Lam, Lui, Guyon, Etienne M., Langevin, Dominique, Stanley, H. Eugene, Kleman, Maurice, and Lavrentovich, Oleg D.
We describe the state of deformation of a nematic or a cholesteric phase, at a fixed temperature T, by the director field n(r). The free energy associated with the deformation depends necessarily on the gradient of the director, ∇n, whose components $$ \frac{{\partial n_i }} {{\partial x_j }} $$ will be noted ni,j. We assume that the distortions are small, ni,j« 1/a, where a is a typical molecular length. This assumption has some advantages, as follows: There is a well-defined "tangent" perfect (liquid) crystal at each point r, with orientation n(r), whose spatial extention is large enough to make a continuous description possible.Therefore, the order parameter is a locally well-defined constant s[T(r)], which depends on temperature uniquely.At any point r, the symmetry properties of the tangent liquid crystal should reflect in its free energy density f(r), which however depends not only on n(r), but also on its derivatives ∇n. It is stated that f must be invariant under any change of the orientation of n and of the values of its derivatives ∇n, which are allowed by the symmetries. This invariance is by no means trivial, and it should be considered as a principle, to which one could attach the name of Noll (principle of material invariance); it goes much farther than does the invariance of the Landau expansion, which does not depend on the derivative. [ABSTRACT FROM AUTHOR]