the photodegradation process. The heterojunction is magnetic and can be separated under guidance of magnetic field which makes reusability and separation easy. Based on ESR findings, band structure analysis and mass spectrometry NFX degradation route was predicted. This work provides effective potential solution for preparing new magnetic S-scheme heterojunctions for effective antibiotics degradation and further will expand to realm of clean energy storage and conversion. [ABSTRACT FROM AUTHOR]

In pursuit of advancing photocatalysts for superior performance in water treatment and clean energy generation, researchers are increasingly focusing on layered double hydroxides (LDHs) which have garnered significant attention due to their customizable properties, morphologies, distinctive 2D layered structure and flexible options for modifying anions and cations. No review has previously delved specifically into ZnCr and NiCr LDH-based photocatalysts and therefore, this review highlights the recent surge in ZnCr and NiCr-based LDHs as potential photocatalysts for their applications in water purification and renewable energy generation. The structural and fundamental characteristics of layered double hydroxides and especially ZnCr-LDHs and NiCr-LDHs are outlined. Further, the various synthesis techniques for the preparation of ZnCr-LDHs, NiCr-LDHs and their composite and heterostructure materials have been briefly discussed. The applicability of ZnCr-LDH and NiCr-LDH based photocatalysts in tackling significant issues in water treatment and sustainable energy generation is the main emphasis of this review. It focuses on photocatalytic degradation of organic pollutants in wastewater, elucidating the principles and advancements for enhancing the efficiency of these materials. It also explores their role in H 2 production through water splitting, conversion of CO 2 into valuable fuels and NH 3 synthesis from N 2 , shedding light on their potential for clean energy solutions. The insights presented herein offer valuable guidance for researchers working towards sustainable solutions for environmental remediation and renewable energy generation. [Display omitted] • Fundamentals and properties of Layered Double Hydroxides (LDHs). • ZnCr and NiCr LDHs as photocatalysts-Properties and Performance. • Water treatment and clean energy production-Mechanism and issues. • ZnCr and NiCr LDH based water treatment & clean energy production. • The challenges and future development direction for sustainable use are discussed. [ABSTRACT FROM AUTHOR]

[Display omitted] • Overview of fundamentals of Nb 2 O 5 as photocatalyst-structure and properties. • Heterojunction photocatalysts -Z and S scheme- charge transfer routes. • Recent advances in Nb 2 O 5 based heterojunctions for photocatalytic applications. • Strategies for improving the photocatalytic performance Nb 2 O 5 based heterojunctions. Significant advancements in the field of photocatalysis in recent years have highlighted the heterojunctions based on Nb 2 O 5 as a focal point of research. This comprehensive review diligently analyses the progress in Nb 2 O 5 -based heterojunctions for their application in photocatalysis, focusing on synthesis, characteristics and their pivotal role in addressing crucial energy and environmental challenges. The review emphasizes the fundamental principles of photocatalysis in pollutant removal and H 2 generation, elucidating key processes such as light absorption, charge generation and surface reactions. The different types of heterojunctions, their basic principles and role in enhancing the charge separation and overall photocatlytic performance have been discussed. The recent advances in Nb 2 O 5 -based heterojunctions are extensively discussed for the photocatalytic applications such as pollutants removal and H 2 evolution. Furthermore, the review delves into strategies employed to enhance the photocatalytic activity of Nb 2 O 5 -based heterojunctions such as doping, oxygen vacancies modification, morphological engineering and atomic control, as well as loading with support materials. Each strategy is explained, emphasizing its impact on charge separation and overall efficiency. The review concludes by highlighting existing challenges and providing insights into potential future directions that integrates synthetic processes, novel methods for photoelectric characterization, and an in-depth understanding of the local structure of Nb 2 O 5. This review serves as a valuable resource for researchers in the field, offering a comprehensive overview of the state-of-the-art in Nb 2 O 5 -based heterojunctions for advanced photocatalytic applications. [ABSTRACT FROM AUTHOR]

