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This study investigates the impact of resonant acoustic powder mixing on the delay time of the W-KClO4-BaCrO4 (WKB) mixture and its potential implications for powder and material synthesis. Through thermal analysis, an inverse linear relationship was found between thermal conductivity and delay time, allowing us to use thermal conductivity as a reliable proxy for the delay time. By comparing the thermal conductivity of WKB mixtures mixed manually and using acoustic powder mixer, we found that acoustic powder mixing resulted in minimal deviations in thermal conductivity, proving more uniform mixing. Furthermore, DSC analysis and Sestak-Berggren modeling demonstrated consistent reaction dynamics with a constant activation energy as the reaction progressed in samples mixed using acoustic waves. These findings underscore the critical role of uniform powder mixing in enhancing the thermodynamic quality of the WKB mixture and emphasize the importance of developing novel methods for powder and material synthesis., Comment: 29 pages, 8 figures

Piezoresponse force microscopy (PFM) has been widely used for nanoscale analysis of piezoelectric properties and ferroelectric domains. Although PFM is useful because of its simple and nondestructive features, PFM measurements can be obscured by non-piezoelectric effects that could affect the PFM signals or lead to ferroelectric-like behaviors in non-ferroelectric materials. Many researches have addressed related technical issues, but they have primarily focused on vertical PFM. Here, we investigate significant discrepancies of lateral PFM signals between the trace and the retrace scans, which are proportional to the scan angle and the cantilever lateral tilting discrepancy. The discrepancies of PFM signals are analyzed based on intrinsic and extrinsic components, including out-of-plane piezoresponse, electrostatic force, and other factors. Our research will contribute to the accurate PFM measurements for visualization of ferroelectric in-plane polarization distributions., Comment: 38 pages, 18 figures

Here, we optimized the annealing temperature of HZO/TiN thin film heterostructure via multiscale analysis of remnant polarization, crystallographic phase, minimum ferroelectric domain size, and average grain size. We found that the remnant polarization was closely related to the relative amount of the orthorhombic phase whereas the minimum domain size was to the relative amount of the monoclinic phase. The minimum domain size was obtained at the annealing temperature of 500$^\cird$C while the optimum remnant polarization and capacitance at the annealing temperature of 600$^\circ$C. We conclude that the minimum domain size is more important than the sheer magnitude of remnant polarization considering the retention and fatigue of switchable polarization in nanoscale ferroelectric devices. Our results are expected to contribute to the development of ultra-low-power logic transistors and next-generation non-volatile memory devices., Comment: 28 pages, 11 figures, 1 table

Artificially induced asymmetric tribological properties of ferroelectrics offer an alternative route to visualize and control ferroelectric domains. Here, we observe the switchable friction and wear behavior of ferroelectrics using a nanoscale scanning probe where down domains having lower friction coefficient than up domains can be used as smart masks as they show slower wear rate than up domains. This asymmetry is enabled by flexoelectrically coupled polarization in the up and down domains under a sufficiently high contact force. Moreover, we determine that this polarization-sensitive tribological asymmetry is universal across ferroelectrics with different chemical composition and crystalline symmetry. Finally, using this switchable tribology and multi-pass patterning with a domain-based dynamic smart mask, we demonstrate three-dimensional nanostructuring exploiting the asymmetric wear rates of up and down domains, which can, furthermore, be scaled up to technologically relevant (mm-cm) size. These findings establish that ferroelectrics are electrically tunable tribological materials at the nanoscale for versatile applications., Comment: 72 pages, 33 figures

We imaged the topography of a silicon grating with atomic force microscopy (AFM) using different scan parameters to probe the effect of pixel pitch on resolution. We found variations in the measured step height and profile of the grating depending on scan parameters, with measured step width decreasing from 1300 to 108 nm and step height increasing from 172 to 184 nm when a pixel pitch in the scan axis decreased from 625 nm to 3.91 nm. In order to resolve the measurement anomaly of step width, we compared these values with step width and height of the same grating measured using scanning electron microscopy (SEM). The values obtained from SEM imaging were 187.3 nm +/- 6.2 nm and 116 nm +/- 10.4 nm, which were in good agreement with AFM data using a 3.91 nm of pixel pitch. We think that we need at least four pixels over the step width to avoid the measurement anomaly induced by the stick-slip or dragging of the tip. Our findings that RMS roughness varied less than 1 nm and converged at the value of 77.6 nm for any pixel pitch suggest that the RMS roughness is relatively insensitive to the pixel pitch., Comment: 11 pages, 3 figures

Here we quantitatively evaluate the early stages of mechanical and morphological changes of polished human enamel surfaces induced by soft drinks using atomic force microscopy. With an increase of the immersion time in soft drinks, we found a significant increase of surface roughness (Ra) and a considerable decrease of elastic modulus (E) of the enamel. The prismatic structure of enamel was clearly observed after a one-hour immersion in Coca-Cola, which shows its strong erosion effect. A high surface roughness of enamel results in a high chance of cavities due to easier bacterial adhesion on rougher surface, while a drastic deterioration of the mechanical properties of the enamel weakens its protection property. Our findings show the variation of enamel surface at the very beginning stage of etching process by acidic drinks, which can also be applicable to the etching mechanism of enamel surface by other sources., Comment: 17 pages, 4 figures, 1 table

Polymer composite electrolytes of Nafion and phosphotungstic acid (PWA) are fabricated and analyzed using electrochemical strain microscopy (ESM) and conductive atomic force microscopy (C-AFM) to visualize hydrophilic ion channels near the surface, which are composed of water and sulfonic acid groups. The results indicate that the fibrillar objects in ESM image, without significant changes in topography, are hydrophilic ion channels and additional ion channels formed by interaction between PWA and sulfonic groups in Nafion. In this study, the buried ion channels lying under the surface are probed as well as the inlet and outlet of the channels on the surface through combined use of ESM and C-AFM. The results further enhance the understanding of ionic conduction in composite polymer electrolytes in various fields., Comment: 13 pages, 3 figures

Multiferroic materials have driven significant research interest due to their promising technological potential. Developing new room-temperature multiferroics and understanding their fundamental properties are important to reveal unanticipated physical phenomena and potential applications. Here, a new room temperature multiferroic nanocomposite comprised of an ordered ferrimagnetic spinel LiFe5O8 (LFO) and a ferroelectric perovskite BiFeO3 (BFO) is presented. We observed that lithium (Li)-doping in BFO favors the formation of LFO spinel as a secondary phase during the synthesis of LixBi1-xFeO3 nanoceramics. Multimodal functional and chemical imaging methods are used to map the relationship between doping-induced phase separation and local ferroic properties in both the BFO-LFO composite ceramics and self-assembled nanocomposite thin films. The energetics of phase separation in Li doped BFO and the formation of BFO-LFO composites is supported by first principles calculations. These findings shed light on Li-ion role in the formation of a functionally important room temperature multiferroic and open a new approach in the synthesis of light element doped nanocomposites.