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Municipal solid waste (MSW) leachate contains various refractory pollutants that pose potential threats to both surface water and groundwater. This paper established a novel catalytic oxidation process for leachate treatment, in which OH is generated in situ by pumping both H 2 and O 2 in the presence of Pd catalyst and Fe 2+ . Volatile fatty acids in the leachate were removed almost completely by aeration and/or mechanical mixing. In this approach, a maximum COD removal of 56.7% can be achieved after 4 h when 200 mg/L Fe 2+ and 1250 mg/L Pd/Al 2 O 3 (pH 3.0) are used as catalysts. After oxidation, the BOD/COD ratio in the proposed process increased from 0.03 to 0.25, indicating that the biodegradability of the leachate was improved. By comparing the efficiency on COD removal and economical aspect of the proposed Pd-based in-situ process with traditional Fenton, electro-Fenton and UV-Fenton for leachate treatments, the proposed Pd-based in-situ process has potential economic advantages over other advanced oxidation processes while the COD removal efficiency was maintained. [ABSTRACT FROM AUTHOR]

• A novel flower-like anisotropic MgAl-LDH/BC engineered biochar was synthesized. • Cationic Pb2+ and anionic CrO 4 2− can be simultaneously captured by MgAl-LDH/BC. • CrO 4 2− was mainly removal via reduction, and subsequently isomorphic substitution. • The mechanism for Pb2+ removal was the complexations and electrostatic attraction. • The fixed-bed column evaluated the feasibility of MgAl-LDH/BC. Cationic and anionic heavy metal contaminants generally co-exist in practical industrial effluent, and simultaneously removal of these species is a bottleneck for most of the bio-adsorbents because of their contrary charge. In this work, pinewood sawdust derived engineered biochar (BC) was fabricated with MgAl layered double hydroxide (MgAl-LDH) nanosheets, which could efficiently and simultaneously capture heavy metal cations and oxyanions from wastewater. The synergetic effect between loaded MgAl-LDH and BC substantially improves its adsorption performance towards both cationic and anionic contaminants, i.e., Pb2+ and CrO 4 2−. The adsorption capacity of MgAl-LDH/BC for Pb2+ reached 591.2 mg/g, which is 263% higher than that of BC, and in the case of CrO 4 2−, the adsorption capacity is 330.8 mg/g, 416% higher than that of BC. The elimination of Pb2+ was mainly attributed to forming complexations with surface functional groups. While for oxyanions removal, CrO 4 2− can be reduced to Cr3+ by functional groups, and then generated Cr3+ could replace Al3+ via morphic substitution, consequently formed an MgCr-LDH structure. Further, in the continuous fixed-bed column study, 225 bed volume of simulating electroplating wastewater co-existed with Pb2+ and CrO 4 2− can be efficiently treated. Hence, this study sheds light on the engineered biochar design to efficiently and simultaneously capture heavy metal cations and oxyanions and its feasibility on real wastewater purification. [ABSTRACT FROM AUTHOR]

The agglomeration of rGO resulted from the morphological irregularities restrict its direct applications as catalyst for pollutants removal using advance oxidation processes (AOPs). In this study, we addressed this problem after incorporating the nanosheets of reduced graphene oxide (rGO) in the layers of hydroxides (LDHs) as Fe-rGO LDH hetero-composite. Based on the first order kinetic model, the fabricated composite showed excellent phenol removal with degradation rate constant of 0.16 min−1, 5–100 times higher than Fe-LDH/rGO or other control catalysts. This enhanced catalytic activity was resulted from the systematic assembly of both monolayered rGO and LDHs as superlattice materials, avoiding the aggregation of rGO during the reaction and thus promote the interfacial electron transfer among the active sites. Moreover, Fe-rGO LDH/PMS system exhibited consistent performance over a wide pH range (3.0 ─ 12.0) and broad spectrum of co-existing water constituents (anions and humic acid). The spectroscopic and analytical results suggested that the special arrangement of monolayered rGO in Fe-LDHs facilitated Fe sites to form a stable Fe intermediates after reacting PMS, offering a suitable centre to accept electron from another PMS to generate superoxides (•O 2 −). Finally, singlet oxygen (1O 2) was accounted as dominant reactive oxygen species (ROS) for pollutants removal. Image 1 [ABSTRACT FROM AUTHOR]

• Synergistic effect of Cu and Co oxides was find on various supports. • Incorporation of Cu changed the activation pathway of PMS by Co catalysts. • Surface hydroxyl groups on catalysis was studied quantitatively. • Electron transfer between Cu and Co improved the stoichiometric efficiency of PMS. Synergistic effect was commonly observed in bimetallic oxide catalysts in sulfate radical-based advanced oxidation processes by forming spinel structures. In this paper, we found the incorporation of Cu demonstrated the most remarkable promotional effect to Co oxides comparing with Fe and Mn in PMS activation, and no spinel structure of mixed metals was found. Moreover, the synergism between oxides of Cu and Co was observed on various supports including MgAl layered double hydroxides, mesoporous MnO 2 and ZnO. Under conditions of 0.2 g L−1 catalysts, 2 mM PMS, and 40 ppm 4-chlorophenol (4-CP), CuCo@ZnO/PMS system demonstrated excellent performance that 96.0% 4-CP could be removed, while the removal efficiency of 4-CP in Cu@ZnO/PMS and Co@ZnO/PMS systems was only 12.1% and 45.4%, respectively. The simultaneous incorporation of Co and Cu bimetallic oxides in CuCo@ZnO led to a higher surface hydroxyl density, and this surface hydroxyl density showed a linear relationship to their first order kinetic constant in 4-CP degradation. Moreover, the results of peroxymonosulfate (PMS) decomposition, quantification of sulfate radical (SO 4 −), EPR, XPS, H 2 -TPR, and CV indicated that the synergism of Cu/Co also arose from the electron transfer between Cu(I) and Co(III), which altered the redox circle of Co(II)/Co(III) and increased the steady concentration of oxidative radicals. Due to this synergism, the degradation percentage of organic contaminants, stability of heterogeneous catalysts and the stoichiometric efficiency of PMS were all improved. These findings were highly suggestive to the further development of bimetallic heterogeneous catalysts in persulfate based advanced oxidation processes. [ABSTRACT FROM AUTHOR]