[Display omitted] • Oxygen vacancies fundamentals and importance in photocatalysis. • Oxygen vacancies rich heterojunction-Synthetic strategies. • OVs rich Z-scheme and S-scheme heterojunctions- Photocatalytic mechanism. • Applications for Hydrogen production and water treatment. • The existing challenges and future perspectives. Photocatalytic removal of pollutants and energy production is a green, low cost and environment friendly technology for addressing the mounting pressure of energy crisis and environmental deterioration. Developing efficient photocatalysts is still a big challenge for accelerating the photocatalytic hydrogen production and pollutant degradation especially utilizing solar light. Therefore, constructing oxygen vacancies rich Z-scheme and S-scheme semiconductor heterojunctions emerged as a promising approach to enhance the light harvesting and increasing the redox capability of photocatalysts. This review comprehensively summarises the state of art focus on oxygen vacancy's role in photocatalysts especially in Z-scheme and S-scheme heterojunctions including synthesis process and modifications. In particular, the functions of oxygen vacancy in supporting the main processes in photocatalytic energy production and pollutant removal, such as light absorption, charge separation and conversion are highlighted in this review. The current issues and future prospective in oxygen vacancies rich heterojunctions for efficient photocatalytic removal of pollutant and energy production are also addressed. Finally, a brief discussion on challenges and future prospects is demonstrated. [ABSTRACT FROM AUTHOR]

The population explosion and rapid economic development has led to tremendous increase in the per capita use of fossil fuel energy resulting in major environmental consequences. To tackle these significant energy and environmental concerns, semiconductor photocatalysis is viewed as a promising environmentally friendly and sustainable solution. The photocatalytic hydrogen evolution utilizes solar energy into clean hydrogen energy which makes it green, environmentally friendly and effective technique to meet energy demands. This process requires workable catalysts to reach a significant reaction rate because of their multiple electrons and multiple proton nature. Among various visible light active photocatalytic materials, metal molybdates have been reported as emerging class of materials owing to their outstanding features as stable crystal structure, photo-corrosion inhibition, high redox efficiency, low cost and toxicity and suitable band structure. The present research provides an extensive review of the most recent advances and new insights into the utilization of metal molybdates in photocatalytic clean energy production and environment challenges. This review article summarizes the recent progresses in advanced strategies applied in metal molybdate based photocatalysts to enhance the photocatalytic performance. The advanced strategies are categorized as control over morphology and surface modification, doping of heteroatom, co-catalyst loading, noble metal deposition and construction of heterojunction, which are devoted to photocatalytic H 2 production and CO 2 reduction and to overcome the fast recombination of charge carriers and increasing the light absorption capacity. The fabrication strategies of metal molybdates and based materials are discussed in detail, as well as their usage as catalysts for H 2 evolution and CO 2 reduction have been analysed. Metal molybdates are promising photocatalysts for addressing present environmental issues, and this work paves the way for future photocatalytic research and development, which may assist in the development of highly effective photocatalysts for sustainable energy needs. [Display omitted] • Metal molybdates as photocatalysts-Structure and properties. • Introduced the synthetic routes: Effect on properties and photocatalytic performance. • Discussed strategies to improve the photocatalytic potential of metal molybdates. • Application for superior hydrogen evolution and CO 2 conversion-Recent advances. • Fundamentals and bottlenecks along with future prospects are discussed. [ABSTRACT FROM AUTHOR]

The chitosan based nanohydrogel reinforced nanocomposite was fabricated by facile sol–gel polymerization technique. A chitosan-cl-poly(AA)/ZrPO 4 nanocomposite was discovered as a capable photocatalyst for the elimination of rhodamine dye. The designed chitosan-cl-poly(AA)/ZrPO 4 nanocomposite was examined by various characterization approaches such as Scanning electron microscopy (SEM), X-Ray diffraction (XRD), Fourier-transform infrared spectroscopy (FTIR) and Transmission electron microscopy (TEM). The photocatalytic experiment outcomes revealed that the nanocomposite had good remediation potential as 82% of rhodamine B dye was remediated within 3 h of process. The antimicrobial behavior of nanocomposite was studied against Pseudomonas aeruginosa, Escherichia coli and Staphylococcus aureus bacteria. Cell toxicity of the synthesized chitosan-cl-poly(AA)/ZrPO4 nanocomposite was performed against Vibrio fischeri as model organism. The chitosan-cl-poly(AA)/ZrPO 4 nanocomposite demonstrated the potential antibacterial behavior. [ABSTRACT FROM AUTHOR]

