1. Rational design of high-quality 2D/3D perovskite heterostructure crystals for record-performance polarization-sensitive photodetection.
- Author
-
Zhang, Xinyuan, Li, Lina, Ji, Chengmin, Liu, Xitao, Li, Qing, Zhang, Kun, Peng, Yu, Hong, Maochun, and Luo, Junhua
- Subjects
PEROVSKITE ,PHOTODETECTORS ,CRYSTALS ,ELECTRIC fields ,OPTICS ,METHYLAMMONIUM ,OPTOELECTRONIC devices - Abstract
Polarization-sensitive photodetection is central to optics applications and has been successfully demonstrated in photodetectors of two-dimensional (2D) materials, such as layered hybrid perovskites; however, achieving high polarization sensitivity in such a photodetector remains extremely challenging. Here, for the first time, we demonstrate a high-performance polarization-sensitive photodetector using single-crystalline 2D/3D perovskite heterostructure, namely, (4-AMP)(MA)
2 Pb3 Br10 /MAPbBr3 (MA = methylammonium; 4-AMP = 4-(aminomethyl)piperidinium), which exhibits ultrahigh polarization sensitivity up to 17.6 under self-driven mode. To our knowledge, such a high polarization selectivity has surpassed all of the reported perovskite-based devices, and is comparable to, or even better than, the traditional inorganic heterostructure-based photodetectors. Further studies reveal that the built-in electric field formed at the junction can spatially separate the photogenerated electrons and holes, reducing their recombination rate and thus enhancing the performance for polarization-sensitive photodetection. This work provides a new source of polarization-sensitive materials and insights into designing novel optoelectronic devices. [ABSTRACT FROM AUTHOR]- Published
- 2021
- Full Text
- View/download PDF