Photocatalysis has established itself as a fascinating topic, giving promise for effective processing of greenhouse gases and contaminants into useful products, in the search for renewable energy sources and atmospheric rehabilitation. This review study provides a thorough examination of S-scheme heterojunction photocatalysts with an emphasis on their uses in the photocatalytic reduction of CO 2 , N 2 fixation and NO x degradation processes. The review explains various environment-related issues, the basic ideas of photocatalysis and heterojunctions, emphasizing the benefits of S-scheme topologies in increasing interfacial transmission of charges and lowering electron-hole recombination. The fundamentals and issues of photocatalytic CO 2 reduction, nitrogen fixation and NO x degradation, outlining the mechanics involved in employing S-scheme heterojunctions have been discussed. The recent advancements of S-scheme photocatalysts for a variety of applications are highlighted in this review. The future prospects of such assemblies are also critically evaluated, highlighting the importance of full use of solar spectrum, wide scale preparation of photocatalysts, maintaining the redox capability and mechanism elucidation to prepare superior S-scheme heterojunctions to resolve the important energy and environmental issues. [Display omitted] • S-scheme heterojunctions as efficient photocatalysts –Fundamentals and advantages. • Mechanisms of photocatalytic CO 2 reduction, N 2 fixation and NO x degradation. • Designing and synthesis of S-scheme heterojunction photocatalysts. • Applications for reducing CO 2 into fuels, fixation of N 2 into NH 3 and degrading NO x. [ABSTRACT FROM AUTHOR]

A binary S-scheme heterojunction photocatalyst, ZIF-67/Ag 3 VO 4 (ZAV), was successfully synthesized using a hydrothermal technique. The optimal ZAV-30 (ZIF-67/30 wt%Ag 3 VO 4) demonstrated excellent performance by degrading 98.5% of Venlafaxine (VEN) within 60 min under visible light. Extensive investigations were carried out regarding the crystal structure, morphology, composition, specific surface area, optical characteristics and electrochemical impedance. The ZAV-30 heterojunction photocatalyst outperformed bare ZIF-67 and Ag 3 VO 4 photocatalysts, primarily due to enhanced photon absorption and improved charge carriers' separation via S-scheme transfer, redox capability and high charge transfer capacity supported by electrochemical experiments and photoluminescence. The S-scheme transfer was validated by in-situ XPS measurements after light exposure. Scavenger experiments indicated that both •OH and •O 2 − played crucial roles as active species in the photocatalytic process. Mass spectrometry (MS) analysis of intermediates facilitated the proposal of a probable photocatalytic degradation pathway for VEN. The photoactivity of the heterojunction was influenced by a range of factors including the pH of the VEN solution, initial VEN concentration, ZAV photocatalyst dosage, and ion effects. Interestingly the ZAV-30 heterojunction exhibited superior performance in lake water, tap water and river water too. Importantly, the ZAV-30 heterojunction exhibited excellent stability and reusability, making it a promising photocatalyst. [Display omitted] • ZIF-67/Ag 3 VO 4 S-scheme heterojunction synthesized by hydrothermal technique. • ZAV-30 demonstrated 98.5% degradation of Venlafaxine within 60 min under visible light. • The S-scheme transfer accelerates charge transfer, separation and strong redox capability. • •OH and •O 2 − as main active species for photocatalytic degradation • High mineralization, reusability and durability. [ABSTRACT FROM AUTHOR]

Gum acacia based nanocomposite ion exchanger has been fabricated using simple sol–gel method. The effect of biopolymer concentration on ion exchange capacity has been studied. The GA/CeMoPO4 nanocomposite ion exchanger has been well characterized using various techniques as FTIR, XRD, SEM and TEM. The GA/CeMoPO4 showed better ion exchange capacity of 1.04 meq/g in comparison to its inorganic counterpart GA/CeMoPO4 (0.65 meq/g). The various physicochemical properties including thermal stability, elution behavior and pH titrations were studied in detail. The photocatalytic nature of GA/CeMoPO4 and CeMoPO4 were investigated using methyl violet as test dye. The GA/CeMoPO4 showed 86% of methyl violet photodegradation in 2 h of illumination. [ABSTRACT FROM AUTHOR]

Graphical abstract Highlights • Ag@BiPO 4 /BiOBr/BiFeO 3 heterojunction prepared by a simple route. • Wide spectrum response- High performance in UV, Vis, NIR and Solar light. • A dual Z-scheme mechanism predicted-SPR effect of Ag. • High degradation of Norfloxacin-Degradation pathway predicted. • Elucidating mechanism for binary, PBF and APBF under UV & visible-Scavenging & ESR. Abstract Metallic Ag deposited BiPO 4 /BiOBr/BiFeO 3 ternary nano-hetero-structures were rationally designed and synthesized by a simple precipitation-wet impregnation-photo deposition method. The plasmonic junction possesses an excellent wide spectrum photo-response and makes best use of BiPO 4 which is otherwise a poor photocatalyst. Ag@BiPO 4 /BiOBr/BiFeO 3 showed superior photocatalytic activity for degradation of norfloxacin (NFN) under visible, ultra-violet, near-infra-red and natural solar light. Especially catalyst APBF-3 (0.3 wt% Ag@BiPO 4 /BiOBr/BiFeO 3) shows 98.1% degradation of NFN (20 mg/L) in 90 min under visible light and 99.1% in less than 45 min under UV exposure. Free radical scavenging experiments and electron spin resonance (ESR) results has been used for explanation of charge transfer, photocatalytic mechanism and role of radicals for binary, ternary and Ag deposited ternary junctions for UV and visible exposure. Metallic Ag in addition to its surface plasmon resonance helps in protection of high conduction band and valence band in the three semiconductors. A dual Z-scheme mechanism has been predicted by comparing with possibilities of double charge and vectorial charge transfer. [ABSTRACT FROM AUTHOR]

Abstract Rational designing of metal-free carbon nitride based photocatalysts can lead to an excellent optical response and a higher photocatalytic activity driven by visible and solar light. This combines green photocatalytic technology with greener materials prepared by facile approaches for environmental remediation. Herein we report utilization of star photocatalyst g-C 3 N 4 (CN) to form highly efficient hetero-assemblies along with acidified g-C 3 N 4 (ACN), polyaniline (PANI), reduced graphene oxide (RGO) and biochar. By use of these organic semiconductors we synthesize g-C 3 N 4 /ACN/RGO@Biochar (GARB), g-C 3 N 4 /PANI/RGO@Biochar (GPRB) and ACN/PANI/RGO@Biochar (APRB) nano-assemblies with different optical response and band edge positions for a better charge flow and reduced recombination of carriers. These synthesized catalysts were used for visible light powered degradation of 2,4-Dichlorophenoxy acetic acid (2,4-D) and ibuprofen (IBN). APRB performs the best and degrades 99.7% and 98.4% of 2,4-D and IBN (20 mg L−1) under Xe lamp exposure in 50 min and retention of high activity in natural sunlight. Optical analysis, photoelectrochemical response and radical quenching studies show both hydroxyl and superoxide radical anions as major reactive species and a Z-scheme photocatalytic mechanism. RGO acts as an electron mediator and protects higher positioned bands of PANI and ACN in APRB for a remarkable photocatalytic activity for a metal free material. The degradation pathway was analyzed by LC-MS analysis and 42% and 40% total organic carbon was removed in 2 h for 2,4-D and IBN degradation respectively. The toxicity of degraded products was analyzed by analyzing viability of human peripheral blood cells with retaining of 99.1% cells. Graphical abstract Image 1 Highlights • Metal free organic semiconductors based nano-assemblies as photocatalysts. • Utilizing g-C 3 N 4 , acidified C 3 N 4 , PANI for designing efficient photocatalyst. • Z-scheme mechanism-high spectral response and charge separation. • Excellent photo-degradation of Ibuprofen and 2,4-D under artificial and solar light. • Complete mineralization and no toxicity on human PBL cells. [ABSTRACT FROM AUTHOR]

• g-C 3 N 4 and MOFs based heterojunctions –synthesis routes and advantages. • Types of g-C 3 N 4 and MOFs heterojunctions were discussed-modification strategies. • g-C 3 N 4 and MOFs based heterojunctions for photocatalytic environmental remediation and energy production. • Conclusion and future research prospects on g-C 3 N 4 and MOFs based on heterojunctions. Photocatalytic technology has emerged as a promising solution for environmental remediation and energy production, and the development of efficient and stable photocatalysts is of great importance. Recent advances in g-C 3 N 4 /Metal Organic Frameworks (MOFs) heterojunctions have shown excellent potential in achieving high-performance photocatalytic environmental remediation and energy production. In this review, we have summarized the recent advances in the design and synthesis of g-C 3 N 4 /MOFs heterojunctions and their application in photocatalytic environmental remediation and energy production. We have discussed the advantages and challenges of g-C 3 N 4 /MOFs heterojunctions, such as enhanced light absorption, increased surface area, and improved electron-hole separation, and their effects on photocatalytic performance. We also highlight the recent research progress in the utilization of g-C 3 N 4 /MOFs heterojunctions for various environmental remediation applications, including the degradation of organic pollutants and the removal of heavy metals, as well as for energy production applications such as hydrogen evolution and CO 2 reduction. Furthermore, we provide an overview of the latest theoretical and experimental investigations into the mechanisms of photocatalysis in g-C 3 N 4 /MOFs heterojunctions, which can help to guide the rational design of high-performance photocatalysts. Our analysis of the literature reveals that g-C 3 N 4 /MOF heterojunctions have demonstrated excellent photocatalytic activity for the degradation of various pollutants, such as methyl orange, rhodamine B, and bisphenol A. For instance, a g-C 3 N 4 /ZIF-8 heterojunction achieved a photocatalytic degradation rate of 99.9% for methyl orange under visible light irradiation within 60 min. Moreover, the g-C 3 N 4 /MOF heterojunctions have also been found to be efficient in water splitting for hydrogen production. For instance, a g-C 3 N 4 /UiO-66 heterojunction achieved a hydrogen production rate of 1260 μmol h−1g−1 under visible light irradiation. The recent data on the advances in g-C 3 N 4 /MOFs heterojunctions demonstrate their enormous potential for practical applications in photocatalytic environmental remediation and energy production. [ABSTRACT FROM AUTHOR]

In the contemporary era marked by pressing environmental and energy challenges, there is a growing imperative to create effective and eco-friendly approaches to combat pollution and promote the generation of clean and green energy. One such strategy that has attracted much interest recently is the photocatalytic generation of green energy and pollutant removal. Numerous photocatalysts have been created to treat water and generate clean energy. Zn-Ti LDH materials are two-dimensional materials that have unique physical and chemical properties, making them promising photocatalysts. Zn-Ti LDHs have a distinctive layered structure that makes them extremely adaptable for photocatalytic applications. This structure also provides large surface areas, customisable compositions, and abundant active sites. However, Zn–Ti LDH has a low solar energy efficiency because it is primarily triggered by ultraviolet light, which makes up around 5% of sunshine. Therefore, this investigation aims to provide a thorough summary of the latest advancements in the modification of the materials based on Zinc-Titanium Layered Double Hydroxides (Zn-Ti LDHs) for a broad spectrum of photocatalytic uses. This study also covers the fabrication methods for Zn-Ti LDHs and the creation of heterojunctions and composites based on Zn-Ti LDHs. Additionally, it delves into the mechanisms underlying the degradation of pollutants and the generation of clean energy. We have highlighted the potential for new prospects, existing challenges, and progress in this context. [Display omitted] • Fabrication and photocatalytic mechanisms of Zn-Ti LDH based materials for environmental solutions. • Latest advancements in heterojunctions and composites utilizing Zn-Ti LDH for applications in photocatalysis. • Various approaches for enhancing the photocatalytic capabilities of Zn-Ti LDH are explored. • The summary, challenges, and future outlook are all addressed. [ABSTRACT FROM AUTHOR]

In this research work we report synthesis of g-C 3 N 4 /FeVO 4 (CI) and g-C 3 N 4 /FeVO 4 /Fe@NH 2 -Biochar (CIB) nano-hetero assemblies for removal of methyl paraben (MeP) and 2-cholrophenol (2-CP) via adsorption, photocatalysis and photo-ozonation. CI and CIB have been characterized by FT-IR, X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), transmission electron microscopy (TEM), scanning electron microscopy (SEM), UV–Vis spectroscopy, photoluminescence (PL), vibrating sample magnetometry (VSM), Brauner-Emmet Teller surface area analyzer (BET). CIB shows good photocatalytic activity owing to higher specific area, nanosheet porous structure, stability, broader solar spectrum response and reduced charge carriers recombination. Fe@NH 2 -biochar facilitates the degradation via high adsorption capability due to reduced recombination, better charge separation, adsorption and acting of biochar as sink of electrons. The CIB photocatalytic system was tested under three experimental conditions for photodegradation of MeP and 2-CP; adsorption followed by photo-degradation (AP); simultaneous adsorption and photocatalysis (SAP); SAP + O 3 . An apparent synergism between adsorption, photocatalysis and photo-ozonation brings out excellent and promising results. 98.4% of MeP and 90.7% of CP degradation was achieved under simultaneous adsorption and photocatalysis in presence of CIB. The results were analyzed in terms of reaction kinetics, adsorption isotherms, scavenger effect, liquid chromatography-mass spectrometry (LC-MS), Total Organic Carbon (TOC) analysis and cytotoxicity analysis of treated water. An efficient TOC removal 74.2 & 73.9% for MeP and 2-CP were respectively achieved under SAP + O 3 +CIB photocatalysis system. Degradation pathways have been proposed for degradation of MeP and CP thorough photo-degradation and photo-ozonation. The cyto-toxicity studies on Human peripheral blood lymphocytes provide a reference for removal of noxious pollutants in real systems. This experimental work paves a way to design tuneable simple junctions for photocatalytic applications by utilizing various experimental protocols. [ABSTRACT FROM AUTHOR]

In this research work we report Gum-ghatti supported ZnSe-WO 3 nano-hetero-assembly for solar powered degradation of endocrine disruptor Bisphenol S (BPA). The photocatalyst was characterized by Scanning electron microscopy (SEM), High resolution transmission electron microscopy (HRTEM), Small area electron diffraction (SAED), X-Ray diffraction (XRD), Fourier transform infra red spectroscopy (FTIR), Photoluminescence (PL), Energy dispersive X-ray (EDX), UV–vis spectrophotometry and Brauner Emmet Teller surface area analyzer (BET). We achieve a Z-scheme photocatalyst (ZnSe-WO 3 ) with a higher charge flow and visible absorption. Gum ghatti acts as a superadsorbent and a sink for charge carriers. The removal of BPA has been studied under three experimental protocols where 99.5% removal was achieved by symbiose of photocatalysis-adsorption-ozonation in just 45 min hetero-assembly has a high surface area, stability and reduced carrier recombination. The results have been analyzed by scavenger effect, mass spectrometry, kinetics and total organic carbon (TOC) analysis. 49.4% of TOC was removed and COD was reduced to 16.7% after 2 h in symbiotic condition. From the band edges and scavenger effect it was inferred that superoxide radical anions are major attacking species. The work paves way for designing of novel photocatalysts with increasing biogenic quotient and higher efficiency. [ABSTRACT FROM AUTHOR]

[Display omitted] • Fundamentals of S-scheme and dual S-scheme have been discussed. • Types of heterojunctions are elaborated with mechanism comparisons. • Recent developments in synthetic methods and different morphology of S-scheme and dual S- schemes. • S-scheme and dual S-scheme for photocatalytic environmental remediation and energy production. • Bottlenecks, conclusion and future prospects discussed. Discovering alternative materials and technologies that provide the meaningful potential to environmental and energy-related challenges in critical to the long-term viability of industrial activity and the evolution of society. Photocatalysts are undeniably important, and scientists are working hard to improve their photocatalytic performance. The high recombination rates of photogenerated electron-hole pairs as well as poor redox capability are addressed via heterojunction modification. In this direction, oxidation type and reduction type photocatalysts based S-scheme heterojunctions are highly promising owing to highly diminished recombination facilitated by internal electric field. This review has focused on the shift from Z-scheme to new revolutionary S-scheme based photocatalytic materials with high performance applications in the field of energy and environment. It can be concluded that controllable built-in electric field intensity and stable interfacial carrier transport process make S-scheme heterostrctures ideal. However their application is mainly limited to powder photocatalysts, don't apply to photo-chemistry and solar cells with external circuit, reaction thermodynamics and dynamics management in S-scheme photocatalysts is not adequate. To some extent, dual S-schemes address to these limitations and further research is to be carried out to fight the bottlenecks. Several perspectives on the future of S-scheme and dual S-scheme heterostructure were also provided based on rigorous review of the reported results. A discussion on the previously reported different types of heterojunctions and S-schemes is presented in this review along with plausible charge transfer mechanisms. The synthetic routes to S-scheme heterojunctions are also provided along with modifications and combinations. The current designing and perspective applications in numerous pollutant degradation, hydrogen production and CO 2 conversion is selectively highlighted. The transition of mechanism elucidation from Z-scheme to S-scheme has been discussed with suitable case studies. However, S-scheme heterojunctions designing and fabrication is still new commercially and so present readiness and bottlenecks have been discussed. Hence it is quite imperative for a future roadmap to be laid to design and develop economically viable high performance S-scheme heterojunctions. [ABSTRACT FROM AUTHOR]

The nanocomposite pectin thorium(IV) tungstomolybdate (Pc/TWM) has been prepared by incorporating pectin biopolymer within thorium(IV) tungstomolybdate, precipitated at 80˚C. The synthesized nanocomposite material was characterized using scanning transmission electron microscopy, transmission electron microscopy, scanning electron microscopy, X-ray diffraction analysis, and Fourier transform infrared spectroscopy. The binary mixture separations of heavy metal ions have been performed proficiently on the columns of Pc/TWM. The synthesized nanocomposite was exploited for removal of malachite green from the aqueous system under two set of conditions. The synergistic/adsorptional photocatalysis conditions were found to be more efficient than equilibrium adsorption followed by photocatalysis in the dark. The Pc/TWM also showed promising antibacterial activity against the bacteria, Staphylococcus aureus. Thus, the nanocomposite material can be used as an adsorbent for the remediation of harmful metals and dye pollutants from wastewater. [ABSTRACT FROM AUTHOR]

A polyaniline Zr(IV) selenotungstophosphate nanocomposite was prepared via sol-gel method and characterized by thermogravimetric analysis, scanning electron microscopy, energy dispersive X-ray spectroscopy, and transmission electron microscopy. The combined sorptional–photocatalytic activity of the nanocomposite for degradation of methylene blue and malachite green was investigated and was found to be more efficient than separate adsorption in the dark followed by photocatalysis. The dyes were degraded in 3 h by 96% and 89% by the combined process, as compared to 86% and 72% by the two-step process in 5 h. The nanocomposite material showed antimicrobial activity againstStaphylococcus aureusandEscherichia coli. [ABSTRACT FROM PUBLISHER]

Extensive research is being done to develop multifunctional advanced new materials for high performance photocatalytic applications in the field of energy production and environmental detoxification, MXenes have emerged as promising materials for enhancing photocatalytic performance owing to their excellent mechanical properties, appropriate Fermi levels, and adjustability of chemical composition. Numerous experimental and theoretical research works implied that the dimensions of MXenes have a significant impact on their performance. For photocatalysis to thrive in the future, we must understand the current state of the art for MXene in different dimensions. Using MXene co-catalysts in widely used in photocatalytic applications such as CO 2 reduction, hydrogen production and organic pollutant oxidation, this study focuses on the most recent developments in MXenes based materials, structural modifications, innovations in reaction and material engineering. It has been reported that using 5 mg of CdS–MoS 2 -MXene researchers were able to generate as high as 9679 μmol/g/h hydrogen under visible light. The MXenes based heterojunction photocatalyst Co 3 O 4 /MXene was utilized to degrade 95% bisphenol A micro-pollutant in just 7 min. Numerous novel materials, their preparations and performances have been discussed. Depending upon the nature of MXene-based materials, the synthesis techniques and photocatalytic mechanism of MXenes as co-catalyst are also summarized. Finally, some final thoughts and prospects for developing highly efficient MXene-based photocatalysts are provided which will indeed motivate researchers to design novel hybrid materials based on MXenes for sustainable solutions to energy and pollution issues. [Display omitted] • MXenes as new interesting class of photocatalysts. • Composites and heterojunctions with 0D, 1D, 2D, 3D MXenes. • Variable and tunable optical band gaps. • Suitable for energy production and pollution mitigation. [ABSTRACT FROM AUTHOR]

Designing and fabrication of smart hybrid multifunctional materials for energy/fuel production and environmental detoxification is indeed of great significance for sustainable development. Herein, we synthesized a new well-structured S-scheme heterostructure Fe@TiO 2 /Boron Carbon nitride (FT/BCN) with high performance tetracycline degradation and selective CO 2 photo-reduction to CH 4. Under visible light irradiation, 96.3% tetracycline was degraded in 60 min using best performing FT30/BCN sample with a high 83.2% total organic carbon removal in 2 h. The tetracycline degradation rate for FT30/BCN composite catalyst was ∼7 times than bare boron carbon nitride (BCN). The impact of reaction parameters as pH, presence of interfering electrolytes, light source and water matrix was also investigated. The FT30/BCN photocatalyst shows dramatic improvement in CO 2 photoreduction as exhibited in 24.7 μmol g−1 h−1 CH 4 and 2.4 μmol g−1 h−1 CO evolutions with optimal 91.1% CH 4 selectivity. Pure BCN shows a poor 39.1% selectivity. Further, effect of alkali activation, CO 2 /H 2 O feed ratio, reducing agent and light source onto CH 4 production and selectivity was also investigated. The CH 4 evolution and selectivity was improved because of enhanced visible light absorption, high adsorption potential, charge carrier separation and high reducing power of photogenerated electrons induced by an effective S-scheme heterojunction between Fe@TiO 2 and boron carbon nitride. An S-scheme (step-scheme) charge transfer mechanism is here operative both during tetracycline removal and CO 2 reduction. The drug degradation route and photocatalytic mechanism for antibiotic removal and CO 2 reduction was also predicted. [Display omitted] • Fe@TiO 2 /Boron carbon nitride heterojunction fabricated by hydrothermal route. • High performance antibiotic removal under visible and solar light. • Photo-induced CO 2 reduction with H 2 O for highly selective CH 4 production. • Efficient S-scheme charge transfer mechanism observed between Fe@TiO 2 and BCN. • Antibiotic degradation and selective CH 4 production detailed mechanism elucidated. [ABSTRACT FROM AUTHOR]

This study explains the effect of adsorption on dye degradation using bovine serum alum and ZnWO4 based nanocomposite (BSA-ZnWO4). The synthesis of BSA-ZnWO4 was performed by a hydrothermalmethod involving the encapsulation of ZnWO4 with BSA. BSA-ZnWO4 was characterized by SEM, TEM, XRD, FTIR, and UV-Vis spectral techniques. The photocatalytic experiments were performed under solar light. The dye removal was investigated under different reaction conditions. The photocatalytic efficiency of solar/BSA-ZnWO4 process was higher compared to solar/ZnWO4, dark/BSA-ZnWO4, solar/BSA, dark/ZnWO4, and solar light systems. The simultaneous adsorption and photodegradation process (A+ P) was the most efficient process due to rapid destruction of adsorbed dyemolecules. BSA-ZnWO4 showed superior degradation efficiency and reusability over ZnWO4 for MB degradation. [ABSTRACT FROM AUTHOR]